Abstract: Continuous electrolytic pickling method for steels, Nickel, superalloys, Titanium and alloys thereof, characterised in that the material to be treated , for a time comprised between 3 sec and 60 sec, is immersed into or passes through at least one electrolytic cell with an electrolytic solution consisting of a neutral or acid aqueous solution, at a temperature comprised between 20 DEG C. and 95 DEG C., with at least one pair of electrodes connected to an alternate current power supply having a frequency ranging from 1 Hz to 1000 Hz, the electrolysis being carried out at a current density having an effective amplitude ranging from 10 A/dm2 to 250 A/dm2. The Figure depicts the progress of the weight loss of an AISI 409 (X6CrTil2) steel as a function of the application time of an embodiment of the pickling method according to the present invention.