Abstract: A method of making surface-functionalized transition metal oxide nanoparticles comprises: providing a sol comprising transition metal oxide nanoparticles dispersed in an aqueous liquid medium having a pH of less than or equal to 3.5, combining the sol with an extractant composition comprising at least one carboxylic acid and at least one organic amine, and a water-immiscible organic solvent, and separating at least a portion of the organic phase from the aqueous phase and then at least partially removing the water-immiscible organic solvent. The carboxylic acid has from 6 to 30 atoms. The organic amine has is 1° or 2° and has from 6 to 34 carbon atoms. The at least one organic amine is present in an amount sufficient raise the pH to at least 5, thereby forming discrete separable aqueous and organic phases. A surface-modified nanoparticle composition, a curable composition and an article comprising the same are also disclosed.

Abstract: An optical film includes a plurality of first layers disposed on a plurality of second layers. For each angle of incidence in an incident angle range of 0-50 degrees, an optical transmittance of each of the optical film and the plurality of second layers versus wavelength includes a band edge disposed in a transition wavelength range separating a visible wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Tv and Tv2 from an infrared wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Ti and Ti2. Each of Tv and Tv2 is greater than about 30%. An average value of Tv2 is greater than an average value of Tv by at least 5%. An average value of Ti is less than an average value of Ti2 by at least 20%.

Abstract: Optical devices include a visible light source, a visible light detector, and a multi-layer film article in the pathway between the visible light source and the visible light detector. The multi-layer film article includes an optical film layer and an optically clear adhesive layer. The optically clear adhesive layer includes a polymeric adhesive matrix, and at least one infrared light absorbing material that absorbs light in the range of 680-1100 nanometers. The infrared light absorbing material is an organic dye.

Abstract: A method of making surface-functionalized transition metal oxide nanoparticles comprises: providing a sol comprising transition metal oxide nanoparticles dispersed in an aqueous liquid medium having a pH of less than or equal to 3.5, combining the sol with an extractant composition comprising at least one carboxylic acid and at least one organic amine, and a water-immiscible organic solvent, and separating at least a portion of the organic phase from the aqueous phase and then at least partially removing the water-immiscible organic solvent. The carboxylic acid has from 6 to 30 atoms. The organic amine is represented by the formula R2R3NH, wherein R2 is a hydrocarbyl group having from 6 to 30 carbon atoms, and R3 is H or an alkyl group having from 1 to 4 carbon atoms. The at least one organic amine is present in an amount sufficient raise the pH to at least 5, thereby forming discrete separable aqueous and organic phases.

Abstract: An optical film includes a plurality of first layers disposed on a plurality of second layers. For each angle of incidence in an incident angle range of 0-50 degrees, an optical transmittance of each of the optical film and the plurality of second layers versus wavelength includes a band edge disposed in a transition wavelength range separating a visible wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Tv and Tv2 from an infrared wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Ti and Ti2. Each of Tv and Tv2 is greater than about 30%. An average value of Tv2 is greater than an average value of Tv by at least 5%. An average value of Ti is less than an average value of Ti2 by at least 20%.

Abstract: Presently described are optical films comprising a polymerized (e.g. microstructured) surface that comprises the reaction product of a polymerizable resin composition and polymerizable resin compositions that comprise nanoparticles; at least one first monomer comprising at least two (meth)acrylate groups; and at least one second (meth)acrylate monomer having the structure wherein at least one R1 comprises an aromatic substituent, t is an integer from 1 to 4, and R2 is hydrogen or methyl.

Abstract: Presently described are optical films comprising a polymerized (e.g. microstructured) surface that comprises the reaction product of a polymerizable resin composition and polymerizable resin compositions that comprise nanoparticles; at least one first monomer comprising at least two (meth)acrylate groups; and at least one second (meth)acrylate monomer having the structure wherein at least one R1 comprises an aromatic substituent, t is an integer from 1 to 4, and R2 is hydrogen or methyl.

Abstract: Optical devices include a visible light source, a visible light detector, and a multi-layer film article in the pathway between the visible light source and the visible light detector. The multi-layer film article includes an optical film layer and an optically clear adhesive layer. The optically clear adhesive layer includes a polymeric adhesive matrix, and at least one infrared light absorbing material that absorbs light in the range of 680-1100 nanometers. The infrared light absorbing material is an organic dye.

Abstract: Described herein is a dicarboxylic acid compound of formula (I): Wherein: R3 comprises an aryl group, R2 is an alkylene group comprising 1 to 6 carbon atoms, n is 0 or 1, R1 is H or CH3, and X is S or NZ, wherein Z is H, an alkyl group comprising 1 to 4 carbon atoms or a phenyl group. Such compounds can be used to modify the surface of inorganic particles. These modified inorganic particles may then be advantageously used in polymerizable resins to increase the refractive index of the resulting composite, while enabling good flow properties of the polymerizable composition.

Abstract: An optical system comprises a turning film and a lenticular diffuser. The lenticular diffuser comprises a structured surface comprising a plurality of microstructures comprises a plurality of lenticular prisms separated by substantially flat land areas, the lenticular prisms having a rounded tip and two sides comprising a linear base section and a linear tip section connected by a polynomial blend section.

Abstract: An optical system comprises a turning film and a lenticular diffuser. The lenticular diffuser comprises a structured surface comprising a plurality of microstructures each comprising a lenticular prism having linear end sections connected by a blend section separated by a substantially flat land area, wherein the blend section shape is a segment of an ellipse of 2nd, 4th or 6th order polynomial.

Abstract: The present disclosure provides an article including a layer having a nanostructured first surface including nanofeatures and an opposing second surface, and an organic layer including a major surface attached to a portion of the nanofeatures. The nanostructured first surface includes protruding features that are formed of a single composition and/or recessed features. The nanofeatures and the major surface of the second layer together define at least one void. The present disclosure also provides a method of making the article including contacting nanofeatures of a layer having a nanostructured surface with a major surface of an organic layer and reacting at least one material to secure the two layers together. In addition, the present disclosure provides an optical information display and an OLED device including the article. The nanostructured surface of the article is protected from damage and contamination by the organic layer.

Abstract: The composition includes an antimicrobial monomer represented by formula CH2?C(R1)—C(O)—O-Q-N+(R)2CnH2n+1(X—), a non-fluorinated crosslinking monomer having at least two acrylate groups, methacrylate groups, or a combination thereof, a polar monomer having at least one of acrylic acid, methacrylic acid, or a carboxylate salt thereof, and a nonpolar monomer represented by formula CH2?C(R1)—C(O)—O—R2. The antimicrobial monomer, the non-fluorinated crosslinking monomer, the polar monomer, and the nonpolar monomer together account for greater than 95 percent by weight, based on the total weight of the composition. The article includes a film having a plurality of pendent groups represented by formula —C(O)—O-Q-N+(R)2CnH2n+1(X—) covalently bonded in a crosslinked non-fluorinated acrylic network. A method of making an article is also described.

Abstract: Presently described are optical films comprising a polymerized (e.g. microstructured) surface that comprises the reaction product of a polymerizable resin composition and polymerizable resin compositions that comprise nanoparticles; at least one first monomer comprising at least two (meth)acrylate groups; and at least one second (meth)acrylate monomer having the structure wherein at least one R1 comprises an aromatic substituent, t is an integer from 1 to 4, and R2 is hydrogen or methyl.

Abstract: Optical devices comprising at least one optical layer and at least one antistatic layer disposed on at least one surface of the optical layer wherein the antistatic layer comprises the reaction product of: (a) at least one polymerizable onium salt; and (b) at least one polymerizable, non-onium, silicone or perfluoropolyether moiety-containing monomer, oligomer, or polymer.

Abstract: Described herein is a dicarboxylic acid compound of formula (I): Wherein: R3 comprises an aryl group, R2 is an alkylene group comprising to 6 carbon atoms, n is 0 or 1, R1 is H or CH3, and X is S or NZ, wherein Z is H, an alkyl group comprising to 4 carbon atoms or a phenyl group. Such compounds can be used to modify the surface of inorganic particles.

Abstract: A method of making surface-functionalized transition metal oxide nanoparticles comprises: providing a sol comprising transition metal oxide nanoparticles dispersed in an aqueous liquid medium having a pH of less than or equal to 3.5, combining the sol with an extractant composition comprising at least one carboxylic acid and at least one organic amine, and a water-immiscible organic solvent, and separating at least a portion of the organic phase from the aqueous phase and then at least partially removing the water-immiscible organic solvent. The carboxylic acid has from 6 to 30 atoms. The organic amine is represented by the formula R2R3NH, wherein R2 is a hydrocarbyl group having from 6 to 30 carbon atoms, and R3 is H or an alkyl group having from 1 to 4 carbon atoms. The at least one organic amine is present in an amount sufficient raise the pH to at least 5, thereby forming discrete separable aqueous and organic phases.

Abstract: A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.

Abstract: A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.

Abstract: An optical film includes a plurality of first layers disposed on a plurality of second layers. For each angle of incidence in an incident angle range of 0-50 degrees, an optical transmittance of each of the optical film and the plurality of second layers versus wavelength includes a band edge disposed in a transition wavelength range separating a visible wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Tv and Tv2 from an infrared wavelength range where the optical film and the plurality of second layers have respective average optical transmittances Ti and Ti2. Each of Tv and Tv2 is greater than about 30%. An average value of Tv2 is greater than an average value of Tv by at least 5%. An average value of Ti is less than an average value of Ti2 by at least 20%.