Abstract: Described is a fuser member including a substrate and a release layer disposed on the substrate. The release layer includes a fluoropolymer having a plurality of metal fibers having a diameter of from about 5 nanometers to about 20 microns dispersed throughout the fluoropolymer. A method of manufacturing the fuser member is also provided.

Abstract: The present disclosure provides a transparent cross-linked siloxane composition. The composition is a polymerization product of a mixture of a difunctional alkoxysilane precursor materials and a monofunctional alkoxysilane material. The monofunctional alkoxysilane material is from about 1 weight percent to about 50 weight percent of the composition. The mole ratio of the monofunctional alkoxysilane materials to difunctional alkoxysilane precursor materials is from 1 to 4 to about 1 to 1.

Abstract: There is provided a crosslinked siloxane composition. The crosslinked siloxane composition is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials. At least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material. In addition at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: Described is a fuser member including a substrate and a release layer disposed on the substrate. The release layer includes a fluoropolymer having a plurality of metal fibers having a diameter of from about 5 nanometers to about 20 microns dispersed throughout the fluoropolymer. A method of manufacturing the fuser member is also provided.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a non-woven polymer fiber matrix and a polymer dispersed throughout the non-woven polymer fiber matrix. The polymer fiber matrix has a first surface energy and the polymer has a second surface energy. The difference between the first surface energy and the second surface energy is from about 30 mJ/m2 to about 5 mJ/m2.

Abstract: An intermediate transfer member containing a thermally conductive nanofiller dispersed in a polymer base, a method of forming the intermediate transfer member, and a method of printing an image to a substrate using the intermediate transfer member.

Abstract: A formulation composition for preparing a print head face plate coating includes a sol containing a mixture of monomers including at least one fluoroalkyl alkoxysilane monomer; a solvent; a catalyst; and water. The formulation composition is stable towards gelation for more than 1.5 hours. A method of preparing a print head involves preparing a formulation composition containing a sol prepared from a mixture of monomers including at least one fluoroalkyl alkoxysilane monomer, a solvent, a catalyst, and water; applying the formulation composition as a sol on a surface of the print head; and curing the formulation composition to form a crosslinked siloxane layer on the print head. A method of printing involves using the print head to apply inkjet ink to a substrate.

Abstract: An organo siloxy network film composition including at least one type of tether molecule having a siloxy functionality; at least one type of building block having a siloxy functionality; wherein the tether molecule and the building block each have the same siloxy functionality; and wherein the siloxy functionality in the organo siloxy network film is derived from the same siloxy functionality on both the tether molecules and the building blocks.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a surface layer having a surface roughness (Ra) of from about 50 nm to about 5 microns. The surface layer has a surface energy between 8 mN/m2 and 30 mN/m2. The surface layer includes an elastomeric matrix having a plurality texture particles dispersed therein. The weight percent of the texture particles in the surface layer is from about 0.2 weight percent to about 20 weight percent.

Abstract: A reinforced fluoropolymer composite is presented, which includes a fluoropolymer and a fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates. The fluoro-functionalized nanocrystalline cellulose may be used to produce stable dispersions with fluoropolymers exhibiting enhanced adhesion between the nanocrystalline particles and fluoropolymer in a composite material, and decreased surface free energy of the cellulose surface.

Abstract: An organo siloxy network film composition including at least one type of tether molecule having a siloxy functionality; at least one type of building block having a siloxy functionality; wherein the tether molecule and the building block each have the same siloxy functionality; and wherein the siloxy functionality in the organo siloxy network film is derived from the same siloxy functionality on both the tether molecules and the building blocks.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a non-woven polymer fiber matrix and a polymer dispersed throughout the non-woven polymer fiber matrix. The polymer fiber matrix has a first surface energy and the polymer has a second surface energy. The difference between the first surface energy and the second surface energy is from about 30 mJ/m2 to about 5 mJ/m2.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: Described herein is a transfer member for use in aqueous ink jet printer. The transfer member includes a surface layer of a cross-linked polydiphenylsiloxane network formed from a silanol terminated dialkylsiloxane-diphenylsiloxane copolymer and a trialkoxy- or trihydroxysilane terminated polydialkylsiloxane. The diphenylsiloxane moieties are from about 5 weight percent to about 80 weight percent of the network. The trialkoxy- or trihydroxysilane terminated polydialkylsiloxane are from about 1 weight percent to about 60 weight percent of the network. All silane molecules are bonded together via silicon oxide (Si—O—Si) linkages in a single system. The network is insoluble in solvents selected from the group consisting of: ketones, chlorinated solvents and ethers.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a non-woven polymer fiber matrix and a polymer dispersed throughout the non-woven polymer fiber matrix. The polymer fiber matrix has a first surface energy and the polymer has a second surface energy. The difference between the first surface energy and the second surface energy is from about 30 mJ/m2 to about 5 mJ/m2.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: An intermediate transfer member containing a layer of a siloxyfluorocarbon networked polymer. A method of preparing an intermediate transfer member including mixing a coating solution containing siloxyfluorocarbon precursor materials; applying the coating solution as a sol on a substrate; curing the coating solution on the substrate to form an intermediate transfer member containing a layer of a siloxyfluorocarbon networked polymer. The surface free energy of the intermediate transfer member may be from about 10 mN/m to about 40 mN/m. A method of printing an image to a substrate includes applying an inkjet ink to an intermediate transfer member containing a layer of a siloxyflurocarbon networked polymer; spreading the ink onto the intermediate transfer member; inducing a property change of the ink; and transferring the ink to a substrate.