Abstract: A method of preparing a diene rubber latex having large size particles, good stability and reduced coagulum during polymerization wherein the method comprises: (a) pretreating a seed diene rubber latex with an anionic emulsifier and a non-ionic emulsifier, (b) adjusting the pH of an unsaturated carboxylic acid-containing copolymer latex to about 5 to 11 and adjusting the solids content of the copolymer latex to about 1 to 10% by weight solids content to produce an agglomerating latex solution, and (c) adding the pretreated seed diene rubber latex of step (a) to the agglomerating latex solution of step (b). Step (c) must be carried out by adding the pretreated seed diene rubber latex to the agglomerating latex. If the agglomerating latex is added to the rubber latex, an undesirable level of coagulum is produced.

Abstract: The present invention provides a method of preparing a synthetic rubber latex having a large particle size, showing good stability and reducing coagulum during polymerization, which comprises (a) pretreating a seed synthetic rubber latex by mixing the seed synthetic rubber latex with deionized water and a small amount of an emulsifier and stirring, (b) preparing an agglomerating latex with a pH value of about 5.0˜8.0 by mixing a copolymer latex containing unsaturated acid having from about 10 to about 50% by weight of solid content with deionized water and a pH controlling agent, and (c) adding the pretreated seed synthetic rubber latex of step (a) to the agglomerating latex of step (b). The step (c) may be carried out by adding the pretreated seed synthetic rubber latex dropwisely to the agglomerating latex containing unsaturated acid for about 30 minutes to about 1 hour.

Abstract: A flameproof thermoplastic resin composition of the present invention comprises (A) a base resin comprising 40 to 95% by weight of a rubber modified styrene-containing resin (a1) composed of 20 to 100% by weight of a styrene-containing graft copolymer resin (a11) and 0 to 80% by weight of a styrene-containing copolymer resin (a12), and 60 to 5% by weight of polyphenylene ether resin (a2); (B) 2 to 40 parts by weight of a styrene-acrylonitrile copolymer containing 5 to 18% by weight of acrylonitrile per 100 parts by weight of the base resin; (C) 5 to 30 parts by weight of an aromatic phosphoric acid ester compound having a melting point of more than 90° C. per 100 parts by weight of the base resin; and (D) 3 to 30 parts by weight of a phenolic resin per 100 parts by weight of the base resin.

Abstract: A method of preparing a diene rubber latex having large size particles, good stability and reduced coagulum during polymerization wherein the method comprises:

Abstract: A flameproof thermoplastic resin composition of the present invention comprises (A) a base resin comprising 40 to 95% by weight of a rubber modified styrene-containing resin (a1) composed of 20 to 100% by weight of a styrene-containing graft copolymer resin (a11) and 0 to 80% by weight of a styrene-containing copolymer resin (a12), and 60 to 5% by weight of polyphenylene ether resin (a2); (B) 2 to 40 parts by weight of a styrene-acrylonitrile copolymer containing 5 to 18% by weight of acrylonitrile per 100 parts by weight of the base resin; (C) 5 to 30 parts by weight of an aromatic phosphoric acid ester compound having a melting point of more than 90° C. per 100 parts by weight of the base resin; and (D) 3 to 30 parts by weight of a phenolic resin per 100 parts by weight of the base resin.

Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting a mixture of water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60˜80° C., preferably for about 8˜16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5˜20° C. higher than the polymerization temperature, preferably for about 4˜12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order.

Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60.about.80.degree. C., preferably for about 8.about.16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5.about.20.degree. C. higher than the polymerization temperature, preferably for about 4.about.12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order. The agglomerating agent is prepared a method comprising a first step of forming agglomerating seeds by batch polymerization of an alkyl acrylate of C.sub.1 .about.C.sub.12, an anionic surfactant and an anionic initiator, a second step of growing the agglomerating agent in semi-batch polymerization by adding an alkyl acrylate of C.sub.1 .about.C.sub.