Publication number: 20240047731
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, a separator, and an electrolyte, wherein the positive electrode includes a positive electrode active material layer having a positive electrode active material containing an overlithiated manganese-based oxide represented by Formula 1 below, and the negative electrode includes a negative electrode active material layer having a silicon-based negative electrode active material, LiaNibCocMndMeO2 ??[Formula 1] wherein, M is at least one selected from the group consisting of Al, B, Co, W, Mg, V, Ti, Zn, Ga, In, Ru, Nb, Sn, Sr, and Zr, and 1<a, 0?b?0.5, 0?c?0.1, 0.5?d<1.0, and 0?e?0.2, and. Preferably, in the Formula 1, 1.1?a?1.5, 0.1?b?0.4, 0?c?0.05, 0.5?d?0.80, and 0?e?0.1.
Type:
Application
Filed:
July 21, 2022
Publication date:
February 8, 2024
Applicant:
LG Energy Solution, Ltd.
Inventors:
Byung Chun Park, Yo Han Kwon, Je Young Kim, Seok Koo Kim, Wang Mo Jung, Yong Ju Lee, Chul Haeng Lee
Publication number: 20230059519
Abstract: Provided is a method of preparing an irreversible positive electrode additive for a secondary battery, which includes mixing Li2O, NiO, and NH4VO3 and performing thermal treatment to prepare a lithium nickel composite oxide represented by Chemical Formula 1 below, wherein the NH4VO3 is mixed in an amount of 1.5 to 6.5 parts by weight with respect to a total of 100 parts by weight of the Li2O, NiO, and NH4VO3. Li2+aNi1?b?cM1bVcO2?dAd??[Chemical Formula 1] In Chemical Formula 1, M1 is at least one selected from the group consisting of Cu, Mg, Pt, Al, Co, P, W, Zr, Nb, and B, A is at least one selected from the group consisting of F, S, Cl, and Br, and 0?a?0.2, 0?b?0.5, 0.01?c?0.065, and 0?d?0.2 are satisfied.
Type:
Application
Filed:
February 26, 2021
Publication date:
February 23, 2023
Applicant:
LG Energy Solution, Ltd.
Inventors:
Tae Gu Yoo, Byung Chun Park, Bo Ram Lee, Tae Gon Kim, Min Kwak, Wang Mo Jung