Abstract: The invention relates to a method for modifying the water permeability of a subterranean formation, comprising at least the following steps: Preparing an injection fluid from a dispersion of a hydrophilic phase in a lipophilic phase, with water or brine, the dispersion comprising: a hydrophilic phase comprising at least one cross-linked (co)polymer PR, a lipophilic phase, at least one interface polymer composed of at least one monomer of formula (I): Injecting the injection fluid into the subterranean formation, said cross-linked (co)polymer PR forming a hydrogel in the presence of water.

Abstract: The present invention relates to an effluent treatment method for treating an aqueous effluent having solid particles, the method including the addition to the effluent of at least one water-soluble polymer comprising at least one non-ionic monomer and at least one anionic monomer obtained by controlled radical polymerization, the said polymer having a UL viscosity of between 2 and 4.5 cps.

Abstract: This invention relates to a process of enhanced oil recovery by sweeping an underground formation comprising injecting into the underground formation an injection fluid comprising at least one water-soluble LCST macromonomeric polymer.

Abstract: A process for enhanced oil recovery comprising the following steps: a) Preparation of an injection fluid comprising at least one water-soluble (co)polymer prepared at least from 2-acrylamido-2-methylpropane sulfonic acid (ATBS) or from at least one of its salts, with water or with brine, where the 2-acrylamido-2-methylpropane sulfonic acid is a hydrated crystalline form of 2-acrylamido-2-methylpropane sulfonic acid having a 2-theta powder X-ray diffraction diagram comprising peaks at 10.58°, 11.2°, 12.65°, 13.66°, 16.28°, 18.45°, 20°, 20.4°, 22.5°, 25.5°, 25.88°, 26.47°, 28.52°, 30.28°, 30.8°, 34.09°, 38.19°, 40.69°, 41.82°, 43.74°, 46.04° degrees. b) Injection of injection fluid into an underground formation, c) Flushing of the underground formation using the fluid injected, d) Recovery of an aqueous and hydrocarbon mixture.

Abstract: The invention relates to an inverse polymer emulsion having the particular feature of auto-inverting without any need for the use of an inverting agent and containing a polymer of at least one water-soluble monomer and at least one LCST macromonomer. The invention also relates to the use of the inverse emulsion in the fields of the oil and gas industry, water treatment, slurry treatment, paper manufacturing, construction, mining, cosmetics, textiles, detergents or agriculture.

Abstract: Fracturing fluid comprising, in solution in water, a proppant and an associative amphoteric polymer, the said polymer and comprising: 0.01 to 10 mol % of at least one cationic monomer containing a hydrophobic chain, from 0.09 to 89.99 mol % of at least one anionic monomer, and from 10 to 99.9 mol % of at least one nonionic water-soluble monomer, the total amount of monomer being 100 mol %. Fracturing process using this fluid.

Abstract: A composition for preparing an injection fluid in oil and gas recovery comprising an inverse emulsion of a water-soluble polymer A comprising cationic monomer units, and solid particles of a water-soluble polymer B comprising cationic monomer units, and wherein water-soluble polymer A comprises between 10 and 40 mol % of a cationic monomer units based on the total amount of monomer units; and wherein the cationicity in mol % of polymer A is superior or equal to the cationicity in mol % of polymer B. Method of treating a portion of subterranean formation comprising providing said composition, preparing an injection fluid with at least said composition, introducing the injection fluid into portion of the subterranean formation. The composition is particularly useful to prepare fracturing fluid in fracturing operations.

Abstract: The present invention relates to a method for enhanced oil recovery by flushing an underground formation, comprising the injection into the underground formation of an aqueous composition comprising microgels having at least one crosslinked polymer, characterized in that the polymer is crosslinked with at least one crosslinking agent capable of being degraded under the temperature conditions of the underground formation, and a content of crosslinking agent between 1 and 90 ppm per mole with respect to the total number of moles of monomer constituting the polymer.

Abstract: The invention relates to a new dialkyl tin oxide catalyst composition and its use for the synthesis of amino alkyl (meth)acrylates by transesterification from an alkyl (meth)acrylates and an amino alcohol, and especially 2-dimethylaminoethyl (meth)acrylate. The invention also relates to polymers made with quaternized amino alkyl (meth)acrylates and use of said polymers in water treatment, sludge dewatering, papermaking process, agriculture, cosmetic and detergency composition, textile process, oil and gas recovery process such as enhanced oil recovery, fracturing, mining operation such as tailings treatment.

Abstract: The present invention relates to a method for determining the anionic charge density of at least one polymer present in a sample, according to the following steps: bringing the at least one polymer present in the sample into contact with, and enabling the interaction thereof with, a developer solution comprising lanthanide (III) ions, exciting the sample at an excitation wavelength ?exc and detecting, by time-resolved photoluminescence, a signal originating from the lanthanide (III) ions that have interacted with the at least one polymer at an emission wavelength ?em, and determining the anionic charge density of the at least one polymer of the sample using the signal detected at the emission wavelength ?em.

Abstract: The present invention relates to an aqueous multiphase particulate suspension comprising a water-soluble polymer and to an enhanced oil recovery method using said suspension. The invention further relates to the use of the multiphase suspension in a drilling, hydraulic fracturing and mining effluent treatment operation.

Abstract: The invention concerns a flocculation formulation. The invention also concerns the treatment of mine tailings in the form of aqueous effluents comprising solid particles. With the method of the invention, it is possible to separate all or part of the water from an aqueous effluent comprising solid particles.

Abstract: The present invention concerns a method for treating the production water originating from enhanced hydrocarbon recovery, and containing one or more water-soluble polymers and Fe2+ ions, consisting of at least partially oxidizing the Fe2+ ions by introducing at least one reaction activator and oxygen into said production water, the molar ratio of introduced oxygen to Fe2+ ions being less than or equal to 0.25.

Abstract: Process for the production of anionic water-soluble polymer obtained by the polymerization of acrylic acid and acrylamide obtained by biocatalysed reaction, said process comprising the steps of preparing a diluted solution of acrylic acid by mixing acrylic acid and water wherein the mass ratio between acrylic acid and water is comprised between 95:5 and 70:30, preparing a diluted solution of bioacrylamide and water wherein the mass ratio between bioacrylamide and water is comprised between 60:40 and 10:90, mixing said diluted solution of acrylic acid with said diluted solution of bioacrylamide, neutralizing partially or totally the acid function of acrylic acid and polymerizing the resulting mixture.

Abstract: The present application concerns a water-in-oil inverse emulsion comprising: oil; water; at least one water-soluble anionic polymer of average molecular weight higher than 3 million daltons, containing between 4 and 14 mol % of sulfonated anionic monomers, between 0 and 17 mol % of carboxylated anionic monomers and between 69 and 94 mol of nonionic monomers; at least one inverting agent and at least one emulsifying agent, the weight ratio R between the total amount of inverting agent and the total amount of emulsifying agent being higher than 1.

Abstract: Process for the production of 2-dimethylaminoethyl (meth)acrylate in multiple stage batch reactions involving the recycling of the catalyst (DBTO) in subsequent reaction, the addition a certain amount of fresh catalyst to the recycled catalyst, the use of said catalysts in the subsequent reaction, and wherein the volume decrease due to azeotropic distillation is compensate in order to keep the volume constant in the reactor during the reaction by the continuous addition of a composition comprising methyl(meth)acrylate and dimethylaminoethanol.

Abstract: Method of treating a portion of subterranean formation, comprising providing a water in oil emulsion of a water-soluble polymer, said emulsion comprising at least an inverting agent, and at least an emulsifying agent, wherein the mass ratio R of the total amount of inverting agent to the total amount of emulsifying agent is superior to 1.2, wherein the water in oil emulsion contains from 0.5% to 6% by weight of inverting agent; inverting the water in oil emulsion by adding it into an aqueous fluid to form an injection fluid; introducing the injection fluid into portion of the subterranean formation.

Abstract: The present invention relates to a fracturation fluid comprising at least one propping agent and at least one water-soluble (co)polymer prepared from the hydrated crystalline form of 2-acrylamido-2-methylpropane sulfonic acid and/or at least one of its salts. The invention relates to a process to prepare said fluid, and to a hydraulic fracturation process using said fluid.

Abstract: The present invention is concerned with the treatment of produced water, that may be obtained from a chemically enhanced oil recovery process using viscosity-increasing polymeric compounds. Said treatment comprises particularly the steps of obtaining a produced water, such as from an oil-water mixture recovered from an oil-bearing formation, wherein the produced water comprises the viscosity-increasing polymeric compounds; and, of directing the produced water to a specific filtration device, and subjecting the produced water to filtration, for obtaining a retentate stream and a permeate stream. Said process allows particularly obtaining a permeate comprising the viscosity-increasing polymeric compounds, said permeate being substantially free of suspended solids, free oil and emulsified oil.

Abstract: The invention concerns the treatment of mine tailings in the form of aqueous effluents comprising solid particles. With the method of the invention it is possible to separate all or part of the water from an aqueous effluent comprising solid particles. This method comprises (a) adding at least one sulfonated dispersing agent to the effluent, then (b) adding at least one agent to flocculate the solid particles. The invention also relates to a composition comprising an aqueous effluent comprising dispersed, flocculated solid particles. Preferably it relates to a composition comprising an aqueous effluent comprising solid particles, at least one sulfonated dispersing agent and at least one agent to flocculate solid particles.