Abstract: A method for manufacturing a battery cell includes coating a three dimensional current collector (3DCC) with a lithiophilic metal oxide layer; and one of laminating the 3DCC with the lithiophilic metal oxide layer between a first lithium metal layer and a second lithium metal layer to create an anode electrode; and coating the 3DCC with the lithiophilic metal oxide layer with molten lithium to create an anode electrode.

Abstract: A method for manufacturing a current collector for an electrode of a battery cell includes providing a wire mesh current collector including wires that have a diameter and form mesh junctions; and rolling the wire mesh current collector using a first roller and a second roller, wherein the first roller and the second roller are spaced by a predetermined gap. The predetermined gap is less than 2 times the diameter of the wires of the wire mesh current collector.

Abstract: A battery that cycles lithium ions includes a negative electrode current collector and a lithium metal layer deposited thereon. The negative electrode current collector has a layered structure including a metal substrate and a carbon layer formed in situ on the metal substrate. The negative electrode current collector includes a plurality of perforations extending therethrough. The lithium metal layer is chemically bonded to the carbon layer of the negative electrode current collector. The negative electrode current collector is manufactured via a method that includes a photolithography process, a pyrolysis process, and a surface functionalization process.

Abstract: A composite electrode for an electrochemical cell that cycles lithium ions may include a metal current collector having a three-dimensional porous structure defining an interconnected network of open pores and an electrode material disposed within the open pores of the current collector. An oxygen-containing reactive layer may be formed on surfaces of the current collector and an electrode precursor mixture may be deposited thereon and dried to form a solid electrode material having a continuous structure within the open pores of the current collector. The electroactive material particles and/or the electrically conductive agent may interact with the oxygen-containing reactive layer on the metal current collector to form an oxygen-containing adhesive layer along an interface between the current collector and the solid electrode material.

Abstract: An electrode assembly includes a current collector, a lithium metal foil, and an alloyed interface that chemically binds the current collector and the lithium metal foil. In certain variations, the alloyed interface includes an intermediate layer disposed between the current collector and the lithium metal foil, a portion of the current collector adjacent to the intermediate layer is alloyed with the indium, gallium, or alloy of indium and gallium defining the intermediate layer, and a portion of the lithium metal foil adjacent to the intermediate layer is alloyed with the indium, gallium, or alloy of indium and gallium defining the intermediate layer. In other variations, the alloyed interface includes a copper-lithium alloy.

Abstract: The present disclosure provides electrode assemblies for safe nondestructive testing in ambient conditions. In certain variations, the electrode assembly includes a current collector and a non-reactive lithium mimic material disposed on or near one or more surfaces of the current collector or embedded in the current collector. In other variations, the electrode assembly includes include a current collector, a lithium metal material disposed on or near one or more surfaces of the current collector or embedded in the current collector to form an electrode assembly, and a non-conductive pouch holding the electrode assembly.

Abstract: The present disclosure provides electrode assemblies for safe nondestructive testing in ambient conditions. In certain variations, the electrode assembly includes a current collector and a non-reactive lithium mimic material disposed on or near one or more surfaces of the current collector or embedded in the current collector. In other variations, the electrode assembly includes include a current collector, a lithium metal material disposed on or near one or more surfaces of the current collector or embedded in the current collector to form an electrode assembly, and a non-conductive pouch holding the electrode assembly.

Abstract: An electrode assembly includes a current collector, a lithium metal foil, and an alloyed interface that chemically binds the current collector and the lithium metal foil. In certain variations, the alloyed interface includes an intermediate layer disposed between the current collector and the lithium metal foil, a portion of the current collector adjacent to the intermediate layer is alloyed with the indium, gallium, or alloy of indium and gallium defining the intermediate layer, and a portion of the lithium metal foil adjacent to the intermediate layer is alloyed with the indium, gallium, or alloy of indium and gallium defining the intermediate layer. In other variations, the alloyed interface includes a copper-lithium alloy.

Abstract: The present disclosure provides a method for preparing an electroactive material for an electrochemical cell that cycles lithium ions. The method includes immersing a plurality of electroactive material particles in an aqueous solution and adding one or more fluorinated lithium salts to the aqueous solution to form a protective particle coating on each of the electroactive material particles of the plurality of electroactive material particles, where the plurality of electroactive material particles defines the electroactive material. The protective particle coatings are continuous coatings that cover greater than or equal to about 95% of a total exposed surface area of each electroactive material particle of the plurality of electroactive material particles.

Abstract: An electrode assembly that includes a current collector, a lithium foil, and a solid solution interface that chemically binds the current collector and the lithium foil is provided. The solid solution interface includes a portion of the current collector that is impregnated with lithium atoms diffused from the lithium foil. In some variations, a method for forming the electrode assembly includes heating a precursor electrode assembly that includes a current collector and a lithium metal film to a temperature that is less than a melting point of lithium, so that lithium atoms diffuse into the current collector during the heating. In other variations, a method for forming the electrode assembly includes disposing a molten lithium onto a heated current collector to form a precursor electrode assembly, and cooling the assembly to form a lithium metal layer that is chemically bonded to the current collector.

Abstract: The present disclosure provides a lithiophilic-supported current collector for an electrochemical cell that cycles lithium ions. The lithiophilic-supported current collector includes a current collector substrate and a lithiophilic material. The lithiophilic material includes an element selected from the group consisting of: indium, lead, bismuth, gold, and combinations thereof. In certain variations, the lithiophilic material defines a lithiophilic layer disposed on or adjacent to one or more surfaces of the current collector substrate. In other variations, the current collector substrate has one or more porous surfaces and the lithiophilic material coats the one or more porous surfaces.

Abstract: An electrode including an electrochemical layer defining a surface having a plurality of dimples formed thereon is provided. The dimples have an average lateral size greater than or equal to about 100 nm to less than or equal to about 100 ?m, and an average depth greater than or equal to about 100 nm to less than or equal to about 50 ?m. In certain variations, the dimples are formed in situ by applying a current to the electrochemical layer. In other variations, the dimples are formed by moving a roller having a plurality of shapes defined thereon along one or more surfaces of the electrochemical layer. In still other variations, the dimples are formed by contacting one or more surfaces of the electrochemical layer with a chemical etchant.