Abstract: A multi-layer cathode coating for positive electrode of a rechargeable electrochemical cell (or secondary cell) (such as a lithium-ion secondary battery) and a secondary battery including a cathode having a multi-layer cathode coating. Multi-layer cathode coatings containing blends of one or more cathode active materials in certain weight ratios thereof.

Abstract: Pre-lithiation methods using lithium vanadium fluorophosphate (e.g., LiVPO4F and its derivatives) (“LVPF”) as a cathode active material in a lithium-ion secondary battery. The pre-lithiation methods include compensating for an expected loss of active lithium by selecting LVPF having a specific pre-lithiated chemistry (or a blend of LVPF selected to have a specific pre-lithiated chemistry) and selecting a total amount of the pre-lithiated LVPF. The pre-lithiation methods may include initially charging the lithium-ion secondary battery at the lower of the two charge/discharge plateaus of LVPF to release active lithium.

Abstract: Provided is a positive electrode active material for a lithium-ion battery, the positive electrode active material including a blend of a doped lithium manganese iron phosphate (dLMFP) according to the formula: LiMnxFeyM1?x?yPO4, wherein 0.9<x+y<1; and M is one or more selected from the group consisting of Mg, Ca and Ba with one or both of a lithium nickel cobalt manganese oxide (NMC) compound having a Ni content greater than 0.6 relative to a total amount of metals other than Li and a lithium nickel cobalt aluminum oxide (NCA) compound. In particular, provided is a blend at a weight ratio of dLMFP to NMC and/or NCA (i.e., dLMFP:(NMC+NCA)) of >70:<30, such as 75:25, 80:20, 85:15, 90:10, etc.

Abstract: Pre-lithiation methods using lithium vanadium fluorophosphate (e.g., LiVPO4F and its derivatives) (“LVPF”) as a cathode active material in a lithium-ion secondary battery. The pre-lithiation methods include compensating for an expected loss of active lithium by selecting LVPF having a specific pre-lithiated chemistry (or a blend of LVPF selected to have a specific pre-lithiated chemistry) and selecting a total amount of the pre-lithiated LVPF. The pre-lithiation methods may include initially charging the lithium-ion secondary battery at the lower of the two charge/discharge plateaus of LVPF to release active lithium.

Abstract: Provided are an electrolyte for low temperature operation of lithium titanate electrodes, graphite electrodes, and lithium-ion batteries as well as electrodes and batteries employing the same. The electrolyte contains 1 to 30 vol % of a low molecular weight ester having a molecular weight of less than 105 g/mol and at least one non-fluorinated carbonate. An electrolyte additive may include 0.1 to 10 wt % of fluorinated ethylene carbonate, particularly when used with a graphite anode. Another electrolyte contains a high content of the low molecular weight ester of at least 70 vol %.

Abstract: Provided is a positive electrode active material for a lithium-ion battery, the positive electrode active material including a blend of a doped lithium manganese iron phosphate (dLMFP) according to the formula: LiMnxFeyM1?x?yPO4, wherein 0.9<x+y<1; and M is one or more selected from the group consisting of Mg, Ca and Ba with one or both of a lithium nickel cobalt manganese oxide (NMC) compound having a Ni content greater than 0.6 relative to a total amount of metals other than Li and a lithium nickel cobalt aluminum oxide (NCA) compound. In particular, provided is a blend at a weight ratio of dLMFP to NMC and/or NCA (i.e., dLMFP:(NMC+NCA)) of >70:<30, such as 75:25, 80:20, 85:15, 90:10, etc.

Abstract: Provided are an electrolyte for low temperature operation of lithium titanate electrodes, graphite electrodes, and lithium-ion batteries as well as electrodes and batteries employing the same. The electrolyte contains 1 to 30 vol % of a low molecular weight ester having a molecular weight of less than 105 g/mol and at least one non-fluorinated carbonate. An electrolyte additive may include 0.1 to 10 wt % of fluorinated ethylene carbonate, particularly when used with a graphite anode. Another electrolyte contains a high content of the low molecular weight ester of at least 70 vol %.