Patents by Inventor Carl K. Esche

Carl K. Esche has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10087390
    Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.
    Type: Grant
    Filed: May 3, 2016
    Date of Patent: October 2, 2018
    Assignee: VANDERBILT CHEMICALS, LLC
    Inventors: Carl K. Esche, Glenn A. Mazzamaro
  • Patent number: 9677024
    Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: June 13, 2017
    Assignee: VANDERBILT CHEMICALS, LLC
    Inventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
  • Publication number: 20160326451
    Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.
    Type: Application
    Filed: May 3, 2016
    Publication date: November 10, 2016
    Applicant: VANDERBILT CHEMICALS, LLC
    Inventors: Carl K. ESCHE, Glenn A. MAZZAMARO
  • Publication number: 20150133352
    Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.
    Type: Application
    Filed: June 5, 2013
    Publication date: May 14, 2015
    Applicant: VANDERBILT CHEMICALS, LLC
    Inventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
  • Publication number: 20140274840
    Abstract: The present invention relates to a lubricant composition Lubricant composition comprising at least one oil-soluble organic molybdenum compound, and at least one alkyl- or aryl-substituted ammonium tungstate, wherein the weight ratio of molybdenum to tungsten in the lubricant composition is at least 2.5:1, and the amount of molybdenum in the lubricant composition is at least 350 ppm based on the total weight of the lubricant composition. The compositions provide unexpected and substantially improved friction and abrasion properties over related compositions devoid of the invention. When using these lubricant compositions, for example in internal combustion engines, the engine power can be increased and the fuel consumption can be reduced.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 18, 2014
    Applicants: PANTERE GMBH & CO. KG, VANDERBILT CHEMICALS, LLC
    Inventors: Carl K. ESCHE, David BOUDREAU, SR., Mihir K. PATEL, Holger AULER, Axel DIETRICH, Michael ESPER
  • Publication number: 20110265372
    Abstract: There is disclosed a fuel composition comprising: a water-free, organic fuel; and a nanoalloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein each n is independently greater than or equal to zero; wherein the nanoalloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7.
    Type: Application
    Filed: June 14, 2011
    Publication date: November 3, 2011
    Inventors: Allen A. Aradi, Carl K. Esche, JR., Katrina Mcintosh, Tze-Chi Jao
  • Patent number: 8003584
    Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.
    Type: Grant
    Filed: July 14, 2006
    Date of Patent: August 23, 2011
    Assignee: Afton Chemical Corporation
    Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
  • Patent number: 7967876
    Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: June 28, 2011
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, Carl K. Esche, Jr., Katrina McIntosh, Tze-Chi Jao
  • Patent number: 7879774
    Abstract: A fully formulated lubricating oil, lubricated surface, and lubricant additive concentrates for lubricants providing reduced sludge formation. The fully formulated lubricating oil composition has therein at least one succinimide dispersant derived from a polyalkylene compound having from about 50 to about 85% vinylidene double bonds in the compound, a metal containing detergent, at least one wear reducing agent, at least one antioxidant, and a hydrocarbon soluble titanium compound as a friction modifier. The lubricating oil composition is also substantially free of molybdenum compounds.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: February 1, 2011
    Assignee: Afton Chemical Corporation
    Inventors: William Y. Lam, John T. Loper, Carl K. Esche, Jr., Christopher J. Dudding, Peter Growcott, Anthony Fagan, Andrew Robertson, Gregory H. Guinther
  • Patent number: 7776800
    Abstract: A lubricating oil composition comprising a) an oil of lubricating viscosity having a viscosity index of at least about 95; b) at least one calcium detergent; c) at least one oil soluble titanium compound; d) at least one friction modifier; and e) at least one metal dihydrocarbyldithiophosphate compound. The composition has a Noack volatility of about 15 wt. % or less, and contains from about 0.05 to about 0.6 wt. % calcium from the calcium detergent, titanium metal in an amount of at least about 10 ppm up to about 1500 ppm titanium from the titanium compound, and phosphorus from the metal dihydrocarbyldithiophosphate compound in an amount up to about 0.1 wt. %.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: August 17, 2010
    Assignee: Afton Chemical Corporation
    Inventors: William Y. Lam, Gregory H. Guinther, Carl K. Esche, Jr.
  • Patent number: 7767632
    Abstract: Lubricated surfaces, lubricant compositions for lubricating a surface, and methods for increasing antiwear properties in lubricants. The lubricated surface is provided by a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble titanium compound effective to provide an increase in antiwear properties of the lubricant composition greater than an increase in antiwear properties of the lubricant composition devoid of the hydrocarbon soluble titanium compound.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: August 3, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Carl K. Esche, Jr., Mark T. Devlin
  • Patent number: 7709423
    Abstract: Lubricated surfaces, lubricant compositions for lubricating a surface, and methods for reducing friction coefficients in lubricants. The lubricated surface is provided by a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble titanium compound effective to provide a reduction in the coefficient of friction of the lubricant composition greater than a reduction in the coefficient of friction of the lubricant composition devoid of the hydrocarbon soluble titanium compound.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: May 4, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Carl K. Esche, Jr., Mark T. Devlin, Tze-Chi Jao
  • Patent number: 7645728
    Abstract: A composition for use as an additive for fuels or lubricants. The composition includes a reaction product of a treated amine and a compound selected from the group consisting of hydrocarbyl succinic anhydrides, Mannich adducts derived from hydrocarbyl-substituted phenols reacted with formaldehydes, ethylene-propylene copolymers grafted with ethylenically unsaturated carboxylic groups, copolymers of unsaturated acids and polyolefins, and acid or ester functionalized hydrocarbon polymers. The reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography. The treated amine includes an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with an aliphatic or aromatic nitrile and hydrogen.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: January 12, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Carl K. Esche, Jr., John T. Loper
  • Patent number: 7615519
    Abstract: A lubricated surface and method for reducing wear between metal parts. The lubricated surface contains a base oil of lubricating viscosity and an amount of a hydrocarbon soluble titanium compound effective to provide a reduction in surface wear greater than a surface wear of a lubricant composition devoid of the hydrocarbon soluble titanium compound.
    Type: Grant
    Filed: July 19, 2004
    Date of Patent: November 10, 2009
    Assignee: Afton Chemical Corporation
    Inventors: Carl K. Esche, Jr., Christopher J. Dudding, Peter Growcott, Anthony Fagan, Andrew Robertson
  • Patent number: 7615520
    Abstract: A method and compositions for lubricating surfaces with lubricating oils exhibiting increased antioxidant properties. The lubricated surface includes a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble metal compound effective to provide a reduction in oxidation of the lubricant composition greater than a reduction in oxidation of the lubricant composition devoid of the hydrocarbon soluble metal compound. The metal of the metal compound is selected from the group consisting of titanium, zirconium, and manganese.
    Type: Grant
    Filed: March 14, 2005
    Date of Patent: November 10, 2009
    Assignee: Afton Chemical Corporation
    Inventor: Carl K. Esche, Jr.
  • Publication number: 20090075853
    Abstract: A slow release liquid additive concentrate for use in an engine oil filter and a method for extending an oil drain interval for an engine. The additive concentrate has therein at least one detergent and at least one antioxidant. The additive concentrate has a tan delta of greater than about 5.
    Type: Application
    Filed: September 18, 2007
    Publication date: March 19, 2009
    Inventors: Naresh C. Mathur, Charles A. Passut, Carl K. Esche, JR.
  • Publication number: 20080040969
    Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.
    Type: Application
    Filed: August 17, 2006
    Publication date: February 21, 2008
    Inventors: Allen A. ARADI, Carl K. Esche, Katrina McIntosh, Tze-Chi Jao
  • Publication number: 20080015128
    Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.
    Type: Application
    Filed: July 14, 2006
    Publication date: January 17, 2008
    Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
  • Patent number: 7049273
    Abstract: This invention relates to a novel multi-functional fuel and lubricant additive that provides dispersancy properties as well as viscosity index improver credit and, improved fuel economy. The invention further relates to concentrates, and to fuel and lubricating oil compositions containing said additive or concentrates. Finally, the invention provides methods for improving fuel economy, improving dispersancy, and for preparing the hybridized, acylated olefin copolymer useful as an oil additive.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: May 23, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventors: Carl K. Esche, Jr., Charles Thomas West
  • Publication number: 20040224858
    Abstract: The present invention provides a low sulfur, low ash, and low phosphorus oil soluble lubricant additive package comprising an overbased metal phenate. Also included in the present invention are lubricating oils comprising the inventive oil soluble lubricant additive package, as well as machines lubricated by such oils. Several methods for lubricating machinery are also disclosed.
    Type: Application
    Filed: May 6, 2003
    Publication date: November 11, 2004
    Applicant: Ethyl Corporation
    Inventor: Carl K. Esche