Patents by Inventor Carl K. Esche
Carl K. Esche has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 10087390Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.Type: GrantFiled: May 3, 2016Date of Patent: October 2, 2018Assignee: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro
-
Patent number: 9677024Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.Type: GrantFiled: June 5, 2013Date of Patent: June 13, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
-
Publication number: 20160326451Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.Type: ApplicationFiled: May 3, 2016Publication date: November 10, 2016Applicant: VANDERBILT CHEMICALS, LLCInventors: Carl K. ESCHE, Glenn A. MAZZAMARO
-
Publication number: 20150133352Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.Type: ApplicationFiled: June 5, 2013Publication date: May 14, 2015Applicant: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
-
Publication number: 20140274840Abstract: The present invention relates to a lubricant composition Lubricant composition comprising at least one oil-soluble organic molybdenum compound, and at least one alkyl- or aryl-substituted ammonium tungstate, wherein the weight ratio of molybdenum to tungsten in the lubricant composition is at least 2.5:1, and the amount of molybdenum in the lubricant composition is at least 350 ppm based on the total weight of the lubricant composition. The compositions provide unexpected and substantially improved friction and abrasion properties over related compositions devoid of the invention. When using these lubricant compositions, for example in internal combustion engines, the engine power can be increased and the fuel consumption can be reduced.Type: ApplicationFiled: March 7, 2014Publication date: September 18, 2014Applicants: PANTERE GMBH & CO. KG, VANDERBILT CHEMICALS, LLCInventors: Carl K. ESCHE, David BOUDREAU, SR., Mihir K. PATEL, Holger AULER, Axel DIETRICH, Michael ESPER
-
Publication number: 20110265372Abstract: There is disclosed a fuel composition comprising: a water-free, organic fuel; and a nanoalloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein each n is independently greater than or equal to zero; wherein the nanoalloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7.Type: ApplicationFiled: June 14, 2011Publication date: November 3, 2011Inventors: Allen A. Aradi, Carl K. Esche, JR., Katrina Mcintosh, Tze-Chi Jao
-
Patent number: 8003584Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.Type: GrantFiled: July 14, 2006Date of Patent: August 23, 2011Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
-
Patent number: 7967876Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.Type: GrantFiled: August 17, 2006Date of Patent: June 28, 2011Assignee: Afton Chemical CorporationInventors: Allen A. Aradi, Carl K. Esche, Jr., Katrina McIntosh, Tze-Chi Jao
-
Patent number: 7879774Abstract: A fully formulated lubricating oil, lubricated surface, and lubricant additive concentrates for lubricants providing reduced sludge formation. The fully formulated lubricating oil composition has therein at least one succinimide dispersant derived from a polyalkylene compound having from about 50 to about 85% vinylidene double bonds in the compound, a metal containing detergent, at least one wear reducing agent, at least one antioxidant, and a hydrocarbon soluble titanium compound as a friction modifier. The lubricating oil composition is also substantially free of molybdenum compounds.Type: GrantFiled: December 15, 2006Date of Patent: February 1, 2011Assignee: Afton Chemical CorporationInventors: William Y. Lam, John T. Loper, Carl K. Esche, Jr., Christopher J. Dudding, Peter Growcott, Anthony Fagan, Andrew Robertson, Gregory H. Guinther
-
Patent number: 7776800Abstract: A lubricating oil composition comprising a) an oil of lubricating viscosity having a viscosity index of at least about 95; b) at least one calcium detergent; c) at least one oil soluble titanium compound; d) at least one friction modifier; and e) at least one metal dihydrocarbyldithiophosphate compound. The composition has a Noack volatility of about 15 wt. % or less, and contains from about 0.05 to about 0.6 wt. % calcium from the calcium detergent, titanium metal in an amount of at least about 10 ppm up to about 1500 ppm titanium from the titanium compound, and phosphorus from the metal dihydrocarbyldithiophosphate compound in an amount up to about 0.1 wt. %.Type: GrantFiled: December 9, 2005Date of Patent: August 17, 2010Assignee: Afton Chemical CorporationInventors: William Y. Lam, Gregory H. Guinther, Carl K. Esche, Jr.
-
Patent number: 7767632Abstract: Lubricated surfaces, lubricant compositions for lubricating a surface, and methods for increasing antiwear properties in lubricants. The lubricated surface is provided by a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble titanium compound effective to provide an increase in antiwear properties of the lubricant composition greater than an increase in antiwear properties of the lubricant composition devoid of the hydrocarbon soluble titanium compound.Type: GrantFiled: December 22, 2005Date of Patent: August 3, 2010Assignee: Afton Chemical CorporationInventors: Carl K. Esche, Jr., Mark T. Devlin
-
Patent number: 7709423Abstract: Lubricated surfaces, lubricant compositions for lubricating a surface, and methods for reducing friction coefficients in lubricants. The lubricated surface is provided by a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble titanium compound effective to provide a reduction in the coefficient of friction of the lubricant composition greater than a reduction in the coefficient of friction of the lubricant composition devoid of the hydrocarbon soluble titanium compound.Type: GrantFiled: November 16, 2005Date of Patent: May 4, 2010Assignee: Afton Chemical CorporationInventors: Carl K. Esche, Jr., Mark T. Devlin, Tze-Chi Jao
-
Patent number: 7645728Abstract: A composition for use as an additive for fuels or lubricants. The composition includes a reaction product of a treated amine and a compound selected from the group consisting of hydrocarbyl succinic anhydrides, Mannich adducts derived from hydrocarbyl-substituted phenols reacted with formaldehydes, ethylene-propylene copolymers grafted with ethylenically unsaturated carboxylic groups, copolymers of unsaturated acids and polyolefins, and acid or ester functionalized hydrocarbon polymers. The reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography. The treated amine includes an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with an aliphatic or aromatic nitrile and hydrogen.Type: GrantFiled: February 17, 2004Date of Patent: January 12, 2010Assignee: Afton Chemical CorporationInventors: Carl K. Esche, Jr., John T. Loper
-
Patent number: 7615519Abstract: A lubricated surface and method for reducing wear between metal parts. The lubricated surface contains a base oil of lubricating viscosity and an amount of a hydrocarbon soluble titanium compound effective to provide a reduction in surface wear greater than a surface wear of a lubricant composition devoid of the hydrocarbon soluble titanium compound.Type: GrantFiled: July 19, 2004Date of Patent: November 10, 2009Assignee: Afton Chemical CorporationInventors: Carl K. Esche, Jr., Christopher J. Dudding, Peter Growcott, Anthony Fagan, Andrew Robertson
-
Patent number: 7615520Abstract: A method and compositions for lubricating surfaces with lubricating oils exhibiting increased antioxidant properties. The lubricated surface includes a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble metal compound effective to provide a reduction in oxidation of the lubricant composition greater than a reduction in oxidation of the lubricant composition devoid of the hydrocarbon soluble metal compound. The metal of the metal compound is selected from the group consisting of titanium, zirconium, and manganese.Type: GrantFiled: March 14, 2005Date of Patent: November 10, 2009Assignee: Afton Chemical CorporationInventor: Carl K. Esche, Jr.
-
Publication number: 20090075853Abstract: A slow release liquid additive concentrate for use in an engine oil filter and a method for extending an oil drain interval for an engine. The additive concentrate has therein at least one detergent and at least one antioxidant. The additive concentrate has a tan delta of greater than about 5.Type: ApplicationFiled: September 18, 2007Publication date: March 19, 2009Inventors: Naresh C. Mathur, Charles A. Passut, Carl K. Esche, JR.
-
Publication number: 20080040969Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.Type: ApplicationFiled: August 17, 2006Publication date: February 21, 2008Inventors: Allen A. ARADI, Carl K. Esche, Katrina McIntosh, Tze-Chi Jao
-
Publication number: 20080015128Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
-
Patent number: 7049273Abstract: This invention relates to a novel multi-functional fuel and lubricant additive that provides dispersancy properties as well as viscosity index improver credit and, improved fuel economy. The invention further relates to concentrates, and to fuel and lubricating oil compositions containing said additive or concentrates. Finally, the invention provides methods for improving fuel economy, improving dispersancy, and for preparing the hybridized, acylated olefin copolymer useful as an oil additive.Type: GrantFiled: July 17, 2002Date of Patent: May 23, 2006Assignee: Afton Chemical Intangibles LLCInventors: Carl K. Esche, Jr., Charles Thomas West
-
Publication number: 20040224858Abstract: The present invention provides a low sulfur, low ash, and low phosphorus oil soluble lubricant additive package comprising an overbased metal phenate. Also included in the present invention are lubricating oils comprising the inventive oil soluble lubricant additive package, as well as machines lubricated by such oils. Several methods for lubricating machinery are also disclosed.Type: ApplicationFiled: May 6, 2003Publication date: November 11, 2004Applicant: Ethyl CorporationInventor: Carl K. Esche