Abstract: The invention relates to a process for the production of decorative coatings, comprising the following steps: A) providing a substrate to be coated and a backing film coated on one side with an uncured or only partially cured coating of a coating composition curable by means of high-energy radiation, B) forming zones on the backing film which are opaque to high-energy radiation and correspond to the negative image of a desired pattern or decoration, C) applying the coated side of the backing film having the uncured or only partially cured coating of a coating composition curable by means of high-energy radiation with the coated side thereof onto a substrate surface, D) curing the coating applied by the backing film by irradiation with high-energy radiation through the backing film, E) removing the backing film from the coating which remains on the substrate, and F) removing the un-irradiated and thus uncured parts of the coating remaining on the substrate to obtain the desired pattern or decoration.

Abstract: Non-aqueous, liquid coating compositions curable by free-radical polymerization of olefinic double bonds with a resin solids content consisting of 50 to 100 wt. % of a binder solids content curable by free-radical polymerization of olefinic double bonds, 0 to 30 wt. % of one or more crosslinking agents C and 0 to 50 wt. % of one or more components D, wherein the weight percentages add up to 100 wt. %, wherein the binder solids content consists of above 95 wt. % to 99.5 wt. % of one or more components A curable by free-radical polymerization of olefinic double bonds and 0.5 to below 5 wt. % of one or more polyurethane resins B curable by free-radical polymerization of olefinic double bonds, wherein the weight percentages of the at least one component A and the at least one polyurethane resin B add up to 100 wt.

Abstract: The present invention provides a powder coating composition comprising A) 30 to 90 wt% of at least one glycidyl-functionalised (meth)acrylic resin, B) 30 to 90 wt% of at least one carboxyl functionalised polyurethane resin, C) 0.01 to 10 wt% of at least one wax, and D) 0.05 to 30 wt% of at least one coating additive, and optionally pigment and/or filler, the wt % based on the total weight of the powder coating composition; the powder coating composition provides coatings with a very low gloss level (highly matt finish) and smoothness, a superior durability against aggressive substances and a very good adhesion on metallic substrates.

Abstract: A solvent-based coating composition, used in automotive original and automotive refinish coating, comprising 10-90% by weight of at least one hydroxyl-functional (meth)acrylic copolymer A) having an OH value from 80 to 200 KOH/g and a weight average molecular weight Mw from 2,500 to 30,000 and 90-10 weight.-% of at least one cross-linking agent B), which is capable of entering into a cross-linking reaction with the OH-groups of components A), wherein the % by weight of component A) and B) add up to 100 weight.

Abstract: A process for the preparation of powder coatings with a controlled surface appearance comprising the steps of applying a powder coating composition onto the substrate surface comprising 1 to 95 wt % of at least one hydrophobic agent, irradiating the applied powder coating composition with high energy radiation having a UV dose in a range of 100 to 5000 mJ/cm2 under near-ambient temperature, fusing, melting and flowing out the particles of the powder coating composition by increased temperature to a molten coating, and curing the molten coating; the process according to the invention makes it possible to provide coatings with a controlled surface appearance as well as to provide coatings having a high mechanical and outdoor stability without a change in formulation of the powder coating composition.

Abstract: Polyurethaneurea resins containing at least one group of the formula (I) —NH(CO)XOR1O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—??(I) and/or at least one group of the formula (II) {—NH(CO)XO}a{CH2?CR2(CO)O}bR4{O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—}c??(II) wherein X=[O(CH2)4]q(OC2H4)x(OC3H6)y[(CH2)5(CO)]z; q=0 to 10; x=0 to 20; y=0 to 20; z=0 to 10; n=2 or 3; a=1 or 2; b=0 to 4; c=1 to 5; R1=—C2H4—, —C3H6—, —C4H8—, —CH(CH2O(CO)R5)CH2— or —CH2CH(O(CO)R5)CH2—; R2=H or CH3; R3=C1 to C4 alkyl; R4=a+b+c-valent, saturated hydrocarbon residue of a (cyclo)alkane polyol with a+b+c hydroxyl groups; R5=an acid residue of a monocarboxylic acid, with the proviso that a+b+c=3 to 6 and wherein the sequence of the subformulae indicated q, x, y and z may be varied at will and q, x, y and z in each case merely state the number of instances of the particular subformulae contained in the formulae (I) and (II).

Abstract: Non-aqueous, liquid coating compositions curable by free-radical polymerization of olefinic double bonds with a resin solids content consisting of 50 to 100 wt. % of a binder solids content curable by free-radical polymerization of olefinic double bonds, 0 to 30 wt. % of at least one crosslinking agent C and 0 to 50 wt. % of at least one component D, wherein the weight percentages add up to 100 wt. %, wherein the binder solids content consists of 40 to 95 wt. % of at least one component A curable by free-radical polymerization of olefinic double bonds and 5 to 60 wt. % of at least one binder B curable by free-radical polymerization of olefinic double bonds, wherein the weight percentages of the at least one component A and the at least one binder B add up to 100 wt. %, wherein the at least one component A is liquid and/or is present in dissolved form and wherein the at least one binder B is present as particles of resin having a melting temperature of 60 to 160° C.

Abstract: A process for the production of a coating layer from a thermally curable coating composition on a substrate, comprising the successive steps: a) providing a substrate to be coated, b) applying a backing foil coated on one side with an uncured or at least only partially cured coating layer of a thermally curable coating composition, with its coated side on the entire surface or at least one sub-zone of the surface of the substrate, c) supplying thermal energy onto the entire coating applied in step b), and d) removing the backing foil from the coating which remains on the substrate; wherein the supply of thermal energy onto the coating proceeds prior to and/or after removal of the backing foil.

Abstract: A process for the production of polyurethane di(meth)acrylates in which a diisocyanate component, a diol component and hydroxy-C2–C4-alkyl (meth)acrylate in the molar ratio x:(x?1):2 are reacted without solvent and without subsequent purification operations, wherein x means any desired value from 2 to 5, wherein 50 to 80 mol % of the diisocyanate component is formed by 1,6-hexane diisocyanate, and 20 to 50 mol % by one or two diisocyanates, each forming at least 10 mol % of the diisocyanate component and being selected from the group consisting of toluylene diisocyanate, diphenylmethane diisocyanate, dicyclohexylmethane diisocyanate, isophorone diisocyanate, trimethylhexane diisocyanate, cyclohexane diisocyanate, cyclohexanedimethylene diisocyanate and tetramethylenexylylene diisocyanate, wherein the mol % of the respective diisocyanates add up to 100 mol %, wherein the diol component comprises no more than four different diols, and 20 to 100 mol % of the diol component is formed by at least one linear alipha

Abstract: A powder coating agent comprising a resin solids content, wherein the resin solids content exhibits an equivalent weight of olefinic double bonds of 200 to 2000 and a content of silicon bound in alkoxysilane groups of 1 to 10 wt. %.

Abstract: A process for the production of polyurethane di(meth)acrylates in which a diisocyanate component, a diol component and hydroxy-C2-C4-alkyl(meth)acrylate in the molar ratio x:(x-1):2 are reacted without solvent and without subsequent purification operations, wherein x means any desired value from 2 to 5, wherein 50 to 80 mol % of the diisocyanate component is formed by 1,6-hexane diisocyanate, and 20 to 50 mol % by one or two diisocyanates, each forming at least 10 mol % of the diisocyanate component and being selected from the group consisting of toluylene diisocyanate, diphenylmethane diisocyanate, dicyclohexylmethane diisocyanate, isophorone diisocyanate, trimethylhexane diisocyanate, cyclohexane diisocyanate, cyclohexanedimethylene diisocyanate and tetramethylenexylylene diisocyanate, wherein the mol % of the respective diisocyanates add up to 100 mol %, wherein the diol component comprises no more than four different diols, and 20 to 100 mol % of the diol component is formed by at least one linear aliphat

Abstract: An aqueous coating composition, comprising A) at least one water-dilutable hydroxy-functional binder and B) at least one polyisocyanate crosslinking agent with free isocyanate groups, wherein component A) comprises A1) 40-95 wt. % of at least one water-dilutable hydroxy-functional (meth)acrylic copolymer with a hydroxyl value of 60-250 mg of KOH/g and an acid value of 5-50 mg of KOH/g, which is obtained by free-radical copolymerization performed in a non-aqueous phase, wherein the ratio of primary hydroxyl groups to secondary hydroxyl groups in the (meth)acrylate copolymer A1) is 1:0.1 to 1:1.2 and at least 80% of the secondary hydroxyl groups result from reaction products of a monoepoxy ester and an unsaturated acid-functional monomer, and A2) 5-60 wt. % of at least one water-dilutable polyester oligomer, wherein the total of the weight percentages of component A1) and A2) add up to 100 wt.

Abstract: A process for the production of polyurethane (meth)acrylates, in which a trimer of a (cyclo)aliphatic diisocyanate, 1,6-hexanediisocyanate, a diol component and hydroxy-C2-C4 alkyl (meth)acrylate in the molar ratio 1:x:x:3 are reacted without solvent and without subsequent purification operations, wherein x means any desired value from 1 to 6, wherein the diol component is selected from the group consisting of an individual linear aliphatic alpha,omega C2-C12 diol and a combination of two to four (cyclo)aliphatic diols, wherein in the case of diol combination each of the diols makes up at least 10 mol % of the diols of the diol combination and the diol combination consists to at least 80 mol % of at least one linear aliphatic alpha,omega C2-C12 diol.

Abstract: The invention relates to a process for repairing coated substrate surfaces comprising the following successive steps: a) optionally, preparing a blemished area to be repaired, b) providing at least one backing film coated on one side with an uncured or at least only partially cured coating layer of a thermally curable coating composition, c) applying the at least one backing film with its coated side onto the blemished area to be repaired, d) supplying thermal energy to the coating applied in this manner onto the blemished area to be repaired and e) removing the at least one backing film, wherein the supply of thermal energy onto the coating proceeds through the at least one backing film, and/or after removal of the at least one backing film.

Abstract: The invention relates to a process for the production of decorative coatings, comprising the following steps: A) providing a substrate to be coated and a backing film coated on one side with an uncured or only partially cured coating of a coating composition curable by means of high-energy radiation, B) forming zones on the backing film which are opaque to high-energy radiation and correspond to the negative image of a desired pattern or decoration, C) applying the coated side of the backing film having the uncured or only partially cured coating of a coating composition curable by means of high-energy radiation with the coated side thereof onto a substrate surface, D) curing the coating applied by the backing film by irradiation with high-energy radiation through the backing film, E) removing the backing film from the coating which remains on the substrate, and F) removing the un-irradiated and thus uncured parts of the coating remaining on the substrate to obtain the desired pattern or decoration.

Abstract: A process for the production of backing foils provided on one side with an uncured or at most partially cured transparent coating and, on the side of the coating remote from the foil, with an image, the process comprising the successive steps: a) providing a backing foil provided on one side with an uncured or at most partially cured transparent coating of a curable coating composition and b) providing the side of the coating remote from the foil with an image, in particular by printing.

Abstract: A process for the production of polyurethane di(meth)acrylates in which 1,6-hexane diisocyanate is reacted, without solvent and without subsequent purification operations, with a diol component and hydroxy-C2-C4-alkyl (meth)acrylate in the molar ratio x:(x?1):2, wherein x means any desired value from 2 to 5 and the diol component is a combination of two to four (cyclo)aliphatic diols with molar masses of 62 to 600 and wherein each of the diols constitutes at least 10 mol % of the diols of the diol component and powder coating compositions having the polyurethane di(meth)acrylates as a binder.

Abstract: A process for the production of a coating layer from a coating composition curable with high-energy radiation on a substrate, comprising the successive steps: a) providing a substrate to be coated, b) applying a backing foil coated on one side with an uncured or at least only partially cured coating layer of a coating composition curable by means of high-energy radiation, with its coated side on the entire surface or at least one sub-zone of the surface of the substrate, c) irradiating the entire coating applied in step b) with high-energy radiation, and d) removing the backing foil from the coating which remains on the substrate; wherein irradiation of the coating proceeds through the backing foil and/or after removal of the backing foil.

Abstract: Polyurethaneurea resins containing at least one group of the formula (I) —NH(CO)XOR1O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—??(I) and/or at least one group of the formula (II) {—NH(CO)XO}a{CH2?CR2(CO)O}bR4{O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—}c??(II) wherein X=[O(CH2)4]q(OC2H4)x(OC3H6)y[(CH2)5(CO)]z; q=0 to 10; x=0 to 20; y=0 to 20; z=0 to 10; n=2 or 3; a=1 or 2; b=0 to 4; c=1 to 5; R1=—C2H4—, —C3H6—, —C4H8—, —CH(CH2O(CO)R5)CH2— or —CH2CH(O(CO)R5)CH2—; R2=H or CH3; R3=C1 to C4 alkyl; R4=a+b+c-valent, saturated hydrocarbon residue of a (cyclo)alkane polyol with a+b+c hydroxyl groups; R5=an acid residue of a monocarboxylic acid, with the proviso that a+b+c=3 to 6 and wherein the sequence of the subformulae indicated q, x, y and z may be varied at will and q, x, y and z in each case merely state the number of instances of the particular subformulae contained in the formulae (I) and (II).

Abstract: The present invention is directed to a powder coating composition that produces a low gloss coating upon cure. The powder coating composition includes one or more crosslinkable base polymer, a crosslinkable acrylic polymer and one or more free radical initiators. By adding spheroidal particles to the powder coating composition further reduction in gloss can be obtained while improving smoothness. These compositions are well suited to produce coatings on metallic substrates, such as automotive bodies and non-metallic substrates, such as reconstituted wood substrates, used for desk or table tops.