Abstract: A lightweight flexible BNNT mat or fabric provides improved thermal stability and shielding capabilities under a hypersonic thermal flux. The BNNT mat reduces the stagnation temperature and maintains a low regression rate. An in-situ passivation layer may be formed on the BNNT mat or fabric under high thermal flux. The passivation layer minimizes or prevents penetration of the atmosphere (air or gas) as well as heat and radiation through the thickness of the BNNT material, and it effectively diffuses heat throughout the mat or fabric laterally and radially to minimize localized excessive heat. A BNNT mat according to the present disclosure may also efficiently transfer heat from the BNNT material via radiation due to the high thermal emissivity (0.92) of the BNNT material.

Abstract: The invention consists of radiation shielding materials for shielding in the most structurally robust combination against galactic cosmic radiation (GCR), neutrons, and solar energetic particles (SEP). Materials for vehicles, space structures, habitats, landers, rovers, and spacesuits must possess functional characteristics of radiation shielding, thermal protection, pressure resistance, and mechanical durability. The materials are tailored to offer the greatest shielding against GCR, neutrons, and SEP in the most structurally robust combination, also capable of shielding against micrometeoriod impact. The boron nitride nanotube (BNNT) is composed entirely of low Z atoms (boron and nitrogen).

Abstract: A lightweight flexible BNNT mat or fabric provides improved thermal stability and shielding capabilities under a hypersonic thermal flux. The BNNT mat reduces the stagnation temperature and maintains a low regression rate. An in-situ passivation layer may be formed on the BNNT mat or fabric under high thermal flux. The passivation layer minimizes or prevents penetration of the atmosphere (air or gas) as well as heat and radiation through the thickness of the BNNT material, and it effectively diffuses heat throughout the mat or fabric laterally and radially to minimize localized excessive heat. A BNNT mat according to the present disclosure may also efficiently transfer heat from the BNNT material via radiation due to the high thermal emissivity (0.92) of the BNNT material.

Abstract: Multifunctional Boron Nitride nanotube-Boron Nitride (BN—BN) nanocomposites for energy transducers, thermal conductors, anti-penetrator/wear resistance coatings, and radiation hardened materials for harsh environments. An all boron-nitride structured BN—BN composite is synthesized. A boron nitride containing precursor is synthesized, then mixed with boron nitride nanotubes (BNNTs) to produce a composite solution which is used to make green bodies of different forms including, for example, fibers, mats, films, and plates. The green bodies are pyrolized to facilitate transformation into BN—BN composite ceramics. The pyrolysis temperature, pressure, atmosphere and time are controlled to produce a desired BN crystalline structure. The wholly BN structured materials exhibit excellent thermal stability, high thermal conductivity, piezoelectricity as well as enhanced toughness, hardness, and radiation shielding properties.

Abstract: Novel polyimide copolymers containing ether linkages were prepared by the reaction of an equimolar amount of dianhydride and a combination of diamines. The polyimide copolymers described herein possess the unique features of low moisture uptake, dimensional stability, good mechanical properties, and moderate glass transition temperatures. These materials have potential application as encapsulants and interlayer dielectrics.

Abstract: A polyimide fiber having textile physical property characteristics and the process of melt extruding same from a polyimide powder. Polyimide powder formed as the reaction product of the monomers 3,4'-ODA and ODPA, and endcapped with phthalic anhydride to control the molecular weight thereof, is melt extruded in the temperature range of 340.degree. C. to 360.degree. C. and at heights of 100.5 inches, 209 inches and 364.5 inches. The fibers obtained have a diameter in the range of 0.0068 inch to 0.0147 inch; a mean tensile strength in the range of 15.6 to 23.1 ksi; a mean modulus of 406 to 465 ksi; and a mean elongation in the range of 14 to 103%.

Abstract: A polyimide fiber having textile physical property characteristics and the process of melt extruding same from a polyimide powder. Polyimide powder formed as the reaction product of the monomers 3,4'-ODA and ODPA, and endcapped with phthalic anhydride to control the molecular weight thereof, is melt extruded in the temperature range of 340.degree. C. to 360.degree. C. and at heights of 100.5 inches, 209 inches and 364.5 inches. The fibers obtained have a diameter in the range of 0.0068 inch to 0.0147 inch; a mean tensile strength in the range of 15.6 to 23.1 ksi; a mean modulus of 406 to 465 ksi; and a mean elongation in the range of 14 to 103%.