Patents by Inventor Cedric Klein
Cedric Klein has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20140142305Abstract: The instant invention relates to novel water soluble bis-(triazinylamino)-stilbene optical brightening agents, a process for their preparation and their use for whitening natural and synthetic materials.Type: ApplicationFiled: April 17, 2012Publication date: May 22, 2014Applicant: CLARIANT INTERNATIONAL LTDInventors: Cedric Klein, Frederic Reveaud, Andrew Clive Jackson, David Atkinson
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Publication number: 20130244147Abstract: The instant invention relates to liquid compositions comprising derivatives of diaminostilbene, binders and ink fixing agents such as divalent metal salts for the optical brightening of substrates suitable for high quality ink jet printing.Type: ApplicationFiled: April 26, 2013Publication date: September 19, 2013Applicant: INTERNATIONAL PAPER COMPANYInventors: Andrew Clive Jackson, Cedric Klein, David Puddiphatt, Benny J. Skaggs
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Patent number: 8518557Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2ML comprising two orthometalated ligands having imidazole moieties and an ancillary ligand of ?-diketonate type. The ortho-metalated transition metal complexes are represented by formula (I): It has been surprisingly found that when the metal has bound thereto both orthometalated ligands comprising imidazole moieties and an ancillary ligand of ?-diketonate type, the ligands advantageously participate in the emission process, significantly broadening emission in the visible region and enabling appreciable improvement of the white emission efficiency of complexes [C^N]2ML. Additional objects of the invention are the use of the light emitting materials and organic light emitting device comprising the light emitting material.Type: GrantFiled: October 11, 2007Date of Patent: August 27, 2013Assignee: Solvay (Societe Anonyme)Inventors: Mohammad Khaja Nazeeruddin, Cedric Klein, Michael Graetzel
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Publication number: 20130209820Abstract: Aqueous coating composition for optical brightening and shading of substrates comprising (a) at least one optical brightener of formula (I) in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more identical or different cations selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched hydroxyalkyl radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C1-C4 linear or branched alkylradical and linear or branched hydroxyalkyl radical or mixtures of said compounds, R1 and R1? may be the same or different, and each is hydrogen, C1-C4 linear or branched alkyl, C2-C4 linear or branched hydroxyalkyl, CH2CO2?, CH2CH2CONH2 or CH2CH2CN, R2 and R2? may be the same or different, and each is C1-C4 linear or branched alkyl, C2-C4Type: ApplicationFiled: June 21, 2011Publication date: August 15, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Heidrun Grether-Schene, Cédric Klein, David Puddiphatt
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Publication number: 20130118698Abstract: Object of the invention is the method for preparing white paper which comprises adding to the pulp mass an aqueous formulation comprising a) at least one optical brightener of formula (I) in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more identical or different cations selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched hydroxyalkyl radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C1-C4 linear or branched alkylradical and linear or branched hydroxyalkyl radical or mixtures of said compounds, wherein R1 and R1? may be the same or different, and each is hydrogen, C1-C4 linear or branched alkyl, C2-C4 linear or branched hydroxyalkyl, CH2CO2?, CH2CH2CONH2 or CH2CH2CN, R2 and R2? may be the same oType: ApplicationFiled: July 22, 2011Publication date: May 16, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Heidrun Grether-Schene, Cedric Klein, Frederic Reveaud, David Atkinson, Andrew Clive Jackson
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Patent number: 8440843Abstract: A dye sensitized solar cell, comprising a heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated ?-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.Type: GrantFiled: April 7, 2011Date of Patent: May 14, 2013Assignee: Ecole Polytechnique Fédérale de LausanneInventors: Shaik Mohammad Zakeeruddin, Cêdric Klein, Peng Wang, Michael Graetzel
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Publication number: 20120311798Abstract: The instant invention relates to liquid sizing compositions comprising shading dyestfuffs, derivatives of diaminostilbene, binders, protective polymers, and optionally divalent metal salts which can be used for the optical brightening of substrates, including substrates suitable for high quality ink jet printing.Type: ApplicationFiled: February 5, 2011Publication date: December 13, 2012Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Cedric Klein, Heidrun Grether-Schene
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Publication number: 20120238171Abstract: Concentrated storage stable aqueous solutions (S) comprising components (a), (b) and (c), wherein component (a) is at least one optical brightening agent of formula (1), in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more cations selected from the group consisting of hydrogen, alkali metal cation, alkaline earth metal cation, ammonium, ammonium which is mono-, di- or trisubstituted by a C1-4 linear or branched alkyl radical and ammonium which is mono-, di- or trisubstituted by a C1-4 linear or branched hydroxyalkyl radical, and the concentration of component (a) is 0.08 to 0.Type: ApplicationFiled: December 1, 2010Publication date: September 20, 2012Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Cedric Klein, Frederic Reveaud, David Puddiphatt, Andrew Clive Jackson
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Publication number: 20110265876Abstract: The present invention relates to novel pyridine compounds that can be used as anchoring ligands in metal-based sensitizing dyes of dye sensitized solar cells (DSCS). The dyes comprising the polypyridine compounds exhibit improved light harvesting ability and lead to increased conversion efficiencies, in particular in thin TiO2 film devices.Type: ApplicationFiled: November 11, 2009Publication date: November 3, 2011Applicants: UNIVERSITÄT ULM, ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)Inventors: Shaik Mohammad Zakeeruddin, Cédric Klein, Mohammad Khaja Nazeeruddin, Michael Graetzel, Amaresh Mishra, Markus Fischer, Peter Bäuerle
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Publication number: 20110226993Abstract: The instant invention relates to improved liquid sizing compositions comprising derivatives of diaminostilbene, binders, protective polymers and divalent metal salts for the optical brightening of substrates suitable for high quality ink jet printing.Type: ApplicationFiled: November 20, 2009Publication date: September 22, 2011Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Andrew Clive Jackson, Cedric Klein, David Puddiphatt
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Publication number: 20110190501Abstract: A dye sensitized solar cell, comprising a heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated n-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.Type: ApplicationFiled: April 7, 2011Publication date: August 4, 2011Inventors: Shaik Mohammad Zakeeruddin, Cêdric Klein, Peng Wang, Michaêl Graetzel
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Publication number: 20110168343Abstract: The instant invention relates to mixed salts of optical brighteners of formula (1), wherein M represents a mixture of Mg2+ with another cation, which provide for superior optical brightening effects when applied to the surface of paper.Type: ApplicationFiled: March 12, 2009Publication date: July 14, 2011Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Andrew Clive Jackson, David Puddiphatt, Cédric Klein
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Patent number: 7932404Abstract: A dye sensitized solar cell, comprising a-heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated n-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring? group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.Type: GrantFiled: July 29, 2005Date of Patent: April 26, 2011Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)Inventors: Shaik Mohammad Zakeeruddin, Cédric Klein, Peng Wang, Michaël Graetzel
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Publication number: 20100162495Abstract: The present invention relates to specific pentamethine cyanine azo complex dye compounds and their use as dyes in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength from 630 to 670 nm. The invention further relates to an optical layer comprising said dyes and to a write only read many (WORM) type optical recording medium capable of recording and reproducing information with radiation of a red laser, which employs said pentamethine cyanine azo complex type dye in the optical layer.Type: ApplicationFiled: May 7, 2008Publication date: July 1, 2010Inventors: Cédric Klein, Jean-Christophe Graciet, Martin Alexander Winter
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Publication number: 20100129553Abstract: The instant invention relates to liquid compositions comprising derivatives of diaminostilbene, binders and ink fixing agents such as divalent metal salts for the optical brightening of substrates suitable for high quality ink jet printing.Type: ApplicationFiled: November 19, 2009Publication date: May 27, 2010Applicant: INTERNATIONAL PAPER COMPANYInventors: Andrew Clive Jackson, Cedric Klein, David Puddiphatt, Benny J. Skaggs
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Publication number: 20100102711Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C?N]2ML comprising two orthometalated ligands having imidazole moieties and an ancillary ligand of ?-diketonate type. It has been surprisingly found that when the metal has bound thereto both ortho-metalated ligands comprising imidazole moieties and an ancillary ligand of ?-diketonate type, said ligands advantageously participate in the emission process, significantly broadening emission in the visible region and enabling appreciable improvement of the white emission efficiency of complexes [C?N]2ML. Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.Type: ApplicationFiled: October 11, 2007Publication date: April 29, 2010Applicant: SOLVAY (SOCIETE ANONYME)Inventors: Mohammad Khaja Nazeeruddin, Cédric Klein, Michael Graetzel
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Publication number: 20100093983Abstract: The invention relates to the use of dyestuff salts of indolinium diazamethine type cations with azo metal complex anions based on pyridinones in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength up to 450 nm. The invention further relates to a write once read many (WORM) type optical data recording medium capable of recording and reproducing information with radiation of blue laser, which employs dyestuff salts of indolinium diazamethine type cations with azo metal complex anions based on pyridinones in the optical layer.Type: ApplicationFiled: May 7, 2008Publication date: April 15, 2010Inventors: Cédric Klein, Jean-Christophe Graciet, Lars Lücke, Martin Alexander Winter
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Publication number: 20090200920Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C?N]2ML, comprising chelate monoionic ligands (L), also called ancillary ligands. It has been surprisingly found that when the ancillary ligand comprises a substituted aromatic ring bearing a substituent possessing adequate electron-donating properties, said ligand (L) advantageously participates in the emission process, significantly shifting emission towards higher energies (blue-shift) and enabling appreciable improvement of the emission efficiency of complexes [C?N]2ML. Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.Type: ApplicationFiled: October 6, 2006Publication date: August 13, 2009Applicant: Solvay SAInventors: Sung Ho Jin, Ok-Sang Jung, Young In Kim, Muyung Ho Hyun, Jae Wook Lee, Ung Chun Yoon, Mohammad Khaja Nazeeruddin, Cedric Klein, Michael Graetzel
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Publication number: 20090115327Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C?N]2M(T)(L), comprising chelate dialkylamino-substituted C?N ligands, monodentate neutral ligand (L) having sp2 hybridized N atom and a monodentate anionic ligand (T) chosen among CN?, CNO?, CNS?. It has been surprisingly found that when the metal has bound thereto in addition to substituted orthometalated ligands, both an anion chosen among cyanide, thiocyanate, cyanate, possessing strong C donor and ? acceptor properties, and a monodentate neutral ligand L, as above defined, said ligands advantageously participate in the emission process, significantly shifting emission towards higher energies (blue-shift) and enabling appreciable improvement of the emission efficiency of complexes [C?N]2M(T)(L). Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.Type: ApplicationFiled: April 3, 2007Publication date: May 7, 2009Applicant: SOLVAY (SOCIETE ANONYME)Inventors: Mohammad Khaja Nazeeruddin, Cedric Klein, Michael Graetzel
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Publication number: 20090000658Abstract: A dye sensitized solar cell, comprising a-heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated n-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring? group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.Type: ApplicationFiled: July 29, 2005Publication date: January 1, 2009Inventors: Shaik Mohammed Zakeeruddin, Cedric Klein, Peng Wang, Michael Graetzel