Abstract: Methods for etching a metal layer and a metallization method of a semiconductor device using an etching gas that includes Cl2 and N2 are provided. A mask layer is formed on the metal layer, the etching gas is supplied to the metal layer, and the metal layer is etched by the etching gas using the mask layer as an etch mask. The metal layer may be formed of aluminum or an aluminum alloy. Cl2 and N2 may be mixed at a ratio of 1:1 to 1:10. The etching gas may also include additional gases such as inactive gases or gases that include the elements H, O, F, He, or C. In addition, N2 may be supplied at a flow rate of from 45-65% of the total flow rate of the etching gas, which results in a reduction in the occurrence of micro-loading and cone-shaped defects in semiconductor devices.

Abstract: A capacitor for a semiconductor memory device is fabricated by forming a mold layer on a semiconductor substrate that includes a peripheral circuit area and a cell array area which includes a plug in a buried contact hole. A hard mask layer pattern is formed on the mold layer. The mold layer is etched, using the hard mask layer pattern as an etch mask, to form a mold layer pattern. The hard mask layer pattern is then removed from the mold layer pattern or only partially etched back on the mold layer pattern. A capacitor lower electrode is formed along the walls of the buried contact hole and on a surface of the mold layer pattern. A capacitor dielectric layer is formed on the capacitor lower electrode and a capacitor upper electrode is formed on the capacitor dielectric layer.

Abstract: A capacitor for a semiconductor memory device is fabricated by forming a mold layer on a semiconductor substrate that includes a peripheral circuit area and a cell array area which includes a plug in a buried contact hole. A hard mask layer pattern is formed on the mold layer. The mold layer is etched, using the hard mask layer pattern as an etch mask, to form a mold layer pattern. The hard mask layer pattern is then removed from the mold layer pattern or only partially etched back on the mold layer pattern. A capacitor lower electrode is formed along the walls of the buried contact hole and on a surface of the mold layer pattern. A capacitor dielectric layer is formed on the capacitor lower electrode and a capacitor upper electrode is formed on the capacitor dielectric layer.

Abstract: Methods for fabricating semiconductor devices having capacitors are provided. A plurality of storage node electrodes are formed on a semiconductor substrate. Then, a capacitor dielectric layer is formed over the storage node electrodes. A plate electrode layer is subsequently formed on the capacitor dielectric layer. A hard mask layer is then formed on the resultant structure where the plate electrode layer is formed so as to fill a gap between the adjacent storage node electrodes. The hard mask layer and the plate electrode layer are successively patterned to form a plate electrode.

Abstract: A method for manufacturing a semiconductor device placing a semiconductor substrate with a silicon oxide-containing layer thereon into a plasma reaction chamber, supplying an etching gas containing a linear octafluorobutene into the plasma reaction chamber, and etching at least a portion of the silicon oxide-containing layer by generating plasma from the etching gas.

Abstract: A self aligned contact pad in a semiconductor device and a method for forming the self aligned contact pad are disclosed. A bit line contact pad and a storage node contact pad are simultaneously formed by using a photoresist layer pattern having a T-shaped opening including at least two contact regions. An etch stopping layer is formed over a semiconductor substrate and over a transistor. An interlayer dielectric layer is then formed over the etch stopping layer. Next, the interlayer dielectric layer is planarized to have a planar top surface. A mask pattern having a T-shaped opening is then formed over the interlayer dielectric layer, exposing the active region and a portion of the inactive region. The interlayer dielectric layer and etch stopping layer are sequentially etched to reveal a top surface of the semiconductor substrate using the mask pattern, thereby forming a self aligned contact opening exposing a top surface of the semiconductor substrate. The mask pattern is then removed.

Abstract: A method of etching a platinum group metal film uses a gas mixture containing argon (Ar), oxygen (O2) and halogen gases and a method of forming a lower electrode of a capacitor uses the etching method. The gas mixture contains O2, Ar, and a third component, preferably a halogen, e.g., chlorine (Cl2) or hydrogen bromide (HBr). In the method of forming a lower electrode, a conductive film containing a metal belonging to a platinum (Pt) group is formed on a semiconductor substrate, a hard mask partially exposing the conductive film is then formed on the conductive film. Then, the exposed conductive film is dry-etched using the hard mask as an etching mask and a three-component gas mixture containing argon (Ar) and oxygen (O2), to form a conductive film pattern beneath the hard mask, and the hard mask is then removed.

Abstract: A capping film having a lower etch rate than a tungsten film is formed thereon and a photoresist layer is formed on the capping film. Preferably, the capping film is a titanium-based layer or an aluminum-based layer. After a photoresist pattern is formed by exposing and developing the photoresist film, the tungsten film is patterned by a dry etch method. During the etching of the tungsten film, the capping film reacts with the etching material to form a polymer which serves as a hard mask for the tungsten film. Preferably, the capping film also has a lower reflectivity at the exposing wavelength for the photoresist than the tungsten film, so the exposure of the photoresist may be controlled. Alternatively, or additionally, an anti-reflective film is provided between the capping film and the photoresist to further reduce the effect of the reflection of the tungsten film. Thus, patterning failures can be prevented.