Abstract: The present invention provides a bio-based succinic acid composition, a preparation method therefor, and use thereof. The bio-based succinic acid composition includes bio-based succinic acid and a readily oxidizable substance; and a content of the readily oxidizable substance in the bio-based succinic acid composition is ?0.32 mL/g. In the present invention, the bio-based succinic acid composition has a long shelf life, a small change in b value after aging, and good aging stability. Moreover, a polyester prepared from the bio-based succinic acid composition has a lower acid number, a whiter color, and a higher molecular weight.

Abstract: The present invention provides a bio-based succinic acid composition, a preparation method therefor, and a polyester prepared therefrom. The bio-based succinic acid composition includes bio-based succinic acid and a metal ion; and a mass content of the metal ion in the bio-based succinic acid composition is 10-350 ppm. In the present invention, by adopting the bio-based succinic acid composition containing the metal ion as a raw material for the polyester and controlling the content of the metal ion in the bio-based succinic acid composition within a specific range, the obtained polyester has better mechanical properties and heat retention stability.

Abstract: The present invention provides a succinic acid composition, a polyester prepared therefrom, and a polyester composite material. The succinic acid composition includes succinic acid, a compound containing a sulfate radical, and a phosphorus compound; a mass content of the sulfate radical in the succinic acid composition is 240-500 ppm; and a mass content of a phosphorus element in the succinic acid composition is 0.5-40 ppm.

Abstract: A biodegradable polyester composition, a preparation method therefor and use thereof are provided. The biodegradable polyester composition of the present invention includes a biodegradable polyester and a titanium element. Polymerizable monomers of the biodegradable polyester include: an aromatic dicarboxylic acid or an esterified product thereof, or a mixture thereof; an aliphatic dicarboxylic acid or an esterified product thereof, or a mixture thereof; a dihydroxy compound; and a chain extender. A content of the titanium element in the biodegradable polyester composition is 55-86 ppm; and an acid number of the biodegradable polyester composition is 1.10-1.96 mg KOH/g.

Abstract: An aliphatic-aromatic polyester composition, a polyester fiber, a preparation method therefor and use thereof are provided. The aliphatic-aromatic polyester composition includes the following components: i) an aliphatic-aromatic polyester based on aliphatic and aromatic dicarboxylic acids and an aliphatic dihydroxy compound; and ii) a titanium element, wherein calculated based on a weight of the aliphatic-aromatic polyester composition, a content of the titanium element is 55-88 ppm, and an acid number of the aliphatic-aromatic polyester composition is ?0.84 mg KOH/g according to the standard DIN EN 12634-1998.

Abstract: The present invention discloses a polyester, a preparation method therefor and use thereof. The polyester includes repeating units derived from the following components: a first component A, based on the total molar weight of the first component A, including: a1) 81-100 mol % of succinic acid, or an ester derivative thereof or an anhydride derivative thereof, and a2) 0-19 mol % of a dicarboxylic acid other than succinic acid, or an ester derivative thereof or an anhydride derivative thereof; a second component B: 1,4-butanediol; and a third component C: a dimer(1,4-butanediol); based on the total molar weight of the first component A, the molar content of the repeating unit —CH2CH2CH2CH2—O— in the third component C is 0.05-3.0 mol %. In the present invention, the molar content of the repeating unit —CH2CH2CH2CH2—O— in dimer(1,4-butanediol) is controlled to 0.05-3.0 mol %, and thus, the resin color of the polyester can be effectively improved.

Abstract: Disclosed are a semi-aromatic polyester, and a preparation method therefor and a use thereof. In the present invention, on the basis of the total molar amount of diacid, the molar content of a repeating unit —CH2CH2CH2CH2—O— in dimer(1,4-butanediol) is controlled to be 0.05-0.35 mol %, which can effectively improve the resin color of the semi-aromatic polyester.

Abstract: The present invention discloses a semi-aromatic polyester, and a preparation method therefor and an application thereof. The semi-aromatic polyester has a specific scope of double bond content. Compared with the existing semi-aromatic polyester, the semi-aromatic polyester of the present invention has better melting heat retention stability and fine color.

Abstract: The present invention discloses a semi-aromatic polyester, a preparation method therefor and use thereof. The content of hydroxyl in a semi-aromatic polyester is controlled, and particularly, the content of hydroxyl linked to aliphatic dicarboxylic acid in the semi-aromatic polyester is controlled to 17-40 mmol/kg, the content of hydroxyl linked to aromatic dicarboxylic acid in the semi-aromatic polyester is controlled to 17-40 mmol/kg, and the total content of hydroxyl is controlled to 35-80 mmol/kg, such that the compatibility of the semi-aromatic polyester with materials, e.g., polylactic acid can be significantly improved, thereby obtaining a high-strength tear-resistant film material.

Abstract: The present invention relates to a semi-aromatic polyether ester, a preparation method therefor and use thereof. The semi-aromatic polyether ester includes repeating units derived from the following components: a first component A, based on the total molar amount of the first component A, including: a1) 35-65 mol %, and preferably 40-60 mol % of at least one aliphatic dicarboxylic acid or an ester derivative thereof, or an anhydride derivative thereof, and a2) 35-65 mol %, and preferably 40-60 mol % of at least one aromatic dicarboxylic acid or an ester derivative thereof, or an anhydride derivative thereof; a second component B: 1,4-butanediol; and a third component C: poly(1,4-butanediol) having a molecular formula of HO—(CH2CH2CH2CH2—O)n—H, where n is an integer from 2 to 200; based on the total molar weight of the first component A, the molar content of the repeating unit-CH2CH2CH2CH2—O— in the third component C is 1.5-5.

Abstract: The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55?P?2.02. In the component (B), the talcum powder has a particle size D(50) satisfying: 1 ?m?D(50)?2.6 ?m. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180?M?670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55?P?2.

Abstract: The present invention relates to a polylactic acid 3D printing material and a preparation method thereof, which belong to the technical field of polymer materials. The polylactic acid 3D printing material of the present invention comprises the following preparation raw materials in parts by weight: (a) 40-95 parts of crystalline or semi-crystalline polylactic acid, (b) 5-60 parts of noncrystalline polylactic acid, and (c) 0-1.0 parts of a processing aid. In the polylactic acid 3D printing material, a weight of dextral polylactic acid represents 0.5%-8% of a total weight of the polylactic acid. According to the present invention, a polylactic acid 3D printing material with a good aging resistance property can be obtained, by selecting and using two kinds of polylactic acids with different optical purities as raw materials, rationally distributing the proportional relationship between the two, and defining the content of dextral polylactic acid.

Abstract: Disclosed in the present invention is a semiaromatic polyester, a preparation method and application thereof. Having a specific segment length and carboxyl group content, the semiaromatic polyester provides a balance of degradation rate and mechanical properties, compared with known semiaromatic polyesters. The 30-day weight retention of the semiaromatic polyester obtained in the present invention may be contained to from 45 to 70%.

Abstract: The present invention discloses a biodegradable polyester composition, wherein the biodegradable polyester composition comprises the following components in parts by weight: i) 58 to 80 parts by weight of an aliphatic-aromatic copolyester; ii) 20 to 32 parts by weight of starch; and iii) 0 to 10 parts by weight of a processing agent. The present invention unexpectedly found by research that by using an aliphatic-aromatic copolyester in which an amount of aromatic carboxylic acid accounts for a total amount of diacid is 44 mol % to 48 mol % as a matrix resin, where the aliphatic-aromatic copolyester has a crystallization peak width D of 5° C. to 16° C.

Abstract: The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: i) 50-85 parts by weight of polylactic acid; ii) 8 to 35 parts by weight of an inorganic filler; and iii) 0 to 8 parts by weight of a plasticizer; wherein the polylactic acid composite has an end carboxyl content of 12 to 51 molKOH/t. The present invention unexpectedly discovered through research that, by controlling an end carboxyl content of the polylactic acid composite within a range of 12 to 51 molKOH/t, the polylactic acid composite, under a condition of 60° C. and 60% humidity, with a test time of 30 days, has a ratio of a mass melt index MFIt=30 to an initial mass melt index MFIt=0 satisfying 3.5<?=MFIt=30/MFIt=0<5.1, which indicates that under the test conditions, the product has slow aging degradation, and the polylactic acid composite has a biodegradation rate greater than 90% after 12 weeks in the case where a thickness is 2.

Abstract: The present invention relates to a biodegradable polyester and use thereof, including components: A) acid components containing following repeating units: 50 to 58 mol % of terephthalic acid A1; 30 to 40 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the present invention, in the case of a high content of the terephthalic acid, the biodegradable polyester prepared by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less can satisfy the degradation performance and rigidity and improve the tenacity of the material simultaneously.

Abstract: A biodegradable polyester and use thereof includes components: A) acid components containing following repeating units: 40 to 48 mol % of terephthalic acid A1; 38.5 to 50 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the case of low content of the terephthalic acid unit, by introducing the aliphatic dibasic acid unit with the carbon chain length of 6 or less, mechanical properties of the material can be significantly improved, and the mechanical property retention is better especially when stored in a humid environment.

Abstract: A biodegradable polyester and use thereof includes components: A) acid components containing following repeating units: 40 to 48 mol % of terephthalic acid A1; 38.5 to 50 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the case of low content of the terephthalic acid unit, by introducing the aliphatic dibasic acid unit with the carbon chain length of 6 or less, mechanical properties of the material can be significantly improved, and the mechanical property retention is better especially when stored in a humid environment.

Abstract: The present invention relates to a biodegradable polyester and use thereof, including components: A) acid components containing following repeating units: 50 to 58 mol % of terephthalic acid A1; 30 to 40 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the present invention, in the case of a high content of the terephthalic acid, the biodegradable polyester prepared by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less can satisfy the degradation performance and rigidity and improve the tenacity of the material simultaneously.

Abstract: The present invention discloses a biodegradable polyester composition, wherein the biodegradable polyester composition comprises the following components in parts by weight: i) 58 to 80 parts by weight of an aliphatic-aromatic copolyester; ii) 20 to 32 parts by weight of starch; and iii) 0 to 10 parts by weight of a processing agent. The present invention unexpectedly found by research that by using an aliphatic-aromatic copolyester in which an amount of aromatic carboxylic acid accounts for a total amount of diacid is 44 mol % to 48 mol % as a matrix resin, where the aliphatic-aromatic copolyester has a crystallization peak width D of 5° C. to 16° C.