Abstract: The present disclosure relates to an additive manufacturing (AM) method for making a three-dimensional (3D) object, comprising a) depositing successive layers of a powdered material (M), at least partially recycled, comprising at least one poly(ether ketone ketone) (PEKK), having a phosphorus content of more than 30 ppm, as measured by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), and b) selectively sintering each layer prior to deposition of the subsequent layer.

Abstract: Bonding films comprising PEEK-PEoEK copolymers are compatible with polyaryletherketone chemistry thereby providing joined polyaryletherketone polymer parts with high fracture toughness and overall good mechanical properties.

Abstract: The present invention generally relates to a powder comprising a PEEK-PEoEK copolymer, wherein the PEEK-PEoEK copolymer having RPEEK and RPEoEK repeat units in a molar ratio RPEEK/RPEoEK ranging from 95/5 to 5/95. The present invention also relates to a method of preparing a three-dimensional (3D) object by sintering layers of the powder.

Abstract: The invention relates to a process for the manufacture of a cyclic oligo(arylene ether) which can be a cyclic oligo(dichloromethylene arylene ether) or a cyclic oligo(arylene ether ketone); the process comprises the step of causing an aromatic compound to react with a hexachloroxylene compound in a pseudo-high dilution environment. The invention relates also to new cyclic oligo(arylene ether)s and their use for the manufacture of acyclic poly (arylene ether)s, such as PEKK, by ring-opening polymerization.

Abstract: The present invention relates to blends of poly(ether ketone ketone) (PEKK) polymers, in particular to certain blends endowed with lower melting point than traditional PEKK polymers, yet maintaining high crystallinity and rapid crystallization behaviour, which are composed of a major amount of a first nucleophilic PEKK having a first T/I ratio, and a minor amount of a second PEKK having a second T/I ratio higher than the first T/I ratio: to methods of making the same, and to uses thereof in various fields.

Abstract: The present invention generally relates to a powder comprising a PEEK-PEoEK copolymer, wherein the PEEK-PEoEK copolymer having RPEEK and RPEoEK repeat units in a molar ratio RPEEK/RPEoEK ranging from 95/5 to 5/95. The present invention also relates to a method of preparing the powder, as well as to the uses of the powder for coating, compression molding and to prepare a three-dimensional (3D) object.

Abstract: The present invention relates to poly(ether ketone ketone) (PEKK) polymers, a method for the manufacture thereof, to articles and composites made therefrom, to methods of making the composites, and composite articles including the PEKK composites. It was surprisingly discovered that by synthesizing the PEKK polymers from low-metal monomers and selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly improved melt stability can be obtained. The PEKK composites including the PEKK polymers are especially well-suited for fabrication of thick composite parts where melt stability of the polymer matrix is important.

Abstract: The present invention relates to assembly comprising a first component and a second component, each component comprising a polymer, as well as a film positioned between and bonded to the first component and the second component. The film is such that it comprises at least one poly(ether ketone ketone) (PEKK) polymer and at least one nucleating agent. The assembly has an improved fracture toughness and overall good mechanical properties.

Abstract: The present invention relates to assembly comprising a first component and a second component, each component comprising a polymer, as well as a film positioned between and bonded to the first component and the second component. The film is such that it comprises a blend of at least two poly(ether ketone ketone) (PEKK) polymers and optionally at least one nucleating agent. The assembly has an improved fracture toughness and overall good mechanical properties.

Abstract: The present invention relates to poly(ether ketone ketone) (PEKK) polymers, a method for the manufacture thereof, to articles and composites made therefrom, to methods of making the composites, and composite articles including the PEKK composites. It was surprisingly discovered that by synthesizing the PEKK polymers from low-metal monomers and selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly improved melt stability can be obtained. The PEKK composites including the PEKK polymers are especially well-suited for fabrication of thick composite parts where melt stability of the polymer matrix is important.

Abstract: The present disclosure relates to an additive manufacturing (AM) method for making a three-dimensional (3D) object, using a part material (M) comprising at least one PEEK-PEoEK copolymer, in particular to a 3D object obtainable by Fused Deposition Modelling (FDM) or Fused Filament Fabrication (FFF) from this part material (M).

Abstract: Described herein are poly(ether ketone ketone) (“PEKK”) polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes (“traditional PEKK polymers”). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.

Abstract: A PEKK polymer powder, having a d0.9-value less than 150 ?m, wherein the PEKK polymer has a Td(1%) of at least 500° C., as measured by thermal gravimetric analysis according to ASTM D3850, heating from 30° C. to 800° C. under nitrogen using a heating rate of 10° C./min. A method for producing a PEKK powder for the use in a method for manufacturing a 3D object, in which the PEKK has a Td(1%) of at least 500° C., as measured by thermal gravimetric analysis according to ASTM D3850, heating from 30° C. to 800° C. under nitrogen using a heating rate of 10° C./min, and the powder has been manufactured by grinding from a coarser powder and has a d0.9-value less than 150 ?m, as measured by laser scattering in isopropanol.

Abstract: The present invention generally relates a composite material containing fibers and a resin matrix that comprises a PEEK-PEoEK copolymer having RPEEK and RPEoEK repeat units in a molar ratio RPEEK/RPEoEK ranging from 95/5 to 5/95 in contact with at least a part of the surface of such fibers. The present invention also relates to methods for making such composite materials, shaped articles made from such composite materials, and methods of making such articles.

Abstract: A method of making a PEEK-PEoEK copolymer having RPEEK and RPEoEK repeat units in a molar ratio RPEEK/RPEoEK ranging from 95/5 to 45/55, the PEEK-PEoEK copolymer obtained from the method and the polymer composition including the PEEK-PEoEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.

Abstract: Fiber reinforced composite material comprising a thermoplastic matrix comprising blends of poly(ether ketone ketone) (PEKK) polymers, their method of manufacture and articles obtained therefrom.

Abstract: Described herein are poly(ether ketone ketone) (“PEKK”) polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes (“traditional PEKK polymers”). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.

Abstract: A method of making a PEEK-PEmEK copolymer having RPEEK and RPEmEK repeat units in a molar ratio RPEEK/RPEmEK ranging from 95/5 to 45/55, the PEEK-PEmEK copolymer obtained from the method and the polymer composition including the PEEK-PEmEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.

Abstract: The present invention generally relates a polymer-metal junction comprising PEEK-PEoEK copolymers compositions, in contact with at least a part of the surface of a metal substrate, wherein the PEEK-PEoEK copolymer having RPEEK and RPEoEK repeat units in a molar ratio RPEEK/RPEoEK ranging from 95/5 to 5/95. The present invention also relates to shaped articles including the polymer-metal junction, and methods of making the polymer-metal junctions.

Abstract: Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added in to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures (“Tg”) and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes (“traditional PEKK polymers”). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.