Abstract: Systems and methods are provided herein for removing alternate material from a foil while minimizing the amount of alternate material particles that are deposited on the surface of an active material. For example, a web may comprise an active material on a first portion of a foil and an alternate material on a second portion of the foil. One or more brushes may be used to remove the alternate material from the second portion of the foil. As the one or more brushes remove the alternate material from the second portion of the foil, a vacuum may be used to capture the alternate material that is removed from the second portion of the foil. In such an example, the resulting web no longer has alternate material on the second portion of the foil and has reduced alternate material particles on the surface of the active material.

Abstract: Systems and methods are provided herein for applying sacrificial material to otherwise uncoated areas of a foil to provide uniform pressure during calendering. For example, one or more portions of a foil may be coated with an active material while other portions of the foil may be coated with an appropriately selected alternate material. After the active material and the alternate material are applied to the foil, the foil may be dried and then calendered. During calendering, the compressive force of the rollers can cause the portion of the foil coated in the active material to stretch a similar amount to the portions of the foil coated in the alternate material. The resulting calendered web has minimal wrinkles due to the similarity of the stretching of the foil coated in the active material and the foil coated in the alternate material.

Abstract: Provided are flexible multi-battery assemblies and methods of manufacturing these assemblies. In some examples, a flexible multi-battery assembly comprises a first current collector, parsed into a first plurality of current collector portions such that each portion contacts one of a plurality of electrochemically active stacks. The second current collector may be continuous (e.g., to provide support to the electrochemically active stacks) or similarly parsed into a second plurality of current collector portions. Each electrochemically active stack forms one of flexible electrochemical cells in the flexible multi-battery assembly. Furthermore, at least one outer surface of the first current collector or the second outer surface is fully exposed, e.g., to allow forming electrical and mechanical connections directly to one or both current collectors. In some examples, an insulator layer covers a non-exposed surface of the other current collector.

Abstract: Provided are electrochemical cells, comprising water-retaining components, and methods of fabricating such electrochemical cells. A water-retaining component is configured to deliver water to the positive active material during the operation of the electrochemical cell. The water-retaining component may be a part of the positive active material layer, a part of the electrolyte layer, and/or a standalone component. In some examples, the water-retaining component comprises one or more crystal hydrates (e.g., MgSO4, MgCl2, Na2SO4, Na2HPO4, CuSO4, CaCl2, KAl(SO4)2, and Mg(NO3)2), one or more water-retaining polymers (e.g., sodium polyacrylate, potassium polyacrylate, ammonium polyacrylate, and a cellulose derivative), one or more inorganic compounds (e.g., fumed silica, precipitated silica). In some examples, a method of forming an electrochemical cell comprises printing a positive active material layer, a negative active material layer, and an electrolyte layer, e.g.

Abstract: Provided are printed electrochemical cells, which utilize zinc salts for ionic transfer, and methods of fabricating such cells. In some examples, a printed electrochemical cell comprises a positive electrode with a positive current collector having a two-dimensional shape and comprising an electrolyte-facing surface formed by the graphite. For example, the positive current collector may be a graphite foil or an aluminum foil with a graphite coating. The cell also comprises electrolyte comprising an electrolyte salt and an electrolyte solvent. For example, the electrolyte salt comprises a zinc salt with a concentration of at least 30% by weight in the electrolyte. The cell is fabricated by printing a positive active material layer over the positive current collector, printing one or more electrolyte layers on various cell components, and laminating a separator layer between the positive and negative electrodes while soaking the separator layer with the electrolyte.

Abstract: The disclosure concerns an electrolyte, an electrolyte ink, a battery or other electrochemical cell including the same, and methods of making the electrolyte and electrochemical cell. The electrolyte includes an ionic liquid comprising a hydrophilic or hydrophobic anion, a multi-valent metal cation suitable for use in a battery cell, a polymer binder, and optional additives (e.g., a solid filler). The electrolyte ink includes components of the electrolyte and a solvent. The solvent and the polymer binder (or, when present, the solid filler) have a hydrophilicity, hydrophobicity or polarity similar to or matching that of the ionic liquid's anion, or form hydrogen bonds with the ionic liquid's anion. The electrolyte includes a solid inorganic filler that provides mechanical support form hydrogen bonds with the anion and/or a counterpart anion of the multi-valent metal cation, and links with a material in an adjacent layer of the electrochemical cell.

Abstract: The disclosure concerns an electrolyte, an electrolyte ink, a battery or other electrochemical cell including the same, and methods of making the electrolyte and electrochemical cell. The electrolyte includes an ionic liquid comprising a hydrophilic or hydrophobic anion, a multi-valent metal cation suitable for use in a battery cell, a polymer binder, and optional additives (e.g., a solid filler). The electrolyte ink includes components of the electrolyte and a solvent. The solvent and the polymer binder (or, when present, the solid filler) have a hydrophilicity, hydrophobicity or polarity similar to or matching that of the ionic liquid's anion, or form hydrogen bonds with the ionic liquid's anion. The electrolyte includes a solid inorganic filler that provides mechanical support form hydrogen bonds with the anion and/or a counterpart anion of the multi-valent metal cation, and links with a material in an adjacent layer of the electrochemical cell.

Abstract: The disclosure concerns an electrolyte, an electrolyte ink, a battery or other electrochemical cell including the same, and methods of making the electrolyte and electrochemical cell. The electrolyte includes an ionic liquid comprising a hydrophilic or hydrophobic anion, a multi-valent metal cation suitable for use in a battery cell, a polymer binder, and optional additives (e.g., a solid filler). The electrolyte ink includes components of the electrolyte and a solvent. The solvent and the polymer binder (or, when present, the solid filler) have a hydrophilicity, hydrophobicity or polarity similar to or matching that of the ionic liquid's anion, or form hydrogen bonds with the ionic liquid's anion. The electrolyte includes a solid inorganic filler that provides mechanical support form hydrogen bonds with the anion and/or a counterpart anion of the multi-valent metal cation, and links with a material in an adjacent layer of the electrochemical cell.

Abstract: Ion transport in electrochemical cells or energy storage devices may take place in metal salt-based electrolytes. The metal salt-based electrolytes may comprise high doping metal salt formulations. Electrochemical cells or energy storage devices comprising metal salt-based electrolytes may be used as single-use or rechargeable power sources.

Abstract: The disclosure concerns an electrolyte, an electrolyte ink, a battery or other electrochemical cell including the same, and methods of making the electrolyte and electrochemical cell. The electrolyte includes an ionic liquid comprising a hydrophilic or hydrophobic anion, a multi-valent metal cation suitable for use in a battery cell, a polymer binder, and optional additives (e.g., a solid filler). The electrolyte ink includes components of the electrolyte and a solvent. The solvent and the polymer binder (or, when present, the solid filler) have a hydrophilicity, hydrophobicity or polarity similar to or matching that of the ionic liquid's anion, or form hydrogen bonds with the ionic liquid's anion. The electrolyte includes a solid inorganic filler that provides mechanical support form hydrogen bonds with the anion and/or a counterpart anion of the multi-valent metal cation, and links with a material in an adjacent layer of the electrochemical cell.