Abstract: Catalyst material comprising a ternary spinel mixed oxide for treatment of an exhaust gas stream via direct decomposition removal of NOx to N2 and O2. The low temperature (from about 400° C. to about 650° C.), direct decomposition is accomplished without the need of a reductant molecule. In one example, Mn may be incorporated into metal oxide, such as CuyCo3-yO4 spinel oxide, synthesized using co-precipitation techniques.

Abstract: A catalyst for direct decomposition removal of NOx from an exhaust gas stream to N2 and O2, the catalyst comprising a dual dispersed supported metal oxide material, which comprises MOx-CuOx dispersed on a CO3O4 spinel oxide support, wherein M is selected from the group consisting of Zn, Ce, Mg, Tb, and Gd. The dual dispersed supported metal oxide catalysts have good activity and selectivity for N2.

Abstract: A catalyst for direct decomposition removal of NOx from an exhaust gas stream to N2 and O2, the catalyst comprising a dual dispersed supported metal oxide material, which comprises MOx—CuOx dispersed on a CO3O4 spinel oxide support, wherein M is selected from the group consisting of Zn, Ce, Mg, Tb, and Gd. The dual dispersed supported metal oxide catalysts have good activity and selectivity for N2.

Abstract: Catalyst material composed of a sodium incorporated cerium-zirconium based mixed oxide catalyst material, such as Ce—Zr/Al2O3, for oxygen storage capacity applications. The sodium incorporated cerium-zirconium based mixed oxide catalyst material is synthesized by co-precipitation techniques using sodium carbonate as the precipitating agent and exhibits a high oxygen storage capacity.

Abstract: Catalyst for oxygen storage capacity applications that include a zinc doped manganese-iron spinel mixed oxide material. The zinc doped manganese-iron spinel mixed oxide material may be synthesized by a co-precipitation method using a precipitation agent such as sodium carbonate and exhibits a high oxygen storage capacity.

Abstract: Catalyst for oxygen storage capacity applications that include a zinc doped manganese-iron spinel mixed oxide material. The zinc doped manganese-iron spinel mixed oxide material may be synthesized by a co-precipitation method using a precipitation agent such as sodium carbonate and exhibits a high oxygen storage capacity.

Abstract: Catalysts for passive NOx absorber to remove NOx from exhaust gas system during engine cold start operation having high storage capacity and ideal desorption properties. The catalysts may include a system having an alumina supported Pt/Ce—Zr mixed oxide catalysts material synthesized by deposition co-precipitation using a precipitation agent selected from the group consisting of ammonium hydroxide (NH4OH), ammonium carbonate ((NH4)2CO3), sodium hydroxide (NaOH), sodium carbonate (Na2CO3).

Abstract: Catalysts including multi-transition metal doped copper-cobalt spinel mixed oxide catalyst materials for direct NOx decomposition with selectivity to N2 from combustion engine exhaust, while minimizing formation of the N2O product. In one example, the catalyst may include a ternary zinc-doped copper-cobalt spinel material or a quaternary manganese+zinc doped copper-cobalt spinel material. The catalysts are effective for reducing NO to N2 at suitable temperatures of 350-500° C., with and without excess O2 presence.

Abstract: Catalysts including multi-transition metal doped copper-cobalt spinel mixed oxide catalyst materials for direct NOx decomposition with selectivity to N2 from combustion engine exhaust, while minimizing formation of the N2O product. In one example, the catalyst may include a ternary zinc-doped copper-cobalt spinel material or a quaternary manganese+zinc doped copper-cobalt spinel material. The catalysts are effective for reducing NO to N2 at suitable temperatures of 350-500° C., with and without excess O2 presence.

Abstract: Catalyst material composed of a sodium incorporated cerium-zirconium based mixed oxide catalyst material, such as Ce—Zr/Al2O3, for oxygen storage capacity applications. The sodium incorporated cerium-zirconium based mixed oxide catalyst material is synthesized by co-precipitation techniques using sodium carbonate as the precipitating agent and exhibits a high oxygen storage capacity.

Abstract: Catalyst for passive NOx absorber to remove NOx from exhaust gas system during engine cold start operation having high storage capacity and ideal desorption properties. The catalyst may include a mixed oxide catalyst system having a Pt promoted Ce0.5Zr0.5O2 catalyst material synthesized by co-precipitation using ammonium carbonate as a precipitation agent.

Abstract: Catalyst material comprising a ternary spinel mixed oxide for treatment of an exhaust gas stream via direct decomposition removal of NOx to N2 and O2. The low temperature (from about 400° C. to about 650° C.), direct decomposition is accomplished without the need of a reductant molecule. In one example, Mn may be incorporated into metal oxide, such as CuyCo3-yO4 spinel oxide, synthesized using co-precipitation techniques.

Abstract: A nitrogen oxide (NOx) reduction catalyst that includes a transition metal tungstate having the formula: MWO4 wherein M is selected from the group consisting of Mn, Fe, Co, Ni, and Cu. The catalyst may be utilized in various environments including oxygen rich and oxygen deficient environments.

Abstract: A method to predict the catalytic activity of a metal oxide of formula MxOy where x is a number from 1 to 3 and y is a number from 1 to 8 is provided. The metal of the metal oxide has redox coupled oxidation states wherein the redox transformation is between oxidation states selected from the group consisting of a diamagnetic oxidation state (Md+) and a paramagnetic oxidation state (Mp+), a paramagnetic oxidation state (Mp+) and a ferromagnetic oxidation state (Mf+), and a paramagnetic oxidation state (Mp+) and an antiferromagnetic oxidation state (Ma+)where d, p, f and a are independently numbers from 1 to 6 and one of the oxidation states (Md+), (Mp+), (Mf+), and (Ma+) is formed by reduction by the O2?. The magnetic susceptibility of the metal oxide as a sample in an oxygen environment at a specified temperature is correlated with a value of (Md+ or Mp+ or Mf+ or Ma+)/g (O2 rich).

Abstract: A nitrogen oxide (NOx) reduction catalyst that includes a transition metal tungstate having the formula: MWO4 wherein M is selected from the group consisting of Mn, Fe, Co, Ni, and Cu. The catalyst may be utilized in various environments including oxygen rich and oxygen deficient environments.

Abstract: A three-way catalytic material that reduces NOx in an oxidizing atmosphere and a process for reducing NOx in an oxidizing atmosphere. The material is a mixed metal oxide catalyst and can be made from a doped barium cerate matrix with a chemical formula of BaAyDzCe(1-y-z)O3-?, where A is a precious metal or a combination of two or more precious metals and D is at least one transition metal. The coefficient y has a value between 0.0 and 0.20, inclusive, and the coefficient z has a value between 0.0 and 0.20, inclusive, and ? has a value between 0.00 and 0.20, inclusive.

Abstract: A metal-nitric oxide electrochemical cell which is fed a gas comprising nitric oxide (NO) and at least one gas selected from the group consisting of a nitrogen oxide of formula NxOy, oxygen, water vapor, a gaseous hydrocarbon, carbon monoxide and carbon dioxide is provided. Also provided is a rechargeable battery containing the metal-nitrogen oxides electrochemical cell. A vehicle system wherein exhaust gas from a combustion engine serves as a feed of active cathode material to a metal-nitrogen oxides battery is additionally provided.

Abstract: A three-way catalytic material that reduces NOx in an oxidizing atmosphere and a process for reducing NOx in an oxidizing atmosphere. The material is a mixed metal oxide catalyst and can be made from a doped barium cerate matrix with a chemical formula of BaAyDzCe(1-y-z)O3-?, where A is a precious metal or a combination of two or more precious metals and D is at least one transition metal. The coefficient y has a value between 0.0 and 0.20, inclusive, and the coefficient z has a value between 0.0 and 0.20, inclusive, and 8 has a value between 0.00 and 0.20, inclusive.

Abstract: A metal-NxOy electrochemical cell is provided. The cell contains a partition which inhibits diffusion of NxOy+ active species from the cathode compartment to the anode compartment. Also provided is a rechargeable battery containing the metal-NxOy electrochemical cell. A vehicle system wherein NxOy from a combustion engine exhaust is fed to a metal-NxOy battery is additionally provided.

Abstract: A nitrogen oxide (NOx) reduction catalyst that includes a transition metal tungstate having the formula: MWO4 wherein M is selected from the group consisting of Mn, Fe, Co, Ni, and Cu. The catalyst may be utilized in various environments including oxygen rich and oxygen deficient environments.