Abstract: A process for making an arc tube comprises the steps of sintering an arc tube composition to form the arc tube; annealing the arc tube in a vacuum; and sealing the arc tube with at least one electrode. Preferably, the arc tube annealed according to the present process is a ceramic arc tube. The annealing of the arc tubes in a vacuum preferably occurs at a temperature of between about 1000° C. and 1500° C.

Abstract: The present invention relates to polycrystalline alumina ceramics having low transition metal impurities and methods for producing the same.

Abstract: A high transmittance polycrystalline alumina arc tube for a metal halide discharge lamp is formed by treating an alumina arc tube material having a few percent of closed porosity in a two step process, which provides a high-transmittance arc tube. An initially porous arc tube is formed by extruding or die pressing individual components of the tube from a mixture which includes powdered alumina, assembling the components into an arc tube body, and then partially sintering the components to seal them together. The two step process includes hot isostatic pressing of the partially sintered arc tube and then chemically polishing the surface of the tube. The first, pressing step involves heating the alumina arc tube in an inert atmosphere, such as argon, at a temperature of 1600 to 1900° C. and a pressure of about 700 to 2100 kg/sq.cm. for from about one to three hours. This reduces porosity in the crystalline structure.

Abstract: An arc discharge vessel having electrodes disposed therein, a fill within the discharge vessel wherein the arc discharge vessel is comprised of alumina including the following dopants in parts per million: 50≦MgO≦1500; 100≦HFO2 ≦1500; 0≦ZrO2≦700; 0≦Y2O3≦300; 0≦Sc2O3≦1000; 0≦Dy2O3≦1000; 0≦Tb2O3≦1000; with the proviso that at least 5 ppm Y2O3, Sc2O3, Dy2O3, Tb2O3, or mixtures thereof is included.

Abstract: A high transmittance polycrystalline alumina arc tube for a metal halide discharge lamp is formed by treating an alumina arc tube material having a few percent of closed porosity in a two step process, which provides a high-transmittance arc tube. An initially porous arc tube is formed by extruding or die pressing individual components of the tube from a mixture which includes powdered alumina, assembling the components into an arc tube body, and then partially sintering the components to seal them together. The two step process includes hot isostatic pressing of the partially sintered arc tube and then chemically polishing the surface of the tube. The first, pressing step involves heating the alumina arc tube in an inert atmosphere, such as argon, at a temperature of 1600 to 1900° C. and a pressure of about 700 to 2100 kg/sq.cm. for from about one to three hours. This reduces porosity in the crystalline structure.

Abstract: A high pressure discharge lamp utilizing an improved ceramic arctube. The arctube has a ceramic central portion, a first ceramic leg extending from one end of the central portion and in some embodiments a second ceramic leg extending from the other end of the central portion. The arctube has reinforcing means where one or both of the legs joins the central portion to reinforce and strengthen the connection between each leg and the central portion. The reinforcing means is preferably seal glass or a layer of seal glass adjacent a ceramic ring.

Abstract: A polycrystalline ceramic scintillator exhibiting reduced afterglow includes between about 5 and 50 mole percent Gd.sub.2 O.sub.3, between about 0.02 and 12 mole percent of either Eu.sub.2 O.sub.3 or Nd.sub.2 O.sub.3 as a rare earth activator oxide, and between about 0.003 and 0.5 mole percent of either Pr.sub.2 O.sub.3 and Tb.sub.2 O.sub.3 as an afterglow reducer. The remainder of the scintillator composition is Y.sub.2 O.sub.3. The resulting scintillator is especially useful for a radiation detector of the type having a plurality of radiation receiving channels. A scintillator body is disposed in each channel so that radiation being received therein is incident on the scintillator body and causes the body to convert the incident radiation to light energy of a predetermined wavelength. The radiation detector also includes means for converting the light energy from the scintillator into electrical signals which are proportional to the amount of radiation incident on the scintillator body.

Abstract: Transparent, polycrystalline garnet bodies having desirable properties for use as laser material, luminescent x-ray scintillator materials and other uses are produced by mixing a chloride source solution of the desired cations with a basic ammonium solution to produce a precipitate having a substantially uniform composition which can be further processed to provide the desired transparent body. This precipitate is separated from the solution, dried, thermally decomposed at a temperature in the range from 700.degree. to 1,000.degree. C., pressed to form a compact, isostatically pressed at up to 60,000 psi to provide a green, unsintered compact having a density in the vicinity of 55% of theoretic density. That green compact is then sintered in oxygen at a temperature between 1,400.degree. and 1,700.degree. C. to produce the desired transparent body. Alternatively, the compact may be sintered in oxygen at temperatures in the range from about 1,400.degree. to about 1,600.degree. C.

Abstract: Afterglow in a luminescent material in which a significant factor in afterglow is the release of holes from hole traps in the scintillator material is substantially reduced by adding cerium as a hole-trapping species to the scintillator composition which successfully competes with the hole traps in the basic scintillator composition. In gadolinium gallium garnet activated with chromium, the addition of cerium in the range of 0.2 to 0.255 weight percent reduces afterglow in this manner while exhibiting excellent stability to x-ray damage after exposure to an initial pair of x-ray pulses.

Abstract: In a computed tomography machine employing a luminescent material in a scintillator in which a significant factor in afterglow is the release of holes from hole traps in the scintillator material, afterglow in the luminescent material is substantially reduced by adding a hole-trapping species to the scintillator composition which successfully competes with the hole traps in the basic scintillator composition. For a gadolinium gallium garnet scintillator activated with chromium, the addition of cerium reduces afterglow in this manner.

Abstract: Afterglow in a luminescent material in which a significant factor in afterglow is the release of holes from hole traps in the scintillator material is substantially reduced by adding a hole-trapping species to the scintillator composition which successfully competes with the hole traps in the basic scintillator composition. In gadolinium gallium garnet activated with chromium, the addition of cerium, terbium or praseodymium reduces afterglow in this manner.

Abstract: A simplified method of forming polycrystalline translucent-to-transparent yttria-gadolinia scintillators comprises coprecipitating oxalates of the yttria-gadolinia composition, drying the oxalates at about 75.degree. C. to 125.degree. C., forming an aqueous suspension of the dried oxalates, and agitating the suspension while admixing an effective amount of an ammonium hydroxide solution to disperse agglomerations of the oxalate coprecipitates. The dispersed oxalates are calcined to substantially fully oxidize the oxalates and form an oxide powder of the yttria-gadolinia composition. The oxide powder is cold pressed to form a compact, and the compact is sintered in a reducing atmosphere or vacuum to form the polycrystalline translucent-to-transparent yttria-gadolinia scintillator.

Abstract: Selected scintillator materials provided in transparent block form for use in systems such as CT scanning systems employ a garnet host material for an activator ion which provides the desired luminescence. The garnet host material preferably includes gadolinium as one of its components in order to provide a transparent host material in bar form which has a high x-ray stopping power (where the radiation to be detected is x-ray radiation). Chromium, cerium and neodymium are preferred activator materials.

Abstract: Polycrystalline ceramic bodies having uniform transparent optical characteristics are produced by providing a green compact, presintering that compact at a temperature in the range from about 1,350.degree. C. to about 1,650.degree. C. until the closed porosity stage is reached, hot isostatic pressing the presintered compact to collapse substantially all pores disposed at grain boundaries and resintering the hot isostatically pressed compact at a temperature in the range from 1,700.degree. C.-1,950.degree. C. to cause grain growth under conditions in which pores, within those grains which are consumed by the growth of other grains, collapse as the grain boundary of the growing grain passes through the location of the pore in the smaller grain being consumed.

Abstract: An imaging X-ray sensor is composed of a linear array of microscopically small bars of polycrystalline ceramic scintillator material bonded at the bar ends to an integrated circuit photodetector array. The scintillator bars are the basic resolution elements of the detector and are less than 50 microns in width. Each bar produces a flash of light with intensity related to the X-ray flux penetrating the bar. A reflective coating covering five surfaces of the bars isolates each detector element and channels the light into the photodetector bonded to one end of the bar. A method of fabricating the detector array utilizes the machineability and good mechanical strength of scintillators such as rare earth oxides doped with rare earth activators.

Abstract: A polycrystalline ceramic scintillator is disclosed for radiographic applications which has received a controlled oxidation anneal to reduce radiation damage otherwise occuring when said scintillator is exposed to X radiation during conversion of said X radiation to the display image. The particular ceramic material treated in said manner comprises a densely sintered rare earth doped gadolinia containing metal oxide having a cubic crystal structure which has been annealed after sintering in a controlled oxygen containing atmosphere. A preferred ceramic composition comprises from about 5 mole percent up to about 50 mole percent Gd.sub.2 O.sub.3, between about 0.5 mole percent and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu.sub.2 O.sub.3 and Nd.sub.2 O.sub.3, and between about 0.0001 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr.sub.2 O.sub.3 and Tb.sub.2 O.sub.3, and the remainder of said composition being Y.sub.2 O.

Abstract: A polycrystalline body having a composition comprised of Y.sub.2-x Sr.sub.x O.sub.3-x/2 wherein x ranges from about 0.0015 to about 0.012.

Abstract: A sinterable yttrium oxide powder is produced useful for pressureless sintering a compact thereof into an optically translucent or transparent body. The yttrium oxide powder has a specified particle size range and specific surface area. It is formed by preparing yttrium oxalate hydrate powder by means of the wet chemical oxalate method, comminuting the yttrium oxalate hydrate powder to a required degree and calcining the yttrium oxalate hydrate.

Abstract: Rare-earth-doped, polycrystalline yttria-gadolinia ceramic scintillators with high density, optical clarity, uniformity, cubic structure and which are useful in the detection of x-rays, include one or more of the oxides of rare earth elements Eu, Nd, Yb, Dy, Tb, and Pr as activators. The ceramic scintillator may also include CaO, SrO, and Yb.sub.2 O.sub.3 as afterglow reducers. Sintering, sintering combined with gas hot isostatic pressing, and hot pressing methods for preparing the ceramic scintillators are also described.

Abstract: Sintering and gas hot isostatic pressing are used to prepare polycrystalline yttria-gadolinia ceramic scintillator bodies. Multicomponent powder compacts, formed by cold pressing and cold isostatic pressing, are sintered to the closed porosity stage. The density of the sintered compacts is then increased by gas hot isostatic pressing. The finished scintillator includes Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and one or more of Eu.sub.2 O.sub.3, Nd.sub.2 O.sub.3, Yb.sub.2 O.sub.3, Dy.sub.2 O.sub.3, Pr.sub.2 O.sub.3, and Tb.sub.2 O.sub.3 rare-earth activator oxides. At least one of the oxides of elements Zr, Th, and Ta is included as a transparency promoting densifying agent. At least one of CaO and SrO may be included as a light output restorer.