Abstract: A polyurethaneurea composition comprises a reaction product of at least one diisocyanate compound, a polymeric glycol, a poly(tetramethylene-co-ethyleneether) glycol comprising constituent units derived by copolymerizing tetrahydrofuran and ethylene oxide (EO) wherein the portion of the constituent units derived from ethylene oxide is present in the poly(tetramethylene-co-ethyleneether) glycol from greater than about 37 to about 70 mole percent, at least one diamine chain extender, and at least one chain terminator. The invention further relates to the use of blends of polymeric glycols and poly(tetramethylene-co-ethyleneether) glycols as the soft segment base in spandex compositions. The invention also relates to new polyurethane compositions comprising polymeric glycols and poly(tetramethylene-co-ethyleneether) glycols, and their use in spandex.

Abstract: The present invention discloses liquid quaternary ammonium salts that can be used to treat and coat the surfaces of the proppant sand or inorganic particles that are used in down-hole oil well fracturing operations as well as the containment structure and that these treated surfaces will cause water and oils to flow faster through the porous structure. These liquid quaternary ammonium salts can be chosen from a list that includes but is not limited to cocobis(2-hydroxyethyl)ethylammonium ethyl sulfate, benzylcocobis(hydroxyethyl)ammonium 2-ethylhexylsulfate, dibenzylcocobishydroxyethyl ammonium phenolsulfonate, didecyldimethyl-ammonium dodecylbenzenesulfonate and tallow-bis(2-hydroxyethyl)ethylammonium ethyl sulfate.

Abstract: An aqueous alkyd resin coating composition, comprising (a) at least one alkyd resin as a dispersed phase; (b) an emulsifier based on styrenated phenols that have been converted into reactive surfactants by first reaction with one or more equivalents of an allyl glycidyl ether to provide pendant allyl groups and then oxyalkylated and (c) water. The invention also provides a method for preparing these aqueous alkyd resin coating compositions from solvent borne alkyd compositions.

Abstract: A treatment mixture for treating biofilms on a human or animal is provided. The treatment mixture comprises: an effective amount of a salt of alkyleth sulfate defined by Formula I: R1—(OCHR2CH2)n—OSO3X1??Formula I wherein: R1 is a branched or unbranched alkyl of 8-24 carbons; R2 is hydrogen or methyl; n is an integer of 2 to 30; and each X1 is independently a counter ion; an effective amount of at least one surfactant selected from the group consisting of a salt of alkyl sulfoacetate defined by Formula II: R4OC(O)CH2SO3X2??Formula II wherein R4 is a branched or unbranched alkyl of 8-24 carbons; and X2 is a counter ion; and an effective amount of a salt of an alkyl sulfosuccinate defined by Formula III: wherein: R3 is the branched or unbranched alkyl group of an alkyl alcohol with the alcohol hydrogen replaced with the sulfosuccinate wherein the alkyl has of 8-24 carbons, more preferably 10-18 carbons and most preferably 12-14 carbons; and X is a counter ion.

Abstract: A treatment mixture for treating biofilms on a human or animal is provided. The treatment mixture comprises: an effective amount of a salt of alkyleth sulfate defined by Formula I: R1—(OCHR2CH2)n—OSO3X1 ??Formula I wherein: R1 is a branched or unbranched alkyl of 8-24 carbons; R2 is hydrogen or methyl; n is an integer of 2 to 30; and each X1 is independently a counter ion; an effective amount of at least one surfactant selected from the group consisting of a salt of alkyl sulfoacetate defined by Formula II: R4OC(O)CH2SO3X2 ??Formula II wherein R4 is a branched or unbranched alkyl of 8-24 carbons; and X2 is a counter ion; and an effective amount of a salt of an alkyl sulfosuccinate defined by Formula III: wherein: R3 is the branched or unbranched alkyl group of an alkyl alcohol with the alcohol hydrogen replaced with the sulfosuccinate wherein the alkyl has of 8-24 carbons, more preferably 10-18 carbons and most preferably 12-14 carbons; and X is a counter ion.

Abstract: The invention provides compounds having the general structure: wherein R and R? are independently selected from the group consisting of H, C1-24 alkyl, aryl, C1-24 alkylaryl, aryl(C1-24)alkyl, —C(?O)—R1 (esters), C(?O)—NHR1 (urethanes), or C(?O)—O—R1 (carbonates) wherein R1 is selected from the group consisting of C1-24 alkyl, aryl, C1-24 alkylaryl, C1-24 arylalkyl; A is an organic moiety derived from the group consisting of alkylene oxides having 4-12 carbon atoms and aryl epoxides having 8-12 carbon atoms; x=1-300; y=0-200; z=0-200; and with the proviso that R and R? can not be H or ether functionality at the same time. The compounds are useful for improving the water transport characteristics of hydrophobic surfaces.

Abstract: The invention provides a composition comprising: (a) about 0% to 99% by weight of at least one resin wherein the resin is selected from the group consisting of epoxy, latex, polyurethane, polyurea, polyspartic, or alkyd resins; (b) about 1%-99% by weight of tristyrenated phenol or distyrenated phenol; and (c) optionally about 2% to 98% by weight of an additional solvent.

Abstract: An aqueous alkyd resin coating composition, comprising (a) at least one alkyd resin as a dispersed phase; (b) an emulsifier based on styrenated phenols that have been converted into reactive surfactants by first reaction with one or more equivalents of an allyl glycidyl ether to provide pendant allyl groups and then oxyalkylated and (c) water. The invention also provides a method for preparing these aqueous alkyd resin coating compositions from solvent borne alkyd compositions.

Abstract: Waterborne coatings are described having an acceptable balance of properties both during the storage of coating, application and drying. The period in which irregularities in a freshly applied coating can be repaired without resulting in brush marks is referred to as the open time. Aqueous coatings generally employ dispersed high molecular weight polymers as binders. These binders often provide short open times when the coating is dried since the dispersed polymer particles tend to be immobilized quickly in the edge region of an applied coating. As a result, the viscosity of the coating increases rapidly, which leads to a limited window of workability. The instant invention provides additives that are not volatile but that will extend the time that the film is malleable after after it is applied without interfering with other attributes, such as the resistance of the coating to freezing while in the can prior to application.

Abstract: An aqueous alkyd resin coating composition, comprising (a) at least one alkyd resin as a dispersed phase; (b) an emulsifier based on styrenated phenols that have been converted into reactive surfactants by first reaction with one or more equivalents of an allyl glycidyl ether to provide pendant allyl groups and then oxyalkylated and (c) water. The invention also provides a method for preparing these aqueous alkyd resin coating compositions from solvent borne alkyd compositions.

Abstract: The invention provides a composition comprising reaction products from a reaction of a natural butter or natural oil such as shea butter with glycerin in the presence of a basic catalyst and wherein the reaction products retain the unsaponifiable portion of said natural butter or natural oil. The resulting reaction products are self-emulsfiable and are particularly useful in personal care, cosmetic, pharmaceutical, paper and textuile applications.

Abstract: The invention provides lubricating composition comprising: (1) a reaction product selected from the group consisting of: (a) a polyalkanoic or polyalkenoic acid derived from hydroxyfatty acids and a block copolymer selected from the group consisting of polyoxyethylene-polyoxypropylene and a reverse block copolymer of polyoxypropylene-polyoxyethylene-polyoxypropylene; (b) the reaction product of (a) with a maleic acid or anhydride; and (c) the reaction product of (a) with maleated soybean oil; and (2) at least one base oil selected from the group consisting of alkyl benzene, normal paraffin, isoparaffin, mineral oil and ?-olefin.

Abstract: The present invention provides reactive surfactants of the formula R1O—(CH2CHR2O)x—(CH2CH2O)y—(CH2CHR3O)z—R4 where R1 is either alkyl, aryl, alkylaryl, or aralkylaryl of 8-30 carbon atoms, R2 is —CH2OCH2CH?CH2 (AGE); R3 is either H, CH3, or CH2CH3; R4 is H or —SO3M or —PO3M where M is H or K, Na, NH4, NR4, alkanolamine, or other cationic species and x=2-100; y=4-200 and z=0-50.

Abstract: The present invention discloses liquid quaternary ammonium salts that can be used to treat and coat the surfaces of the proppant sand or inorganic particles that are used in down-hole oil well fracturing operations as well as the containment structure and that these treated surfaces will cause water and oils to flow faster through the porous structure. These liquid quaternary ammonium salts can be chosen from a list that includes but is not limited to cocobis(2-hydroxyethyl)ethylammonium ethyl sulfate, benzylcocobis(hydroxyethyl)ammonium 2-ethyl-hexylsulfate, dibenzylcocobishydroxyethyl ammonium phenolsulfonate, didecyldimethyl-ammonium dodecylbenzenesulfonate and tallow-bis(2-hydroxyethyl)ethylammonium ethyl sulfate.

Abstract: The invention provides a composition comprising: (a) about 0% to 99% by weight of at least one resin wherein the resin is selected from the group consisting of epoxy, latex, polyurethane, polyurea, polyspartic, or alkyd resins; (b) about 1%-99% by weight of tristyrenated phenol or distyrenated phenol; and (c) optionally about 2% to 98% by weight of an additional solvent.

Abstract: The invention provides a method for forming a TiO2-latex composite particle dispersion comprising combining an aqueous TiO2 dispersion with a latex manufactured with a phosphate-containing ethylenically unsaturated reactive surfactant. The dispersions have improved opacity or hiding.

Abstract: An aqueous alkyd resin coating composition, comprising (a) at least one alkyd resin as a dispersed phase; (b) an emulsifier based on styrenated phenols that have been converted into reactive surfactants by first reaction with one or more equivalents of an allyl glycidyl ether to provide pendant allyl groups and then oxyalkylated and (c) water. The invention also provides a method for preparing these aqueous alkyd resin coating compositions from solvent borne alkyd compositions.

Abstract: Waterborne coatings are described having an acceptable balance of properties both during the storage of coating, application and drying. The period in which irregularities in a freshly applied coating can be repaired without resulting in brush marks is referred to as the open time. Aqueous coatings generally employ dispersed high molecular weight polymers as binders. These binders often provide short open times when the coating is dried since the dispersed polymer particles tend to be immobilized quickly in the edge region of an applied coating. As a result, the viscosity of the coating increases rapidly, which leads to a limited window of workability. The instant invention provides additives that are not volatile but that will extend the time that the film is malleable after after it is applied without interfering with other attributes, such as the resistance of the coating to freezing while in the can prior to application.

Abstract: An epoxy or hardener mixture comprising (a) optionally water, (b) at least one hardener or epoxy resin, and (c) from 0.1 to 20 weight percent, based on epoxy resin of at least one distyryl phenol, tristyryl phenol or cumylphenol based additive surfactant with phosphate or sulfonate end groups having the structure R—OXn-W wherein R designates a polystyrylphenol or cumylphenol, preferentially chosen from among distyrylphenol, tristyrylphenol or cumylphenol, and mixtures thereof, and wherein OX designates ethylene oxide and/or propylene oxide. The number of groups “n” varies from 0 to 200, and W designates H, sulfate (—SO3?) or phosphate (—PO3H or —PO2—OXnR). Freeze thaw resistance and improved stability is obtained in epoxy mixtures used in dispersion form. Improved pot life and cure time is obtained using either the epoxy mixture, the hardener mixture or a combination of the two in epoxy hardener formulations.

Abstract: The invention provides aqueous coating composition having freeze thaw stability, comprising: (a) at least one latex polymer derived from at least one monomer and at least one reactive surfactant of the formula R1O—(CH2CHR2O)x—(CH2CH2O)y—(CH2CHR3O)z—R4 where R1 is either alkyl, aryl, alkylaryl, or aralkylaryl of 8-30 carbon atoms, R2 is —CH2OCH2CH?CH2 (AGE); R3 is either H, CH3, or CH2CH3; R4 is H or —SO3M or —PO3M where M is H or K, Na, NH4, NR4, alkanolamine, or other cationic species and x=2-100; y=4-200 and z=0-50.