Abstract: A process for separating and recovering hydrogen fluoride from a mixture with an organic compound especially a fluorine-containing compound by extraction with a solution of an alkali metal fluoride in hydrogen fluoride, phase separation and recovery. A process for producing a fluorine-containing organic compound by fluorinating a starting material with hydrogen fluoride and similarly recovering hydrogen fluoride from the product stream. The solution may be anhydrous or aqueous.

Abstract: Processes for separating and recovering hydrogen fluoride from a gaseous mixture of an organic compound and hydrogen fluoride are disclosed. The processes include contacting the gaseous mixture with a solution of an alkali metal fluoride in hydrogen fluoride, separating a gas phase depleted in hydrogen fluoride and containing the organic compound from a liquid phase, and recovering hydrogen fluoride from the liquid phase.

Abstract: A process for separating and recovering hydrogen fluoride from a mixture with an organic compound especially a fluorine-containing compound by extraction with a solution of an alkali metal fluoride in hydrogen fluoride, phase separation and recovery. A process for producing a fluorine-containing organic compound by fluorinating a starting material with hydrogen fluoride and similarly recovering hydrogen fluoride from the product stream. The solution may be anhydrous or aqueous.

Abstract: A process for recovery of hydrogen fluoride comprises contacting a gaseous mixture containing hydrogen fluoride and an organic compound with a solution of an alkali metal fluoride in hydrogen fluoride, separating a gas phase depleted in hydrogen fluoride and containing the organic compound from a liquid phase enriched in hydrogen fluoride, and then recovering the hydrogen fluoride from the liquid phase.

Abstract: A process for the removal of chloroalkane, chlorofluoroalkane and/or hydrofluoroalkane impurities from pentafluoroethane which comprises contacting the impure pentafluoroethane with hydrogen at elevated temperature in the presence of a hydrogenation catalyst to convert the impurity or impurities to a hydrofluoroalkane and/or a hydrocarbon and separating the resulting hydrofluoroalkane and/or hydrocarbon from the pentafluoroethane.

Abstract: A process for separating and recovering hydrogen fluoride from a mixture with an organic compound especially a fluorine-containing compound by extraction with a solution of an alkali metal fluoride in hydrogen fluoride, phase separation and recovery. A process for producing a fluorine-containing organic compound by fluorinating a starting material with hydrogen fluoride and similarly recovering hydrogen fluoride from the product stream. The solution may be anhydrous or aqueous.

Abstract: A process for the production of pentafluoroethane which comprises the steps (i) producing a composition comprising a compound of formula C.sub.2 HCl.sub.x F.sub.y in which x=1,2 or 3 and y=2,3 or 4 provided that x+y is 5, contaminated with a compound of formula C.sub.2 Cl.sub.x+1 F.sub.y, (ii) separating the compound of formula C.sub.2 HCl.sub.x F.sub.y from the compound of formula C.sub.2 Cl.sub.x+1 F.sub.y, and (iii) contacting the compound of formula C.sub.2 HCl.sub.x F.sub.y with hydrogen fluoride in the presence of a fluorination catalyst to produce pentafluoroethane is disclosed.

Abstract: A process for the removal of 1,1,2,2-tetrafluoroethane from 1,1,1,2-tetrafluoroethane which comprises contacting 1,1,1,2-tetrafluoroethane containing 1,1,2,2-tetrafluoroethane with a zeolite having a mean pore size in the range of 3.8 .ANG. an 4.8 .ANG.. The zeolite is preferably calcium chabazite.

Abstract: Process for the manufacture of pentafluoroethane ?HFC 125! by reaction of perchloroethylene with hydrogen fluoride in the vapor phase over a fluorination catalyst in a fluorination reactor with recycle of dichlorotrifluoroethane ?HCFC 123! and chlorotetrafluoroethane ?HCFC 124! to the fluorination reactor, wherein tetrafluoroethane ?HFC 134a! is also recycled to the fluorination reactor. The tetrafluoroethane and the chlorotetrafluoroethane can both be separated from the product stream in a single distillation column and recycled, together to the fluorination reactor.

Abstract: A process for the co-production of two or more hydrofluoroalkanes which comprises contacting an alkene or a halogenated alkane with hydrogen fluoride at elevated temperature in the presence of a fluorination catalyst to produce a first hydrofluoroalkane and wherein an organic precursor to a second hydrofluoroalkane is provided in the process whereby to produce a second hydrofluoroalkane in addition to the first hydrofluoroalkane. In particularly preferred embodiments of the process, the first hydrofluoroalkane is 1,1,1,2-tetrafluoroethane derived from 1-chloro-2,2,2-trifluoroethane or trichloroethylene and the second hydrofluoroalkane is one or more of pentafluoroethane, difluoromethane and 1,1,2,2-tetrafluoroethane.

Abstract: A process for the production of pentafluoroethane which comprises the steps (i) producing a composition comprising a compound of formula C.sub.2 HCl.sub.x F.sub.y in which x=1, 2 or 3 and y=2, 3 or 4 provided that x+y is 5, contaminated with a compound of formula C.sub.2 Cl.sub.x+1 F.sub.y, (ii) separating the compound of formula C.sub.2 HCl.sub.x F.sub.y from the compound of formula C.sub.2 Cl.sub.x+1 F.sub.y and (iii) contacting the compound of formula C.sub.2 HCl.sub.x F.sub.y with hydrogen fluoride in the presence of a fluorination catalyst whereby to produce pentafluoroethane.