Abstract: Compounds having two reactive functional groups are described that can be used to provide a connector group between a substrate and an amine-containing material. The first reactive functional group can be used to provide attachment to a surface of a substrate. The second reactive functional group is a N-sulfonylaminocarbonyl group that can be reacted with an amine-containing material, particularly a primary aliphatic amine, to form a carbonylimino-containing connector group. The invention also provides articles and methods for immobilizing amine-containing materials to a substrate.

Abstract: Compounds having two reactive functional groups are described that can be used to provide a connector group between a substrate and an amine-containing material. The first reactive functional group can be used to provide attachment to a surface of a substrate. The second reactive functional group is a N-sulfonylaminocarbonyl group that can be reacted with an amine-containing material, particularly a primary aliphatic amine, to form a carbonylimino-containing connector group. The invention also provides articles and methods for immobilizing amine-containing materials to a substrate.

Abstract: The present invention provides novel “patch in a bottle” technology in which a fluid composition, e.g., an aerosol spray, is applied onto a surface as a fluid, but then dries to form a covering element, such as a patch, having a tack free outer surface covering an underlying adhesive that helps adhere the patch to the substrate. The fluid compositions have a unique chemical formulation that allows such composite patches to form in situ. Specifically, the fluid compositions include a tacky component, such as an adhesive, and a film-forming, non-tacky component. The non-tacky and tacky components are selected to be immiscible with each other so that the components undergo phase separation as the fluid composition dries.

Abstract: An adhesive composition comprising a silicone free polyurea-based polymer, comprising a segmented copolymer, wherein the copolymer comprises repeating units of Formula I: wherein: each B is independently a polyvalent radical selected form a group consisting of arylene, aralkylene, cycloalkylene, polyoxyalkylene, or mixtures thereof; each D is independently selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, a phenyl group, a group that completes a ring structure that includes B to form a heterocycle, and mixtures thereof; each Z is independently a polyvalent radical having about 1 to about 20 carbon atoms; each Y is independently a polyoxyalkylene; m is an integer greater than zero; and a is zero or an integer greater than zero; and wherein the composition comprises a tackifier in an amount sufficient to provide the adhesive composition as a pressure sensitive adhesive and in an amount less than about 45 parts by weight tackifier per hundred part by we

Abstract: The present invention provides novel “patch in a bottle” technology in which a fluid composition, e.g., an aerosol spray, is applied onto a surface as a fluid, but then dries to form a covering element, such as a patch, having a tack free outer surface covering an underlying adhesive that helps adhere the patch to the substrate. The fluid compositions have a unique chemical formulation that allows such composite patches to form in situ. Specifically, the fluid compositions include a tacky component, such as an adhesive, and a film-forming, non-tacky component. The non-tacky and tacky components are selected to be immiscible with each other so that the components undergo phase separation as the fluid composition dries.

Abstract: The present invention is directed toward compositions that are chemically different after application to a substrate as compared to the composition prior to its application. A method of the invention comprises a method of transitioning a crosslinked polymer composition from a first chemical state to a second chemical state. Advantageously, compositions of the invention are relatively stable after transformation to their altered, or second, chemical state.

Abstract: The present invention provides novel “patch in a bottle” technology in which a fluid composition, e.g., an aerosol spray, is applied onto a surface as a fluid, but then dries to form a covering element, such as a patch, having a tack free outer surface covering an underlying adhesive that helps adhere the patch to the substrate. The fluid compositions have a unique chemical formulation that allows such composite patches to form in situ. Specifically, the fluid compositions include a tacky component, such as an adhesive, and a film-forming, non-tacky component. The non-tacky and tacky components are selected to be immiscible with each other so that the components undergo phase separation as the fluid composition dries.

Abstract: An essentially solventless process for preparing a hot melt-processable release material comprises the step of providing reactants to a reactor, wherein the reactants comprise at least one backbone polymer having a grafting site that is reactive with a release component to selectively form a release moiety substituent at the grafting site; and a release component that is reactive with the grafting site. The release component is used in an effective amount for imparting release properties to the resulting release material. Also disclosed are release materials preparable thereby and coated substrates comprising the release material. Advantageously, release materials of the present invention are preparable and coatable using a single extruder.

Abstract: The present invention provides polydiorganosiloxane oligourea segmented copolymers. The copolymers contain soft polydiorganosiloxane units, hard segments that are diisocyanate residues, the polydiorganosiloxane units and diisocyanate residues being connected by urea linkages, and terminal groups that are non-reactive, reactive under free radical or moisture cure conditions, or amines. The invention also provides methods of preparing the copolymers.

Abstract: The present invention provides polydiorganosiloxane oligourea segmented copolymers. The copolymers contain soft polydiorganosiloxane units, hard segments that are diisocyanate residues, the polydiorganosiloxane units and diisocyanate residues being connected by urea linkages, and terminal groups that are nonreactive, reactive under free radical or moisture cure conditions, or amines. The invention also provides methods of preparing the copolymers.

Abstract: The present invention provides novel “patch in a bottle” technology in which a fluid composition, e.g., an aerosol spray, is applied onto a surface as a fluid, but then dries to form a covering element, such as a patch, having a tack free outer surface covering an underlying adhesive that helps adhere the patch to the substrate. The fluid compositions have a unique chemical formulation that allows such composite patches to form in situ. Specifically, the fluid compositions include a tacky component, such as an adhesive, and a film-forming, non-tacky component. The non-tacky and tacky components are selected to be immiscible with each other so that the components undergo phase separation as the fluid composition dries.

Abstract: Cure-on-demand, moisture-curable compositions of one or more compounds comprising molecules having reactive silane functional groups and an acid generating material are taught herein. The acid generating material releases an acid upon exposure to heat, ultraviolet light, visible light, electron beam irradiation or microwave irradiation to initiate and accelerate the crosslinking reaction. Articles prepared using the moisture curable materials are also disclosed, as are methods of curing those materials.

Abstract: An essentially solventless process for preparing a hot melt-processable release material comprises the step of providing reactants to a reactor, wherein the reactants comprise at least one backbone polymer having a grafting site that is reactive with a release component to selectively form a release moiety substituent at the grafting site; and a release component that is reactive with the grafting site. The release component is used in an effective amount for imparting release properties to the resulting release material. Also disclosed are release materials preparable thereby and coated substrates comprising the release material. Advantageously, release materials of the present invention are preparable and coatable using a single extruder.

Abstract: Polymerizable urethane acid compounds are provided. Preferred compounds additionally comprise a hydroxy functionality. These compounds are made by reaction of hydroxy functional acid compounds with isocyanates.

Abstract: Diblock (B-A) and triblock (B-A-B) polydiorganosiloxane-polyurea block copolymers comprise non-functional polydiorganosiloxane endblock B and polyurea block A. When used to provide release coatings, the block copolymers allow for easier release compared to traditional block copolymers of the (AB).sub.n type having comparable amounts of polydiorganosiloxane. Articles incorporating the copolymers as a release material are also disclosed.

Abstract: The invention provides a radiation curable release coating composition comprising:(a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto;E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group;a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200;b has a value ranging from about 0 to about 0.

Abstract: Diblock (B-A) and triblock (B-A-B) polydiorganosiloxane-polyurea block copolymers comprise non-functional polydiorganosiloxane endblock B and polyurea block A. When used to provide release coatings, the block copolymers allow for easier release compared to traditional block copolymers of the (AB).sub.n type having comparable amounts of polydiorganosiloxane. Articles incorporating the copolymers as a release material are also disclosed.

Abstract: The invention provides a radiation curable release coating composition comprising:(a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto;E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group;a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200;b has a value ranging from about 0 to about 0.

Abstract: Block copolymers having a repeating unit comprised of polysiloxane and urea segments are prepared by copolymerizing certain diaminopolysiloxanes with diisocyanates. The invention also provides novel diaminopolysiloxanes useful as precursors in the preparation of the block copolymers and methods of making such diaminopolysiloxanes. Pressure sensitive adhesive compositions comprising the block copolymer are also provided as are sheet materials coated with the same.

Abstract: A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.