Abstract: Provided is a polyaspartic composition comprising a reaction product of a polyamine with a Michael addition receptor, a pigment, and from >0% to ?3% of a phosphoric acid ester dispersant, wherein the percentage is calculated as (weight of dispersant solids/weight of pigment solids)×100. The inventive polyaspartic compositions may be reacted with a polyisocyanate to provide coatings, adhesives, sealants, composites, castings, and films having a stable initial gloss. Also provided is a method of increasing 60° gloss in a cured polyurea or polyurethane composition, the method comprising reacting a polyisocyanate with the inventive polyaspartic composition to form a reaction product and curing the reaction product, wherein 60° gloss of the cured polyurea or polyurethane composition is ?80%. The high 60° gloss is maintained over at least one-week, and in some cases over at least four weeks, at 40° C. and 80% relative humidity.

Abstract: Low primary amine (LPA) polyaspartic esters are provided which comprise a reaction product of an aliphatic diamine and an excess of a Michael addition receptor optionally, in the presence of a C1-C10 alcohol, wherein the low primary amine (LPA) polyaspartic ester has a monoaspartate content of less than 10%. The low primary amine (LPA) polyaspartic esters of the invention may find use in slow reactivity polyurea systems and react with polyisocyanates to produce polyurea coatings, adhesives, sealants, films, composites, castings, and paints.

Abstract: A method of coating a substrate is disclosed in which a non-aqueous composition is applied to the substrate and then exposed to UV-A light until the composition is substantially cured. The non-aqueous composition comprises an unsaturated (meth)acrylate polymer or oligomer, reactive diluents, one or more photoinitators, an optional solvent or mixture of solvents, and up to 15% by weight of a flattener. A coating is formed having an 85° gloss of less than 15.

Abstract: The present invention provides a dual-cure composition containing multifunctional polyols, uretdiones, peroxide curable monomers containing unsaturation and crosslinking agents. The dual-cure composition may be used to form a high modulus material useful as the matrix in a prepreg material and in composites. The present invention also relates to methods for the production of the dual-cure composition, prepreg materials comprising the dual-cure composition and a fibrous support, and composites made from the prepreg material.

Abstract: The present invention provides a dual-cure composition containing multifunctional polyols, uretdiones, peroxide curable monomers containing unsaturation and crosslinking agents. The dual-cure composition may be used to form a high modulus material useful as the matrix in a prepreg material and in composites. The present invention also relates to methods for the production of the dual-cure composition, prepreg materials comprising the dual-cure composition and a fibrous support, and composites made from the prepreg material.

Abstract: The present invention relates to a flexible sensing material made from (a) at least one flexible polymeric layer and (b) at least one conductive, curable coating layer containing about 0.01 wt. % to about 5 wt. % of multi-walled carbon nanotubes having a diameter of greater than about 4 nm, about 10 wt. % to about 99 wt. % of an aliphatic urethane acrylate and about 0.1 wt. % to about 15 wt. % of a photoinitiator, wherein the weight percentages are based on the weight of the formulation, wherein the coating layer is curable by exposure to radiation and wherein the cured coating layer has a surface resistivity of about 102?/? to about 1010?/?. The inventive sensing material may prove useful for sensing one or more of pressure, temperature and moisture and find use in a wide variety of applications.

Abstract: The present invention provides a dual-cure composition containing multifunctional polyols, uretidiones, peroxide curable monomers containing unsaturation and crosslinking agents. The dual-cure composition may be used to form a high modulus material useful as the matrix in a prepreg material and in composites. The present invention also relates to methods for the production of the dual-cure composition, prepreg materials comprising the dual-cure composition and a fibrous support, and composites made from the prepreg material.

Abstract: The present invention provides a dual-cure composition containing multifunctional polyols, uretidiones, peroxide curable monomers containing unsaturation and crosslinking agents. The dual-cure composition may be used to form a high modulus material useful as the matrix in a prepreg material and in composites. The present invention also relates to methods for the production of the dual-cure composition, prepreg materials comprising the dual-cure composition and a fibrous support, and composites made from the prepreg material.

Abstract: Novel ketal compounds can be made from an oxocarboxylate and a triol. Novel polymeric structures are, in turn, synthesized from the ketal compounds. Such ketal compounds and associated polymers are useful in a broad range of applications as a substitute for materials derived from petroleum or other such nonrenewable resources.

Abstract: A process of producing a low gloss coating curing the coating using UV-A radiation.

Abstract: The present invention relates to a flexible sensing material made from (a) at least one flexible polymeric layer and (b) at least one conductive, curable coating layer containing about 0.01 wt. % to about 5 wt. % of multi-walled carbon nanotubes having a diameter of greater than about 4 nm, about 10 wt. % to about 99 wt. % of an aliphatic urethane acrylate and about 0.1 wt. % to about 15 wt. % of a photoinitiator, wherein the weight percentages are based on the weight of the formulation, wherein the coating layer is curable by exposure to radiation and wherein the cured coating layer has a surface resistivity of about 102?/? to about 1010?/?. The inventive sensing material may prove useful for sensing one or more of pressure, temperature and moisture and find use in a wide variety of applications.

Abstract: The present invention provides a conductive, curable coating made from about 0.01 wt. % to about 5 wt. %, of multi-walled carbon nanotubes, having a diameter of greater than about 4 nm, about 10 wt. % to about 99 wt. % of an aliphatic urethane acrylate and about 0.1 wt. % to about 15 wt. % of a photoinitiator, wherein the coating is curable by exposure to radiation and wherein the cured coating has a surface resistivity of about 102?/? to about 1010?/?. A process for the production of such coatings is also provided. There are many applications where carbon nanotubes in a radiation curable coating may enhance properties other than conductivity, such as physical and thermal properties.

Abstract: Novel ketal compounds can be made from an oxocarboxylate and a triol. Novel polymeric structures are, in turn, synthesized from the ketal compounds. Such ketal compounds and associated polymers are useful in a broad range of applications as a substitute for materials derived from petroleum or other such nonrenewable resources.

Abstract: The invention relates to polyketal compounds. The compounds are synthesized by the selective ketalization of oxocarboxylic acids, e.g. keto acids and semialdehydes, and esters thereof with tetrols and higher polyols that products two or more cyclic ketal ester moieties per molecule, wherein the cyclic ketal moieties are situated in a bis-, tris-, or polyketal conformation. The invention further relates to applications of these compounds and subsequent reactions thereof.