Patents by Inventor Charles U. Pittman, Jr.

Charles U. Pittman, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20140073827
    Abstract: A method for producing biofuel and other hydrocarbons from bio-oil is disclosed. The method does not require the use of hydrogen derived from fossil fuel.
    Type: Application
    Filed: September 9, 2013
    Publication date: March 13, 2014
    Applicant: MISSISSIPPI STATE UNIVERSITY
    Inventors: Philip H. Steele, Sanjeev K. Gajjela, Todd Mlsna, Charles U. Pittman, JR., Fei Yu
  • Patent number: 8603199
    Abstract: This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: December 10, 2013
    Assignee: Mississippi State University
    Inventors: Philip H. Steele, Charles U. Pittman, Jr., Leonard L. Ingram, Jr., Sanjeev Gajjela, Zhijun Zhang, Priyanka Bhattacharya
  • Publication number: 20110192072
    Abstract: This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
    Type: Application
    Filed: October 1, 2010
    Publication date: August 11, 2011
    Applicant: MISSISSIPPI STATE UNIVERSITY
    Inventors: Philip H. Steele, Charles U. Pittman, JR., Leonard L. Ingram, JR., Sanjeev Gajjela, Zhijun Zhang, Priyanka Bhattacharya
  • Patent number: 7820285
    Abstract: Provided is a solid rocket motor (SRM) insulation, wherein carbon nano fibers (CNF) are blended into a polyurethane matrix so as to disperse the CNF in the polymer. The so blended material is then extruded, injection molded or sprayed on or into the desired shape. Such SRM insulation has reduced ablation over prior art insulations, resulting in reduction in weight of the insulation needed in such rockets, permitting increase of payload therein.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: October 26, 2010
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Charles U. Pittman, Jr., Rusty L. Blanski, Joseph H. Koo, Patrick N. Ruth, Shawn H. Phillips
  • Publication number: 20090011967
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Application
    Filed: June 17, 2008
    Publication date: January 8, 2009
    Inventors: Wai Mun Lee, Charles U. Pittman, JR., Robert J. Small
  • Patent number: 7387130
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: June 17, 2008
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 7144849
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: December 5, 2006
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 7051742
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: May 30, 2006
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 6319885
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: June 26, 2000
    Date of Patent: November 20, 2001
    Assignee: EKC Technologies, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 6110881
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: August 29, 2000
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 5911835
    Abstract: A (method using a composition) for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: June 15, 1999
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 5254665
    Abstract: Ammeline-melamine-formaldehyde resins (AMFR) containing from 5-100% ammeline were synthesized by the polymerization of the sodium salt of ammeline, which must be made in advance, melamine, and formaldehyde in basic medium (pH=9.2-10.0). In this copolymerization, it is possible to make uniform random AMFR resins with any mole ratio of ammeline salt to melamine. Preferably the AMFR resin will contain from 5-10% ammeline. As an "ionomer" or a "polyelectrolyte," both the solid and solution properties of these resins (such as melting temperature, solubility, solution stability, etc.) depended directly on the mole ratio of ammeline to melamine and formaldehyde, and/or on the pH value of the medium in which the AMFR resin was present. The pH value controlled the ammeline rings/ammeline's salt groups and also the ratio of unprotonated to protonated amino groups on both the melamine and ammeline rings.
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: October 19, 1993
    Assignee: Melamine Chemicals, Inc.
    Inventors: George M. Crews, Shen Ji, Charles U. Pittman, Jr., Ruicheng Ran
  • Patent number: 5081302
    Abstract: The selective ring-alkylation of anilines comprising providing a mixture of a lower alkanol and an aniline, exposing said mixture to a temperature of from 300.degree. C. to 500.degree. C., preferably from 350.degree. C. to 450.degree. C., in the presence of an acidic Y-type zeolite is described. The Y-type zeolites are predominantly selective to the formation of para-alkylanilines.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: January 14, 1992
    Assignee: First Chemical Corporation
    Inventors: Arthur C. Bayer, Charles U. Pittman, Jr., Lichang Wang, Earl G. Alley, Anthony C. Maliyackel
  • Patent number: 5030759
    Abstract: The selective N-alkylation of anilines comprising providing a mixture of a lower alkanol and an aniline, exposing said mixture to a temperature of from 250.degree. C. to 350.degree. C. in the presence of an acidic zeolite having a pore size of from 6 to 8 angstroms with a three-dimensional tubular shape, such as S-115 zeolite, is described. These zeolites are predominantly selective to the formation of N-alkylanilines.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: July 9, 1991
    Assignee: First Chemical Corporation
    Inventors: Arthur C. Bayer, Charles U. Pittman, Jr., Lichang Wang, Earl G. Alley, Anthony C. Maliyackel
  • Patent number: 4377719
    Abstract: A process for preparing 1,7-octadiene by dimerizing butadiene in the presence of a catalytic amount of palladium acetate and a tertiary phosphine, a solvent in an amount sufficient to dissolve the catalyst, a strong base and formic acid, wherein: (a) the molar ratio of the strong base to the formic acid is 1:1-2, (b) the mole ratio of tertiary phosphine to palladium is at least 1, (c) the amount of strong base present is such that the pH of the reaction medium is from 7.5 to 10.5 and (d) the solvent is at least one member selected from the group consisting of aromatic hydrocarbons, lower alkyl substituted aromatic hydrocarbon, halogenated aromatic hydrocarbons, halogenated lower aliphatic hydrocarbons, nitriles, amides, dilower alkyl ethers, lower alkyl phenyl ethers, lower alkyl esters of lower alkanoic acids, ketones and lower alkanols.
    Type: Grant
    Filed: December 13, 1978
    Date of Patent: March 22, 1983
    Assignee: Charles U. Pittman, Jr.
    Inventors: Charles U. Pittman, Jr., Ronald Hanes
  • Patent number: 4304840
    Abstract: A method is disclosed of delineating a desired integrated circuit pattern upon a circuit substrate. According to the method, the copolymer poly(methyl alpha-chloroacrylate-co-methacrylonitrile) is formed by emulsion polymerization techniques. The copolymer is then dissolved in a spinning solvent that will dissolve the copolymer and form a viscous solution. The solution is applied to the surface of the substrate and the substrate spinned to form a smooth, uniform resist film of about 0.3 to 1.0 micron in thickness. The resist film is heated and the region of the resist film to be patterned then exposed to ionizing radiation until exposures greater than 1.5.times.10.sup.-5 C/cm.sup.2 are obtained. The exposed regions of the resist are then developed to the substrate.
    Type: Grant
    Filed: May 22, 1980
    Date of Patent: December 8, 1981
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: John N. Helbert, Charles U. Pittman, Jr.
  • Patent number: 4258206
    Abstract: A solid supported catalyst useful in the carbonylation of olefins represented by the formula ##STR1## wherein Resin- represents a cross-linked solvent swellable high molecular weight resin; X represents a halide; m+n=4. A method for the carbonylation of .alpha.-olefins using the above-mentioned solid-supported catalyst.
    Type: Grant
    Filed: July 16, 1979
    Date of Patent: March 24, 1981
    Assignee: The University of Alabama
    Inventors: Charles U. Pittman, Jr., Quock Y. Ng
  • Patent number: 4243829
    Abstract: A process for preparing 1,7-octadiene by dimerizing butadiene in the presence of a catalytic amount of palladium acetate and a tertiary phosphine, a solvent in an amount sufficient to dissolve the catalyst, a strong base and formic acid, wherein: (a) the molar ratio of the strong base to the formic acid is 1:1-2, (b) the mole ratio of tertiary phosphine to palladium is at least 1, (c) the amount of strong base present is such that the pH of the reaction medium is from 7.5 to 10.5 and (d) the solvent is at least one member selected from the group consisting of aromatic hydrocarbons, lower alkyl substituted aromatic hydrocarbons, halogenated aromatic hydrocarbons, halogenated lower aliphatic hydrocarbons, nitriles, amides, dilower alkyl ethers, lower alkyl phenyl ethers, lower alkyl esters of lower alkanoic acids, ketones and lower alkanols.
    Type: Grant
    Filed: October 4, 1976
    Date of Patent: January 6, 1981
    Assignee: Charles U. Pittman, Jr.
    Inventors: Charles U. Pittman, Jr., Ronald Hanes