Abstract: The present invention relates to an anticorrosion layer and a manufacturing method thereof, wherein the anticorrosion layer is capable of being coated onto the surface of a substrate for preventing the substrate surface from corrosion, the anticorrosion layer comprises: a polymer material layer, coated on the substrate surface; and a continuous rough surface layer, formed on the surface of the polymer material layer, wherein the continuous rough surface layer has a surface roughness great than 10 nm. Moreover, through the manufacturing method, a protective layer (the anticorrosion layer) with excellent anticorrosion efficiency and low pollution property can be rapidly and massively formed on the substrate surface by way of using a replica mold.