Abstract: Compositions comprising enzyme compositions are provided. Also provided are methods of treating virgin fiber and recycled wastepaper containing mineral oils using the compositions comprising enzyme compositions. The mineral oils generally originate from wastepapers with mineral oil based inks and certain other hydrocarbon-based chemistries used during the manufacturing, paperboard converting, and packaging process. The enzymes break down or modify mineral oils present in the fiber and paper, mobilize and liberate them from the fibers, and increase removal of mineral oils during paper recycling, pulping and papermaking processes. The method results in the break down or modification of mineral oil components in wastepaper, recycled pulp, and paper products by the enzyme compositions so that the mineral oils can be more efficiently detached and removed.

Abstract: Wood pulp is treated with an esterase formulation in combination with a metal ion or cationic polymer to increase the stability or activity or both of esterase enzymes at high temperature, or at extreme pH ranges of acidic and alkaline conditions. The treatment by esterase together with metals ion or cationic polymer can be used to treat pitch containing pulp at high temperatures prior to, during or after refining of wood chip/pulp, in order to enhance the reduction of pitch problems and facilitate in the manufacture of paper.

Abstract: Wood pulp is treated with an esterase formulation in combination with a metal ion or cationic polymer to increase the stability or activity or both of esterase enzymes at high temperature, or at extreme pH ranges of acidic and alkaline conditions. The treatment by esterase together with metals ion or cationic polymer can be used to treat pitch containing pulp at high temperatures prior to, during or after refining of wood chip/pulp, in order to enhance the reduction of pitch problems and facilitate in the manufacture of paper.

Abstract: Compositions comprising enzyme compositions are provided. Also provided are methods of treating virgin fiber and recycled wastepaper containing mineral oils using the compositions comprising enzyme compositions. The mineral oils generally originate from wastepapers with mineral oil based inks and certain other hydrocarbon-based chemistries used during the manufacturing, paperboard converting, and packaging process. The enzymes break down or modify mineral oils present in the fiber and paper, mobilize and liberate them from the fibers, and increase removal of mineral oils during paper recycling, pulping and papermaking processes. The method results in the break down or modification of mineral oil components in wastepaper, recycled pulp, and paper products by the enzyme compositions so that the mineral oils can be more efficiently detached and removed.

Abstract: The present invention provides sol-gel germania-coated chromatography separation columns with improved stability under extreme pHs and high temperatures. Also provided are methods of preparation and uses of the sol-gel germania-coated separation columns of the present invention.

Abstract: Method for controlling the deposition of organic contaminants from the pulp and papermaking systems using water soluble aminoplast ether copolymers is described herein. The aminoplast ether copolymer can be used alone or in combination with one or more additives. The pulps to be treated include mechanical, chemical, semi-chemical pulps; sulfide pulp; recycled old newspapers; mixed office wastes; corrugated boxes; and their combinations. The use of water soluble aminoplast ether copolymers to control or prevent pitch and stickies deposition improves down stream performance of papermaking equipment increasing mill efficiency and improving paper quality.

Abstract: Methods are provided for determining the surface fatty acid content in a wood pulp or whitewater sample. The methods comprise reacting free fatty acids which are present on the surface of the wood pulp fibers in the sample or in the whitewater with one or more reagents to form a measurable species, and determining the fatty acid content from the quantitative measurement of the measurable species. The method is useful as a quick, portable, accurate and low cost assay for assessing the fatty acid content present at various sample points in pulp and paper mills. The method for determining the free fatty acid content can be conducted in a batch process (e.g., where samples are collected periodically and the test is conducted offline). Alternatively, the method for determining the free fatty acid content can be conducted in a continuous or semi-continuous process (e.g., online sampling/analysis).

Abstract: Method for controlling the deposition of organic contaminants from the pulp and papermaking systems using water soluble aminoplast ether copolymers is described herein. The aminoplast ether copolymer can be used alone or in combination with one or more additives. The pulps to be treated include mechanical, chemical, semi-chemical pulps; sulfide pulp; recycled old newspapers; mixed office wastes; corrugated boxes; and their combinations. The use of water soluble aminoplast ether copolymers to control or prevent pitch and stickies deposition improves down stream performance of papermaking equipment increasing mill efficiency and improving paper quality.

Abstract: Formulations for pitch control, and methods of making and using thereof, are described herein. The formulations contains one or more 1,3-selective lipases. 1,3-selective lipases catalyze the hydrolysis of the terminal ester groups in triglycerides leaving the internal ester group intact. The enzyme formulations can contain one or more additives, such as dispersants, metal ions, absorbents, adsorbents, cationic polymers, and combinations thereof. The enzyme formulation is typically applied as a solution to the pulp stock. The enzyme formulations can be applied at any of one or more various points during the pulping and paper manufacturing processes. The use of selective lipase(s) decreases the total concentration of fatty acids in the system, and catalyzes the formation of monoglycerides, which are more effective at dispersing fatty acids than glycerol, the product of non-selective lipases, thereby improving pulp and paper machine runnability and pulp and paper quality.

Abstract: Wood pulp is treated with an esterase formulation in combination with a metal ion or cationic polymer to increase the stability or activity or both of esterase enzymes at high temperature, or at extreme pH ranges of acidic and alkaline conditions. The treatment by esterase together with metals ion or cationic polymer can be used to treat pitch containing pulp at high temperatures prior to, during or after refining of wood chip/pulp, in order to enhance the reduction of pitch problems and facilitate in the manufacture of paper.

Abstract: Methods are provided for determining the surface fatty acid content in a wood pulp or whitewater sample. The methods comprise reacting free fatty acids which are present on the surface of the wood pulp fibers in the sample or in the whitewater with one or more reagents to form a measurable species, and determining the fatty acid content from the quantitative measurement of the measurable species. The method is useful as a quick, portable, accurate and low cost assay for assessing the fatty acid content present at various sample points in pulp and paper mills. The method for determining the free fatty acid content can be conducted in a batch process (e.g., where samples are collected periodically and the test is conducted offline). Alternatively, the method for determining the free fatty acid content can be conducted in a continuous or semi-continuous process (e.g., online sampling/analysis).

Abstract: Methods are provided for determining the surface fatty acid content in a wood pulp or whitewater sample. The methods comprise reacting free fatty acids which are present on the surface of the wood pulp fibers in the sample or in the whitewater with one or more reagents to form a measurable species, and determining the fatty acid content from the quantitative measurement of the measurable species. The method is useful as a quick, portable, accurate and low cost assay for assessing the fatty acid content present at various sample points in pulp and paper mills. The method for determining the free fatty acid content can be conducted in a batch process (e.g. where samples are collected periodically and the test is conducted offline). Alternatively, the method for determining the free fatty acid content can be conducted in a continuous or semi-continuous process (e.g., online sampling/analysis).

Abstract: Methods of treating pulp stocks with an enzyme formulation containing one or more oxidative enzymes, to reduce pitch deposition, control pitch related problems, modify the physical and/or chemical properties of tri, di-, and mono-glycerides, fatty acids, resin acids, esters of fatty acids and resin acids, and metal soaps of fatty acids and resin acids, or change the concentration of triglycerides, fatty acids, resin acids, and esters of fatty acids and resin acids, have been developed. The pulp stock is treated with an enzyme formulation containing laccases, peroxidases, esterases, and/or combinations thereof. The enzyme formulations may also contain a laccase mediator and/or a dispersant. The enzyme formulation can be applied at any of several locations during the pulping and/or papermaking process. The enzyme formulation is typically applied as a solution to the pulp stock. The enzyme treatment is effective at a temperature of between about 30° C. to about 95° C., more preferably from about 50° C.

Abstract: Enzymatic methods are provided for determining the surface triglycerides content in a sample of wood pulp. The methods preferably comprise reacting triglycerides which are present on the surface of the wood pulp fibers in the sample in the presence of a lipase to form glycerol and fatty acids, and then determining the difference between the amount of free glycerol present in the sample and the amount of glycerol formed from said triglycerides. The method is useful as a quick, portable, accurate, and low cost assay for assessing the amount of triglycerides present at various sample points in pulp and paper mills, which advantageously serves as a diagnostic tool for use in controlling the undesirable deposition of pitch during the papermaking process.

Abstract: Enzymatic methods are provided for determining the surface triglycerides content in a sample of wood pulp. The methods preferably comprise reacting triglycerides which are present on the surface of the wood pulp fibers in the sample in the presence of a lipase to form glycerol and fatty acids, and then determining the difference between the amount of free glycerol present in the sample and the amount of glycerol formed from said triglycerides. The method is useful as a quick, portable, accurate, and low cost assay for assessing the amount of triglycerides present at various sample points in pulp and paper mills, which advantageously serves as a diagnostic tool for use in controlling the undesirable deposition of pitch during the papermaking process.

Abstract: Enzymatic methods are provided for determining the surface triglycerides content in a sample of wood pulp. The methods preferably comprise reacting triglycerides which are present on the surface of the wood pulp fibers in the sample in the presence of a lipase to form glycerol and fatty acids, and then determining the difference between the amount of free glycerol present in the sample and the amount of glycerol formed from said triglycerides. The method is useful as a quick, portable, accurate, and low cost assay for assessing the amount of triglycerides present at various sample points in pulp and paper mills, which advantageously serves as a diagnostic tool for use in controlling the undesirable deposition of pitch during the papermaking process.