Abstract: The disclosure provides a method for preparing an amphiphilic lignin nanomaterial based on pulping black liquor, an amphiphilic lignin nanomaterial, and an oil sludge detergent. In the disclosure, physical treatments such as ball milling and high-pressure jet homogenization treatment are conducted on alkali lignin at the early stage to adjust the molecular weight and size of alkali lignin and thus to give alkali lignin nanoparticles with uniform particle sizes; and on this basis, a chemical treatment such as alkylation grafting modification is conducted to give amphiphilic lignin nanoparticles with both hydrophilicity and lipophilicity. Due to the nano-size effect, the amphiphilic lignin nanomaterial has a significantly-increased specific surface area (SSA) and effectively-improved surface properties, which can reduce the oil-water interfacial tension, and emulsify the crude oil and peel off the crude oil from the surface of rock particles, so as to achieve the purpose of oil-solid separation.

Abstract: The disclosure provides a method for preparing an amphiphilic lignin nanomaterial based on pulping black liquor, an amphiphilic lignin nanomaterial, and an oil sludge detergent. In the disclosure, physical treatments such as ball milling and high-pressure jet homogenization treatment are conducted on alkali lignin at the early stage to adjust the molecular weight and size of alkali lignin and thus to give alkali lignin nanoparticles with uniform particle sizes; and on this basis, a chemical treatment such as alkylation grafting modification is conducted to give amphiphilic lignin nanoparticles with both hydrophilicity and lipophilicity. Due to the nano-size effect, the amphiphilic lignin nanomaterial has a significantly-increased specific surface area (SSA) and effectively-improved surface properties, which can reduce the oil-water interfacial tension, and emulsify the crude oil and peel off the crude oil from the surface of rock particles, so as to achieve the purpose of oil-solid separation.

Abstract: A phosphorus-based calcification inhibitor (“inhibitor”) configured to prevent calcification of anaerobic granular sludge.

Abstract: The present disclosure provides a fast and high-capacity intelligent cellulose-based oil-absorbing material and a preparation method and use thereof. The material includes an intelligent response layer and an adsorption layer. The intelligent response layer is a pH-responsive nanofiber layer with an adjustable pH response performance and is obtained by grafting hyperbranched polycarboxylic acid-modified polyethyleneimine on to carboxylated cellulose nanofibers. The hyperbranched polycarboxylic acid is prepared by melting and polycondensing at a high temperature, using trimethylolpropane as a core, citric acid as a reactive monomer, and p-toluenesulfonic acid as a catalyst. The adsorption layer is prepared by coating ferroferric oxide with the carboxylated cellulose nanofibers to prepare magnetic carboxylated cellulose nanofibers, and then modifying the magnetic carboxylated cellulose nanofibers with hexadecylamine.

Abstract: The present invention discloses a biomass intelligent fiber-based amphoteric multifunctional adsorptive material and a preparation method and use thereof. The material is obtained by using a stepwise dual-temperature stimuli-responsive biomass intelligent fiber as a matrix, a crown ether-modified amphoteric hyperbranched polyamine as a functional reagent, and by using a crosslinking agent to directly crosslink and combine the stepwise dual-temperature stimuli-responsive biomass intelligent fiber with the crown ether-modified amphoteric hyperbranched polyamine in one step. The material has a stepwise dual-temperature stimuli-response, high densities of amino group (more than 12 mmol/g) and carboxyl group (5 mmol/g), and nano cavities.

Abstract: The present invention discloses a near-infrared regenerative intelligent fiber-based adsorptive material and a preparation method and use thereof. The material is obtained by chemically grafting a stepwise dual-temperature stimuli-responsive polyethyleneimine onto a carboxylated cellulose nanofiber matrix to prepare a stepwise dual-temperature stimuli-responsive intelligent nanofiber, and combining the stepwise dual-temperature stimuli-responsive intelligent nanofiber with a photosensitizer having near-infrared stimuli-response to prepare a stepwise dual-temperature/near-infrared stimuli-responsive intelligent nanofiber, and then by using a crosslinking agent to directly crosslink and combine the stepwise dual-temperature/near-infrared stimuli-responsive intelligent nanofiber with a hyperbranched polyamine in one step. The material has a stepwise dual-temperature/near-infrared stimuli-response, high density of amino group (greater than 14 mmol/g), and nano cavities.

Abstract: The present invention belongs to the technical field of wastewater treatment, and particularly relates to a method for pre-conditioning high-calcium wastewater by calcification blocking, and a device for implementing the method. The method for treating high-calcium wastewater by calcification blocking includes mixing high-calcium wastewater, an alkalizing agent and a chelating agent, and carrying out alkalizing conditioning pretreatment under a condition of stirring by bubbling of a biogas, so as to obtain pre-conditioned wastewater. The pre-conditioned wastewater is mixed with anaerobic granular sludge, and an anaerobic reaction is performed in a high hydraulic shear flow field formed by the biogas, so as to generate the biogas and calcium scale. A part of the biogas for the stirring is refluxed by bubbling of the biogas and the rest of the biogas is refluxed for forming the high hydraulic shear flow field.

Abstract: Embodiments of the present invention pertain to a composite decalcification agent of calcified anaerobic granular sludge and a decalcification regeneration process.

Abstract: A method may add whey to high calcium papermaking industrial wastewater blended and pre-acidification treatment to promote anaerobic reaction and inhibit calcification. The method includes, before anaerobic treatment of papermaking wastewater, mixing whey wastewater with the papermaking wastewater. The method also includes pre-treating the papermaking wastewater by acidification to stabilize the papermaking wastewater prior to entering an anaerobic reaction system.

Abstract: A phosphorus-based calcification inhibitor (“inhibitor”) configured to prevent calcification of anaerobic granular sludge.

Abstract: Embodiments of the present invention pertain to a composite decalcification agent of calcified anaerobic granular sludge and a decalcification regeneration process.

Abstract: A method may add whey to high calcium papermaking industrial wastewater blended and pre-acidification treatment to promote anaerobic reaction and inhibit calcification. The method includes, before anaerobic treatment of papermaking wastewater, mixing whey wastewater with the papermaking wastewater. The method also includes pre-treating the papermaking wastewater by acidification to stabilize the papermaking wastewater prior to entering an anaerobic reaction system.

Abstract: A graphene ternary composite direct current-carrying plate includes an anode plate and a cathode plate. Placed between the anode plate and the cathode plate is a graphene composite layer. The graphene composite layer is doped with a certain proportion of graphene in the aluminum mesh frame. The plate of the invention has small thickness, low ohmic voltage drop, good porosity, and low current loss. This reduces the electrolysis power consumption, thereby significantly reducing the product cost and effectively promoting the industrial production market of the sodium chlorate electrolysis method. The plate also reduces energy consumption and is environmentally friendly.

Abstract: The patent provides a method for preparing titanium-based active electrodes with high stability coating layer, which belongs to the field of electrochemistry. The patent describes the active electrode is used titanium as the substrate, multi-metal oxides as the activated catalytic layer, and dense oxides as the protective layer. The multi-metal catalytic layer is formed by pyrolysis method to form the main body of titanium-based catalytic layer, and the dense oxide protective layer is combined with Sol-gel method and electrochemical deposition method to form a dense protective layer of titanium base. It can be widely used in chlor-alkali industry, paper industry, sewage treatment and other fields.

Abstract: A high-purity chlorine dioxide gas may use hydrogen peroxide as a reducing agent and may use horizontal generator, evaporation crystallizer, dryer and other devices to produce chlorine dioxide gas (product) and sodium sulfate (by-product). Compared to the conventional chlorine dioxide preparation system, the chlorine dioxide reaction and the sodium sulfate crystallization are performed in two processes. These processes are relatively separate and independent, and continuously produce chlorine dioxide gas with high purity and low moisture content while the by-product salt cake is evaporated, crystallized, filtered and dried, thereby producing sodium sulfate, without generating solid and liquid waste.

Abstract: A high-purity chlorine dioxide gas may use hydrogen peroxide as a reducing agent and may use horizontal generator, evaporation crystallizer, dryer and other devices to produce chlorine dioxide gas (product) and sodium sulfate (by-product). Compared to the conventional chlorine dioxide preparation system, the chlorine dioxide reaction and the sodium sulfate crystallization are performed in two processes. These processes are relatively separate and independent, and continuously produce chlorine dioxide gas with high purity and low moisture content while the by-product salt cake is evaporated, crystallized, filtered and dried, thereby producing sodium sulfate, without generating solid and liquid waste.

Abstract: An efficient electrolysis system for sodium chlorate production may include round or oval cells, reactors, a product pump transfer, a buffer tank, a circulation pump, and explosive clad plate, all of which are connected by way of pipelines. Inlet and the outlet of each cell are separately connected with the reactor via titanium pipes, allowing the electrolyte to recirculate naturally between the cells and the reactors. The outlet of every cell is conical while each reactor includes a standard electrolytic unit with three to eight cells. The electrolytic units are modularly identical and symmetrically linked to the buffer tank. Within each unit, adjacent cells are connected with the explosive clad plates. The buffer tank may be divided into two parts—part A and part B—with part A connecting with the overflow port of the reactor via pipeline, and the part B connecting with the reactor via the circulation pump.

Abstract: An efficient electrolysis system for sodium chlorate production may include round or oval cells, reactors, a product pump transfer, a buffer tank, a circulation pump, and explosive clad plate, all of which are connected by way of pipelines. Inlet and the outlet of each cell are separately connected with the reactor via titanium pipes, allowing the electrolyte to recirculate naturally between the cells and the reactors. The outlet of every cell is conical while each reactor includes a standard electrolytic unit with three to eight cells. The electrolytic units are modularly identical and symmetrically linked to the buffer tank. Within each unit, adjacent cells are connected with the explosive clad plates. The buffer tank may be divided into two parts—part A and part B—with part A connecting with the overflow port of the reactor via pipeline, and the part B connecting with the reactor via the circulation pump.

Abstract: An efficient electrolysis system for sodium chlorate production may include round or oval cells, reactors, a product pump transfer, a buffer tank, a circulation pump, and explosive clad plate, all of which are connected by way of pipelines. Inlet and the outlet of each cell are separately connected with the reactor via titanium pipes, allowing the electrolyte to recirculate naturally between the cells and the reactors. The outlet of every cell is conical while each reactor includes a standard electrolytic unit with three to eight cells. The electrolytic units are modularly identical and symmetrically linked to the buffer tank. Within each unit, adjacent cells are connected with the explosive clad plates. The buffer tank may be divided into two parts—part A and part B—with part A connecting with the overflow port of the reactor via pipeline, and the part B connecting with the reactor via the circulation pump.

Abstract: An efficient electrolysis system for sodium chlorate production may include round or oval cells, reactors, a product pump transfer, a buffer tank, a circulation pump, and explosive clad plate, all of which are connected by way of pipelines. Inlet and the outlet of each cell are separately connected with the reactor via titanium pipes, allowing the electrolyte to recirculate naturally between the cells and the reactors. The outlet of every cell is conical while each reactor includes a standard electrolytic unit with three to eight cells. The electrolytic units are modularly identical and symmetrically linked to the buffer tank. Within each unit, adjacent cells are connected with the explosive clad plates. The buffer tank may be divided into two parts—part A and part B—with part A connecting with the overflow port of the reactor via pipeline, and the part B connecting with the reactor via the circulation pump.