Abstract: A production method for a laminate of a fluorosilicone rubber and a silicone rubber is provided. The production method comprises the following steps: (1) curing a fluorosilicone rubber composition comprising: (A) an organopolysiloxane having alkenyl groups and fluoroalkyl groups, (B) an organopolysiloxane having silicon atom-bonded hydrogen atoms and fluoroalkyl groups, and (C) a hydrosilylation reaction catalyst; (2) laminating a silicone rubber composition comprising: (D) an organopolysiloxane having alkenyl groups and not having fluoroalkyl groups, and (E) an organic peroxide on a surface of a fluorosilicone rubber produced in step (1) above; and (3) curing a silicone rubber composition layer in a laminate produced in step (2) above. A laminate in which a fluorosilicone rubber layer and a silicone rubber layer are adhered well using a hydrosilylation reaction curable fluorosilicone rubber composition is produced.

Abstract: Provided is a method of producing a fluorosilicone rubber laminate. The method comprises: (1) applying a primer composition onto a substrate, and forming a primer layer on a surface of the substrate; and (2) bringing a fluorosilicone rubber composition into contact with the primer layer, and adhering a fluorosilicone rubber to the primer layer. The fluorosilicone rubber composition comprises a platinum-based catalyst and/or a fluorosiloxane containing a silicon atom-bonded hydrogen atom. The primer composition comprises a platinum-based catalyst or a fluorosiloxane containing a silicon atom-bonded hydrogen atom, however the primer composition does not simultaneously comprise a platinum-based catalyst and a fluorosiloxane containing a silicon atom-bonded hydrogen atom. Either the primer composition or the fluorosilicone rubber composition comprises a platinum-based catalyst or a fluorosiloxane containing a silicon atom-bonded hydrogen atom.

Abstract: A silicone rubber composition is provided. The silicone rubber composition comprises: (A) an organopolysiloxane having at least 2 alkenyl groups per molecule, and not having fluoroalkyl groups or having fluoroalkyl groups in a proportion of less than 20 mol % of all silicon atom-bonded organic groups; (B) an organopolysiloxane having at least 2 silicon atom-bonded hydrogen atoms per molecule along with fluoroalkyl groups in a proportion of at least 5 mol % of all silicon atom-bonded organic groups; and (C) a hydrosilylation reaction catalyst. The silicone rubber composition forms a silicone rubber to which a fluorosilicone rubber composition adheres well. Manufacturing methods are also provided, where laminates in which a fluorosilicone rubber layer and a silicone rubber layer adhere well are manufactured.

Abstract: A production method for a laminate of a fluorosilicone rubber and a silicone rubber is provided. The production method comprises the following steps: (1) curing a fluorosilicone rubber composition comprising: (A) an organopolysiloxane having alkenyl groups and fluoroalkyl groups, (B) an organopolysiloxane having silicon atom-bonded hydrogen atoms and fluoroalkyl groups, and (C) a hydrosilylation reaction catalyst; (2) laminating a silicone rubber composition comprising: (D) an organopolysiloxane having alkenyl groups and not having fluoroalkyl groups, and (E) an organic peroxide on a surface of a fluorosilicone rubber produced in step (1) above; and (3) curing a silicone rubber composition layer in a laminate produced in step (2) above. A laminate in which a fluorosilicone rubber layer and a silicone rubber layer are adhered well using a hydrosilylation reaction curable fluorosilicone rubber composition is produced.

Abstract: The present invention relates to a curable silicone rubber composition for various types of water supply components used in contact with water. The present invention also relates to a cured product of this composition, a water resistant cured silicone rubber, and use thereof. The present invention imparts good water resistance to a silicone rubber component used in contact with water, and the present invention prevents or decreases the occurrence of whitening or similar visual appearance failures, and the occurrence of insufficient strength to withstand high temperature steam.

Abstract: A heat resistant silicone rubber composition containing greater than or equal to 0.1 mass % each of titanium oxide and iron oxide is disclosed. The heat resistant silicone rubber composition can form a heat resistant silicone rubber suitable for use in a high temperature environment. A method of reducing formaldehyde and/or low molecular weight organopolysiloxane generated from a cured product of a heat resistant silicone rubber composition upon heating the cured product is also disclosed. The method comprises compounding greater than or equal to 0.1 mass % each of titanium oxide and iron oxide in the heat resistant silicone rubber composition. Generally, even when the cured product is heated to a high temperature, such as a temperature greater than or equal to 300° C., generation of formaldehyde and/or low molecular weight organopolysiloxane (e.g. D4, D5, and D6) from the cured product can be reduced.

Abstract: The present invention relates to a glycerin derivative-modified organopolysiloxane elastomer comprising: as a hydrophilic group, a glycerin derivative group in which an average number of repetitions of glycerin units is in a range of 1.0 to 2.4, being free of an oxyalkylene structure having an average number of repetitions of an oxyalkylene unit of 2 or higher; and a crosslinked three-dimensional net-like structure having a carbon-silicon bond in a crosslinking part.

Abstract: A heat resistant silicone rubber composition containing greater than or equal to 0.1 mass % each of titanium oxide and iron oxide is disclosed. The heat resistant silicone rubber composition can form a heat resistant silicone rubber suitable for use in a high temperature environment. A method of reducing formaldehyde and/or low molecular weight organopolysiloxane generated from a cured product of a heat resistant silicone rubber composition upon heating the cured product is also disclosed. The method comprises compounding greater than or equal to 0.1 mass % each of titanium oxide and iron oxide in the heat resistant silicone rubber composition. Generally, even when the cured product is heated to a high temperature, such as a temperature greater than or equal to 300° C., generation of formaldehyde and/or low molecular weight organopolysiloxane (e.g. D4, D5, and D6) from the cured product can be reduced.

Abstract: A curable silicone composition comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa·s to not more than 50,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass % to less than 3.5 mass %; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst. The curable composition provides a highly transparent cured silicone material that has a hardness in the range from at least 30 to not more than 80, a parallel light transmittance at 25° C. of at least 90%, and a parallel light transmittance at 200° C. that is at least 99% of the parallel light transmittance at 25° C.

Abstract: A curable silicone composition comprises (A) (A-1) an alkenyl-containing dialkylpolysiloxane and a viscosity of at least 1,000 mPa·s to not more than 20,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl, that contains from 2.5 to 5.0 mass % alkenyl group, and that has a ratio for the total number of moles of R12R2SiO1/2 and R13SiO1/2 units to 1 mole of the SiO4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass % silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst. The curable composition provides a bending-tolerant and highly transparent cured silicone material that has a hardness in the range from 80 to 95, and a parallel light transmittance at 200° C. of a value that is at least 99% of the parallel light transmittance at 25° C.

Abstract: The present invention relates to a glycerin derivative-modified organopolysiloxane elastomer comprising: as a hydrophilic group, a glycerin derivative group in which an average number of repetitions of glycerin units is in a range of 1.0 to 2.4, being free of an oxyalkylene structure having an average number of repetitions of an oxyalkylene unit of 2 or higher; and a crosslinked three-dimensional net-like structure having a carbon-silicon bond in a crosslinking part.

Abstract: The present invention relates to an organopolysiloxane elastomer having a silicon-bonded sugar alcohol-modified group and having a crosslinked three-dimensional network structure comprising a carbon-silicon bond in the crosslinking portion. The organomodified organopolysiloxane elastomer of the present invention has, for example, affinity with various oil agents, has excellent viscosity-improving characteristics, gelification characteristics, and emulsification characteristics, imparts excellent tactile sensation—in particular, an excellent tactile sensation characterized by smoothness with a velvet-like thickness—and imparts an excellent sensation during use.

Abstract: A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25° C. viscosity in the range of 5,000 to 35,000 mPa·s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO4/2 units, R12R2SiO1/2 units, and R13SiO1/2 units (where R1 designates alkyl groups with 1 to 10 carbon atoms, and R2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R12R2SiO1/2 units and R13SiO1/2 units to 1 mole of the SiO4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.

Abstract: The present invention relates to a curable silicone rubber composition for various types of water supply components used in contact with water. The present invention also relates to a cured product of this composition, a water resistant cured silicone rubber, and use thereof. The present invention imparts good water resistance to a silicone rubber component used in contact with water, and the present invention prevents or decreases the occurrence of whitening or similar visual appearance failures, and the occurrence of insufficient strength to withstand high temperature steam.

Abstract: A thermosetting silicone rubber composition that contains a cerium oxide powder in an amount of 0.001 to 10 mass % and that is characterized by total transmittance of light equal to or greater than 90% according to JIS K7105 when the light is passed through a 1 mm-thick layer of an alkenyl-containing dimethylpolysiloxane gum with 0.1 mass % of said cerium oxide powder dispersed in the gum.

Abstract: A curable silicone composition comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa·s to not more than 50,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass % to less than 3.5 mass %; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst. The curable composition provides a highly transparent cured silicone material that has a hardness in the range from at least 30 to not more than 80, a parallel light transmittance at 25° C. of at least 90%, and a parallel light transmittance at 200° C. that is at least 99% of the parallel light transmittance at 25° C.

Abstract: A curable silicone composition comprises (A) (A-1) an alkenyl-containing dialkylpolysiloxane and a viscosity of at least 1,000 mPa·s to not more than 20,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl, that contains from 2.5 to 5.0 mass % alkenyl group, and that has a ratio for the total number of moles of R12R2SiO1/2 and R13SiO1/2 units to 1 mole of the SiO4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass % silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst. The curable composition provides a bending-tolerant and highly transparent cured silicone material that has a hardness in the range from 80 to 95, and a parallel light transmittance at 200° C. of a value that is at least 99% of the parallel light transmittance at 25° C.

Abstract: A curable silicone rubber composition comprises (A) an alkenyl-containing organopolysiloxane comprising (A-1) a dialkylpolysiloxane that has an average of at least two alkenyl groups in each molecule and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is C1-10 alkyl and R2 is alkenyl and that contains the alkenyl group in the range from more than 2.5 mass % to not more than 5.0 mass %; (B) an organopolysiloxane that contains the silicon-bonded hydrogen atom; and (C) a hydrosilylation reaction catalyst in a catalytic quantity. The curable composition provides a cured silicone material that has a hardness of not more than 75 and an elongation of at least 35%. Also, a composite in which the cured silicone material provided by the thermosetting of the curable composition is integrated into a single article with a substrate.

Abstract: A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25° C. viscosity in the range of 5,000 to 35,000 mPa·s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO4/2 units, R12R2SiO1/2 units, and R13SiO1/2 units (where R1 designates alkyl groups with 1 to 10 carbon atoms, and R2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R12R2SiO1/2 units and R13SiO1/2 units to 1 mole of the SiO4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.

Abstract: Disclosed is a thermosetting silicone rubber composition containing 0.001-10% by mass of a cerium oxide powder. This thermosetting silicone rubber composition is characterized in that when 0.1% by mass of the cerium oxide powder is dispersed in an alkenyl group-containing dimethylpolysiloxane raw rubber, the total light transmittance according to JIS K7105 through the resulting rubber having a thickness of 1 mm is not less than 90%; This thermosetting silicone rubber composition is excellent in thermal stability during production or in the uncured state, and enables to obtain a silicone rubber having excellent heat resistance after curing.