Abstract: A method for making a multilayer interconnect electronic component structure, and, in particular, an integrated circuit semiconductor device made using a copper damascene method is provided. The process of the invention uses a method for pre-cleaning exposed copper surfaces in the structure. The method employs a cleaning composition containing a nitrogen containing material and an oxygen containing material and also optionally a hydrogen containing material to remove the copper oxide film on copper surfaces in the structure. The preferred nitrogen material is nitrogen gas and the preferred oxygen material is oxygen gas. The gas mixture is preferably energized to form a plasma which is used to contact and remove the copper oxide and clean the structure. A two-step process may be used employing a nitrogen/oxygen mixture and then a hydrogen containing gas mixture such as Ar/H2.

Abstract: A substrate having a conductive layer is provided. A dielectric layer is then formed above the conductive layer. At least one via hole is then formed in the dielectric layer, to expose a portion of the conductive layer. The conductive layer is then covered with a gap fill polymer layer, to completely fill the via hole. A chemical mechanical polishing step is performed to remove the partial gap fill polymer layer on the outside of the via hole. An etching step, is performed to remove a portion of partial gap fill polymer layer remaining in the via hole, resulting in a partial gap fill polymer. A lithographic process is conducted to form a patterned photoresist layer over the dielectric layer. The photoresist layer has an opening that exposes the via hole and partial gap fill polymer. A portion of the dielectric layer exposed by the opening is etched away, to form a trench in the dielectric layer.

Abstract: A substrate having a conductive layer is provided. A dielectric layer is then formed above the conductive layer. At least one via hole is then formed in the dielectric layer, to expose a portion of the conductive layer. The conductive layer is then covered with a gap fill polymer layer, to completely fill the via hole. A chemical mechanical polishing step is performed to remove the partial gap fill polymer layer on the outside of the via hole. An etching step, is performed to remove a portion of partial gap fill polymer layer remaining in the via hole, resulting in a partial gap fill polymer. A lithographic process is conducted to form a patterned photoresist layer over the dielectric layer. The photoresist layer has an opening that exposes the via hole and partial gap fill polymer. A portion of the dielectric layer exposed by the opening is etched away, to form a trench in the dielectric layer.

Abstract: A method for forming a damascene opening in a polymer-based dielectric layer is introduced. The method includes providing a substrate, which has also a conductive structure layer and a polymer-based dielectric layer formed thereon already. The polymer-based dielectric layer is uniformly hardened by a thermal treatment. A mask layer is formed on the polymer-based dielectric layer. The mask layer and the polymer-based dielectric layer are patterned to form an opening. The opening exposes a surface of the polymer-based dielectric layer. The exposed surface of the polymer-based dielectric layer is further hardened by a local hardening process. The local hardening process includes using an irradiation source of a high energy light beam, electron beam or ion beam to proceed the local hardening. The irradiation source can be incident onto the substrate by vertical angle or inclining angle. The substrate can also be rotated.

Abstract: A method for forming a damascene opening in a polymer-based dielectric layer is introduced. The method includes providing a substrate, which has also a conductive structure layer and a polymer-based dielectric layer formed thereon already. The polymer-based dielectric layer is uniformly hardened by a thermal treatment. A mask layer is formed on the polymer-based dielectric layer. The mask layer and the polymer-based dielectric layer are patterned to form an opening. The opening exposes a surface of the polymer-based dielectric layer. The exposed surface of the polymer-based dielectric layer is further hardened by a local hardening process. The local hardening process includes using an irradiation source of a high energy light beam, electron beam or ion beam to proceed the local hardening. The irradiation source can be incident onto the substrate by vertical angle or inclining angle. The substrate can also be rotated.

Abstract: A fabrication method is offered for shallow trench isolation structures. The insulating layer is deposited in trenches and on a mask layer on a substrate. The thickness of the insulating layer in the trenches is between the depth of the trenches and the depth of the trenches plus the thickness of the mask layer. Then, the thin layer is formed on the insulating layer. The screen layer is formed on the thin layer above the trenches to protect the thin layer when the thin layer and the insulating layer above active areas are removed. Next, the thin layer above the trenches and the mask layer are removed.

Abstract: A method of planarizing an oxide layer. The method includes performing an isotropic chemical dry etching operation using a nitrogenous processing gas. Furthermore, oxygen can also be added to the nitrogenous processing gas during the isotropic chemical dry etching operation. In addition, the nitrogenous processing gas can be nitrogen or a nitrogen-oxygen compound, where the nitrogen-oxygen compound can be nitrogen monoxide, nitrogen dioxide or nitrous oxide.

Abstract: A method of forming a multiple layer damascene structure. A substrate comprising of a multi-layered stack that includes, from bottom to top, a metallic layer, a first etching stop layer, a first dielectric layer, a second etching stop layer and a second dielectric layer is provided. A photoresist layer having large area openings and vias pattern is formed over the substrate. Large area openings and vias that expose a portion of the first etching stop layer are formed in the substrate. A barrier layer that fills all the large area openings and vias is formed over the substrate. Chemical-mechanical polishing is conducted to remove a portion of the barrier layer and expose the second dielectric layer. A second photoresist having a trench pattern thereon is formed over the substrate. Using the second photoresist as a mask, etching is conducted so that the second etching stop layer around the vias is exposed. Lastly, the barrier layer is removed.

Abstract: A method for planarizing a polysilicon layer is described. A polysilicon layer is etched with an oxygen-based gas and a halogen-based gas. The oxygen-based gas comprises an nitrogen oxide oxygen gas. The nitrogen oxide gas includes NO, NO2, N2O, or the combination thereof. The halogen-based gas includes a F, Cl, Br., I, NF3, SF6, Cl2, HCl, SiCl4, fluorocarbon, or a combination thereof. The fluorocarbon includes CF4, CHF3, CH2F2, CH3F, or the like.

Abstract: A method of protecting a tungsten plug from corroding. After a tungsten plug is formed in a substrate, a wire is formed on the substrate to couple with the tungsten plug. The substrate is dipped into an electrolyte solution. The electrolyte solution is acid or alkaline enough to discharge charges accumulated on the wire. Then, a wet cleaning process is performed to remove polymer formed on the wire.

Abstract: A method of forming a shallow trench isolation structure is described. A mask layer and a photoresist layer with an opening are formed on a substrate in sequence. The photoresist layer serves as an etching mask, and then a portion of the mask layer and a portion of the substrate are etched to form a trench in the substrate. A portion of the photoresist layer is removed, and the opening is in-situ widened. Then, a portion of the mask layer exposed by the widened opening is removed. In addition, a top corner of the trench is rounded after removing the portion of the mask layer. Finally, the trench is filled with an insulation material to form a shallow trench isolation structure.

Abstract: A method of forming a via. A stacked structure has a barrier layer and a metal line is formed over a substrate. Spacers capable of serving as a barrier are formed over tapering sidewalls of the stacked structure before vias and plugs are formed.

Abstract: A method of planarizing an oxide layer. The method includes performing an isotropic chemical dry etching operation using a nitrogenous processing gas. Furthermore, oxygen can also be added to the nitrogenous processing gas during the isotropic chemical dry etching operation. In addition, the nitrogenous processing gas can be nitrogen or a nitrogen-oxygen compound, where the nitrogen-oxygen compound can be nitrogen monoxide, nitrogen dioxide or nitrous oxide.

Abstract: A method of manufacturing the floating gate of a stacked-gate type of nonvolatile memory unit. A gate oxide layer and a polysilicon layer are sequentially formed over a substrate. The polysilicon layer is etched to form a floating gate above the gate oxide layer. During the polysilicon etching operation, a polymeric material is also deposited on the sidewalls of the floating gate and over the exposed gate oxide. An isotropic chemical dry etching of the floating gate is carried out so that its bottom section is slightly wider than its top section. Finally, a thermal oxidation operation is carried out to form an oxide layer over the floating gate.

Abstract: A method of reducing a chemical mechanical polishing (CMP) dishing effect. A plurality of trenches are formed in the substrate, while a first insulating layer, such as silicon oxide layer is formed on the substrate to fill those trenches. A chemical reaction, such as nitridation reaction, is performed on the surface of the insulating layer to form a second insulating layer, which is harder than the first insulating layer. CMP is then performed.

Abstract: A method for forming a T-shaped contact plug is disclosed. A first insulating layer is formed atop of a substrate. A second insulating layer is then formed atop of the first insulating layer. The first and second insulating layers are patterned and etched to form a contact opening to the substrate. A portion of the second insulating layer surrounding the contact opening is removed. Next, a barrier metal layer is formed along the walls of the contact opening and atop the second insulating layer. Then a conducting layer is formed into the contact opening and atop the barrier metal layer. Finally, a portion of the first conducting layer and barrier metal layer atop the second insulating layer is removed. This leaves a plug formed of the remaining portion of the conducting layer.

Abstract: A method of forming trench type DRAM capacitor. An insulation layer is formed on a substrate with a trench exposing a conductive region of the substrate. A first conductive layer is formed and conformal to a surface profile of the substrate. A photoresist layer is formed over the first conductive layer to fill the trench. A three-stage of etching process is carried out. A first stage of etching step is carried out to remove a portion of the photoresist layer, thereby exposing the first conductive layer. A second stage step is carried out to remove the first conductive layer by performing an isotropic dry etching step. The first conductive layer is slightly over-etched so that a portion of the first conductive layer inside the trench is also removed. Therefore, the first conductive layer inside the trench will be at a distance lower than a top surface of the insulation layer.

Abstract: A method of forming hemispherical grain (HSG) silicon is disclosed. The method comprises the steps of: forming a doped amorphous silicon layer on a substrate; seeding and annealing the amorphous silicon layer until HSG silicon is formed; enlarging the HSG silicon grains during the annealing stage; and performing a chemical dry etch on the HSG silicon to remove an undoped silicon layer from the surface of the HSG silicon.

Abstract: A method of fabricating a landing pad. A gate electrode is formed on a substrate. The gate electrode has a top surface covered by a cap layer and a sidewall covered by a spacer. A polysilicon layer is formed to cover the gate. Using an oxygen based etchant to performed an isotropic chemical dry etching on the polysilicon layer, the polysilicon layer is planarized until a part of the spacer is exposed. The polysilicon layer is patterned to form a landing pad in contact with the substrate.