Abstract: Disclosed is an electrical steel sheet with an insulating coating formed by applying a surface-treatment agent to at least one surface of the electrical steel sheet and drying the surface-treatment agent, wherein the surface-treatment agent contains: certain trialkoxysilane and/or dialkoxysilane (A); a silane coupling agent (B) that does not contain a polymerizable unsaturated group in its structure; plate-like silica (C); a polymerizable unsaturated-group-containing compound (D); and water, within a range satisfying the following conditions (1) to (3): (1) a mass ratio (A/B) of (A) to (B) is from 0.05 to 1.00; (2) a content of (C) is 2 mass % to 30 mass % with respect to a total mass of (A) to (D) in the surface-treatment agent; and (3) a content of (D) is 2 mass % to 18 mass % with respect to the total mass of (A) to (D) in the surface-treatment agent.

Abstract: A non-oriented electrical steel sheet produced by hot-rolling a steel slab containing Si: 2.8 to 6.5 mass % and Zn: 0.0005 to 0.0050 mass % followed by cold rolling and finish annealing, a coating agent containing at least one element from Sn, Sb, P, S, Se, As, Te, B, Pb, and Bi is applied to the surface after annealing forming an insulation coating with nitriding-suppressing ability. Alternatively, an intermediate layer containing at least one element from Sn, Sb, P, S, Se, As, Te, B, Pb, and Bi and having a nitriding-suppressing ability forms on the steel sheet iron matrix after the annealing and forms an insulation coating, without above elements, on the intermediate layer thus obtaining a non-oriented electrical steel sheet wherein a high strength rotor core with and stator core with excellent magnetic is simultaneously obtained, and a motor core including a stator core and rotor core from the steel sheet.

Abstract: An electromagnetic steel sheet coated with an insulating film with excellent hardness and suitable for use as a material for iron cores of large-sized electric-power generators; and a process for producing the electromagnetic steel sheet coated with an insulating film. The purpose is achieved with a coating material for forming insulating films, the coating material including a solvent and components (A) to (C) contained therein in the respective amounts on a solid basis. (A) A water-compatible carboxylated resin; 100 parts by mass. (B) An aluminum-containing oxide; more than 40 parts by mass but less than 300 parts by mass per 100 parts by mass of the component (A). (C) At least one crosslinking agent selected from the group containing of melamine, isocyanates, and oxazoline; 100 parts by mass or more but less than 300 parts by mass per 100 parts by mass of the component (A).

Abstract: An electrical steel sheet having excellent coating peel resistance that can be exhibited during a stamping process, so that sticking of the coating to a die is inhibited. The electrical steel sheet has an insulating coating disposed on at least one surface of the electrical steel sheet. The insulating coating (i) includes a composite comprising P and Al, (ii) has an aspect ratio in a range of 1 to 10, and (iii) has a thickness in a range of 500 nm to 2000 nm. The composite has a particle diameter in a range of 10 nm to 1000 nm.

Abstract: An electrical steel sheet provided with an insulating coating wherein the insulating coating is formed by a method includes forming an insulating coating on an electrical steel sheet, including: preparing a treatment solution that does not contain an Fe compound by adding an Si compound to water; applying the treatment solution to a surface of the electrical steel sheet; leaving the treatment solution on the surface of the electrical steel sheet to allow Fe in the electrical steel sheet to be dissolved in the treatment solution; and baking the treatment solution to form the insulating film such that a coating weight of Si in the insulating coating in terms of SiO2 is 50% to 99% of the total coating weight, and a ratio (Fe/Si) of content of Fe to content of Si in the insulating coating is 0.01 to 0.6 on a molar basis.

Abstract: Provided is a method of manufacturing an electrical steel sheet with an adhesive insulating coating that has excellent high-temperature adhesive property and high-temperature oil resistance and, even after being stacked and subjected to stress relief annealing, has excellent magnetic properties (iron loss, magnetic flux density). The method comprises: applying a coating material to at least one side of an electrical steel sheet, the coating material containing (a) an aqueous epoxy resin, (b) a high-temperature hardening crosslinking agent in an amount of 30 parts by mass or less with respect to 100 parts by mass of the aqueous epoxy resin, in terms of solid content, (c) metal oxide particles, and (d) a solvent; and baking the coating material applied to the electrical steel sheet, under a condition of a peak steel sheet temperature of 150° C. or more and less than 230° C.

Abstract: A method for forming an insulating coating on an electrical steel sheet is provided. The method includes preparing a treatment solution by adding a Si compound to water and applying the treatment solution to a surface of the electrical steel sheet. Fe in the electrical steel sheet dissolves in the treatment solution and, thereafter, the electrical steel sheet and treatment solution are baked to form the insulating film. In the insulating film, a coating weight of Si in terms of SiO2 is 50% to 99% of the total coating weight, and a ratio (Fe/Si) of content of Fe to content of Si in the insulating coating is 0.01 to 0.6 on a molar basis.

Abstract: An electrical steel sheet with an insulating film having excellent chromium elution resistance, even in the case where the insulating film is baked by utilizing rapid heating, which improves productivity, and a method for manufacturing the steel sheet. The insulating film contains Fe, Cr, an organic resin, and an organic reducing agent on at least one surface of an electrical steel sheet. A ratio of the Fe content to the Cr content (Fe/Cr) is 0.010 to 0.6 in terms of molar ratio in the insulating film.

Abstract: Provided is a method of manufacturing an electrical steel sheet with an adhesive insulating coating that has excellent high-temperature adhesive property and high-temperature oil resistance and, even after being stacked and subjected to stress relief annealing, has excellent magnetic properties (iron loss, magnetic flux density). The method comprises: applying a coating material to at least one side of an electrical steel sheet, the coating material containing (a) an aqueous epoxy resin, (b) a high-temperature hardening crosslinking agent in an amount of 30 parts by mass or less with respect to 100 parts by mass of the aqueous epoxy resin, in terms of solid content, (c) metal oxide particles, and (d) a solvent; and baking the coating material applied to the electrical steel sheet, under a condition of a peak steel sheet temperature of 150° C. or more and less than 230° C.

Abstract: The disclosure provides an electrical steel sheet with an insulating coating excellent in both punchability and powdering resistance, without any chromium compound being contained in the insulating coating. The electrical steel sheet with an insulating coating includes an electrical steel sheet and an insulating coating formed on the electrical steel sheet. The insulating coating contains Si and particulate organic resin. The organic resin contains primary particles having an average primary particle size of 1.0 ?m or less, and 5% or more and 50% or less of the primary particles of the organic resin are agglomerated particles.

Abstract: A method for forming an insulating coating on an electrical steel sheet is provided. The method includes preparing a treatment solution by adding a Si compound to water and applying the treatment solution to a surface of the electrical steel sheet. Fe in the electrical steel sheet dissolves in the treatment solution and, thereafter, the electrical steel sheet and treatment solution are baked to form the insulating film. In the insulating film, a coating weight of Si in terms of SiO2 is 50% to 99% of the total coating weight, and a ratio (Fe/Si) of content of Fe to content of Si in the insulating coating is 0.01 to 0.6 on a molar basis.

Abstract: An electrical steel sheet is provided with insulating coating. The insulating coating contains Si and Fe. The coating weight of Si in the insulating coating in terms of SiO2 is 50% to 99% of the total coating weight. The ratio (Fe/Si) of the content of Fe to the content of Si in the insulating coating is 0.01 to 0.6 on a molar basis. The ratio (C (the organic resin+the lubricant)/(Fe2O3+SiO2)) of the coating weight of the organic resin and/or the lubricant in terms of C to the sum of the coating weight of Fe in terms of Fe2O3 and the coating weight of Si in terms of SiO2 preferably is 0.05 to 0.8.

Abstract: An electromagnetic steel sheet coated with an insulating film with excellent hardness and suitable for use as a material for iron cores of large-sized electric-power generators; and a process for producing the electromagnetic steel sheet coated with an insulating film. The purpose is achieved with a coating material for forming insulating films, the coating material including a solvent and components (A) to (C) contained therein in the respective amounts on a solid basis. (A) A water-compatible carboxylated resin; 100 parts by mass. (B) An aluminum-containing oxide; more than 40 parts by mass but less than 300 parts by mass per 100 parts by mass of the component (A). (C) At least one crosslinking agent selected from the group containing of melamine, isocyanates, and oxazoline; 100 parts by mass or more but less than 300 parts by mass per 100 parts by mass of the component (A).

Abstract: The disclosure provides an electrical steel sheet with an insulating coating excellent in both punchability and powdering resistance, without any chromium compound being contained in the insulating coating. The electrical steel sheet with an insulating coating includes an electrical steel sheet and an insulating coating formed on the electrical steel sheet. The insulating coating contains Si and particulate organic resin. The organic resin contains primary particles having an average primary particle size of 1.0 ?m or less, and 5% or more and 50% or less of the primary particles of the organic resin are agglomerated particles.

Abstract: An electrical steel sheet is provided with insulating coating. The insulating coating contains Si and Fe. The coating weight of Si in the insulating coating in terms of SiO2 is 50% to 99% of the total coating weight. The ratio (Fe/Si) of the content of Fe to the content of Si in the insulating coating is 0.01 to 0.6 on a molar basis. The ratio (C (the organic resin+the lubricant)/(Fe2O3+SiO2)) of the coating weight of the organic resin and/or the lubricant in terms of C to the sum of the coating weight of Fe in terms of Fe2O3 and the coating weight of Si in terms of SiO2 preferably is 0.05 to 0.8.

Abstract: A stacked electrical steel sheet used for a stacked iron core of an automotive motor and the like required to have high-temperature bond property and high-temperature oil resistance is provided. An electrical steel sheet for stacking includes: an electrical steel sheet; and a bond-type insulating coating formed on at least one surface of the electrical steel sheet and having Martens hardness HM of 50 or more and less than 500.

Abstract: A semi-organic insulation coating includes an inorganic component and an organic resin, a Zr compound and an Si compound contains a plate-like silica as an inorganic component and are included in a ratio in a dry coating of 20 to 70 mass % of Zr compound (converted to ZrO2) and 10 to 50 mass % of Si compound containing plate-like silica (converted to SiO2), and the remainder is substantially an organic resin, whereby a magnetic steel sheet with a semi-organic insulation coating has no deterioration of corrosion resistance and water resistance without containing a chromium compound and being excellent in powdering resistance, scratch resistance, sticking resistance, TIG weldability, punchability and coating appearance.

Abstract: A coating material that forms an insulation coating, containing apart from a solvent: an aqueous carboxy group-containing resin as component (A) in an amount of 100 parts by mass in terms of solid content; an aluminum-containing oxide as component (B) in an amount of not less than 100 parts by mass but less than 300 parts by mass in terms of solid content, based on the component (A) present in an amount of 100 parts by mass in terms of solid content; and at least one crosslinking agent as component (C) selected from the group consisting of melamine, isocyanate and oxazoline, in an amount of more than 20 parts by mass but less than 100 parts by mass in terms of solid content, based on the component (A) present in an amount of 100 parts by mass in terms of solid content.

Abstract: A black-coated steel sheet exhibits good bendability and a good appearance after press working is provided. Zinc based plating layers, a chromium-free chemical conversion coating disposed on the zinc based plating layer, and a colored single organic coating which is disposed on the chemical conversion coating and which contains a polyester resin having a hydroxyl value of 10 KOHmg/g or more, an imino-containing melamine resin, and 5 to 15 percent by mass of carbon black are included, wherein the glass transition temperature (Tg) of the organic coating is 40° C. or higher, the film thickness is 10 ?m or less, and the hardness is 200 N/mm2 or more.

Abstract: A semi-organic insulation coating includes an inorganic component and an organic resin, a Zr compound and an Si compound contains a plate-like silica as an inorganic component and are included in a ratio in a dry coating of 20 to 70 mass % of Zr compound (converted to ZrO2) and 10 to 50 mass % of Si compound containing plate-like silica (converted to SiO2), and the remainder is substantially an organic resin, whereby a magnetic steel sheet with a semi-organic insulation coating has no deterioration of corrosion resistance and water resistance without containing a chromium compound and being excellent in powdering resistance, scratch resistance, sticking resistance, TIG weldability, punchability and coating appearance.