Abstract: A composite metal oxide material and a preparation method thereof, a positive electrode plate, a secondary battery, a battery module, a battery pack and an electrical device are provided. The composite metal oxide material includes a central core and a coating layer on the surface of the central core, in which the central core material has a chemical formula of Li5FexM1-xO4, 0.6?x?1; the coating layer material has a chemical formula of LiMO2, M is one or more metal elements with +3 valence, and the absolute value of the difference between the +3-valence ion radius of Fe and the +3-valence ion radius of M is ?0.02 nm. The composite metal oxide material of the present disclosure makes the secondary battery have high charge capacity, high discharge capacity and long cycle life.

Abstract: This disclosure relates to the electrochemical field, and in particular, to a positive electrode material and a preparation method and usage thereof. The positive electrode material of this disclosure includes a substrate, where a general formula of the substrate is LixNiyCozMkMepOrAm, where 0.95?x?1.05, 0.5?y?1, 0?z?1, 0?k?1, 0?p?0.1, 1?r?5.2, 0?m?2, m+r?2, M is selected from one or more of Mn and Al, Me is selected from one or more of Zr, Zn, Cu, Cr, Mg, Fe, V, Ti, Sr, Sb, Y, W, and Nb, and A is selected from one or more of N, F, S, and Cl; and an oxygen defect level of the positive electrode material satisfies at least one of condition (1) or condition (2): (1) 1.77?OD1?1.90; or (2) 0.69?OD2?0.74.

Abstract: Provided are a lithium-ion battery positive electrode plate, comprising a positive electrode film layer disposed on at least one surface of the positive electrode current collector, wherein the positive electrode film layer comprises a positive electrode active material mixture composed of the following materials: polycrystalline particles of a first positive electrode active material with a particle size of 11.0-20.0 ?m; polycrystalline particles of a second positive electrode active material with a particle size of 6.0-10.5 ?m; and monocrystalline particles of a third positive electrode active material with a particle size of 1.1-5.2 ?m; wherein the number of the polycrystalline particles of the first positive electrode active material is a, the number of the polycrystalline particles of the second positive electrode active material is b, the number of the monocrystalline particles of the third positive electrode active material is c, and (a+b):c is in the range of 5.7:4.3 to 7.7:2.3.

Abstract: This application provides a positive active material, a positive electrode plate, an electrochemical energy storage apparatus, and an apparatus. The positive active material is LixNiyCozMkMepOrAm, or LixNiyCozMkMepOrAm with a coating layer on its surface; and the positive active material is single crystal or quasi-single crystal particles, and a particle size Dn10 of the positive active material satisfies: 0.3 ?m?Dn10?2 ?m. In this application, particle morphology of the positive active material and an amount of micro powder in the positive active material are properly controlled, to effectively reduce side reactions between the positive active material and an electrolyte solution, decrease gas production of the electrochemical energy storage apparatus, and improve storage performance of the electrochemical energy storage apparatus without deteriorating an energy density, cycle performance, and rate performance of the electrochemical energy storage apparatus.

Abstract: Embodiments of this application provide a ternary precursor material, a preparation method thereof, and a positive electrode active substance. A ternary precursor material may be provided in this application and may include a core and a shell, wherein (1) the core may have a molecular formula of NixCoyMn1-x-y(OH)2±a, where 0.8?x<1.0, 0<y<0.2, and 0<a<0.2; and the shell may include a doping element; and (2) a deformation stacking fault probability fD of the ternary precursor material may be ?4%. With use of the positive electrode active substance prepared by sintering the precursor material, secondary batteries have relatively high gram capacity and cycling performance.

Abstract: This application provides a positive active material, a positive electrode plate, an electrochemical energy storage apparatus, and an apparatus. The positive active material is LixNiyCozMkMepOrAm, or LixNiyCozMkMepOrAm with a coating layer on its surface; and the positive active material is single crystal or quasi-single crystal particles, and a particle size Dn10 of the positive active material satisfies: 0.3 ?m?Dn10?2 ?m. In this application, particle morphology of the positive active material and an amount of micro powder in the positive active material are properly controlled, to effectively reduce side reactions between the positive active material and an electrolyte solution, decrease gas production of the electrochemical energy storage apparatus, and improve storage performance of the electrochemical energy storage apparatus without deteriorating an energy density, cycle performance, and rate performance of the electrochemical energy storage apparatus.

Abstract: A composite metal oxide material and a preparation method thereof, a positive electrode plate, a secondary battery, a battery module, a battery pack and an electrical device are provided. The composite metal oxide material includes a central core and a coating layer on the surface of the central core, in which the central core material has a chemical formula of Li5FexM1-xO4, 0.6?x?1; the coating layer material has a chemical formula of LiMO2, M is one or more metal elements with +3 valence, and the absolute value of the difference between the +3-valence ion radius of Fe and the +3-valence ion radius of M is ?0.02 nm. The composite metal oxide material of the present disclosure makes the secondary battery have high charge capacity, high discharge capacity and long cycle life.

Abstract: This application provides a positive active material, a positive electrode plate, an electrochemical energy storage apparatus, and an apparatus. The positive active material is LixNiyCozMkMepOrAm, or LixNiyCozMkMepOrAm with a coating layer on its surface; and the positive active material is single crystal or quasi-single crystal particles, and a particle size Dn10 of the positive active material satisfies: 0.3 ?m?Dn10?2 ?m. In this application, particle morphology of the positive active material and an amount of micro powder in the positive active material are properly controlled, to effectively reduce side reactions between the positive active material and an electrolyte solution, decrease gas production of the electrochemical energy storage apparatus, and improve storage performance of the electrochemical energy storage apparatus without deteriorating an energy density, cycle performance, and rate performance of the electrochemical energy storage apparatus.

Abstract: This disclosure relates to the electrochemical field, and in particular, to a positive electrode material and a preparation method and usage thereof. The positive electrode material of this disclosure includes a substrate, where a general formula of the substrate is LixNiyCozMkMepOrAm, where 0.95?x?1.05, 0.5?y?1, 0?z?1, 0?k?1, 0?p?0.1, 1?r?5.2, 0?m?2, m+r?2, M is selected from one or more of Mn and Al, Me is selected from one or more of Zr, Zn, Cu, Cr, Mg, Fe, V, Ti, Sr, Sb, Y, W, and Nb, and A is selected from one or more of N, F, S, and Cl; and an oxygen defect level of the positive electrode material satisfies at least one of condition (1) or condition (2): (1) 1.77?OD1?1.90; or (2) 0.69?OD2?0.74.

Abstract: This application relates to the field of battery technologies, and in particular, to a pressure-resistant positive active material and an electrochemical energy storage apparatus. The positive active material includes secondary particles composed of primary particles, and a quantity ? of primary particles per unit sphere area in a SEM graph of the secondary particles is 5/?m2 to 30/?m2. A single-particle pressure-resistant strength of the secondary particles is 60 MPa to 300 MPa. A molecular formula of the positive active material is LixNiyCozMkMepOrAm, where 0.95?x?1.05, 0?y?1, ?z?1, 0?k?1, 0?p?0.1, 1?r?2, 0?m?2, and m+r?2. The positive active material in this application has a compact particle structure and a high single-particle pressure-resistant strength.