Abstract: This invention relates to a metallic composite membrane for separating hydrogen from a mixed gas, a membrane module and a manufacturing method thereof. The composite membrane consists of a three-layer sandwich structure, e.g. the porous metal substrate, an intermediate layer and the hydrogen-selective dense thin metal layer. In the embodiments of the invention, the porous metal substrates were first pretreated to reduce their surface roughness without reducing their gas permeability. The pretreated substrates were coated with intermediate layer, wherein the intermediate layer served as not only a barrier layer to prevent interdiffusion between the substrate and the hydrogen-selective layer, but also a surface modifier to reduce surface roughness and pore size of the substrate. A hydrogen-selective metal layer was then deposited on the intermediate layer-coated substrate by coating methods.

Abstract: A reactor configuration for fluidized bed reactors in which large exposed fixed surface area per unit reactor volume is required. The configuration uses a serpentine or hairpin bend arrangement of continuously connected and communicating thin channels, with the containing surfaces of these channels being vertical. This configuration enables uniform fluidization of particles throughout the cross-sectional area of the reactor and facilitates dispersal of membrane surfaces, heat transfer surface and baffles in gas-solid fluidized bed reactors.

Abstract: This invention relates to a novel fluidized bed membrane reactor for autothermal operations. More particularly, this invention pertains to a unique fluidized bed membrane reactor which includes internal catalyst solids circulation for conveying heat between a reforming zone and an oxidation zone.