Abstract: A method of forming a nanostructure, comprising: providing a first polymeric brush structure attached to at least one surface of a substrate, wherein the first polymeric brush structure comprises a pre-glass polymerizable precursor; and curing the first polymeric brush structure to form a nanostructure comprising glass. The first polymeric brush structure can be formed by reacting (i) at least one vinyl-containing group comprising a pre-glass precursor with (ii) a polymerization active group on the linker comprising a reversible addition-fragmentation chain-transfer (RAFT) agent or an atom transfer radical polymerization (ATRP) initiator. The present disclosure further relates to a substrate, comprising: a surface comprising a plurality of nanostructures comprising glass, wherein at least a portion of the nanostructures comprises a detectable amount of carbon by x-ray photoelectron spectroscopy (XPS).

Abstract: Disclosed herein is an article comprising a substrate; a first region having a first brush polymer chemically bonded to the substrate; where the first brush polymer comprises repeat units of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer; where the first ethylenically unsaturated monomer comprises a first electroactive moiety and where the second ethylenically unsaturated monomer comprises a second electroactive moiety that is different from the first electroactive moiety; where at least one of the first electroactive moiety or the second electroactive moiety is an emitter moiety and where the repeat units of the first ethylenically unsaturated monomer are covalently bonded to repeat units of the second ethylenically unsaturated monomer.

Abstract: Disclosed herein is a device comprising a substrate; where the substrate comprises a plurality of brush polymers that are covalently or ionically bonded to the substrate; where at least a portion of the brush polymers comprise a covalently bonded emitter moiety.

Abstract: Disclosed herein is a device comprising a substrate; where the substrate comprises a plurality of brush polymers that are covalently or ionically bonded to the substrate; where at least a portion of the brush polymers comprise a covalently bonded emitter moiety.

Abstract: Disclosed herein is an article comprising a substrate; a first region having a first brush polymer chemically bonded to the substrate; where the first brush polymer comprises repeat units of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer; where the first ethylenically unsaturated monomer comprises a first electroactive moiety and where the second ethylenically unsaturated monomer comprises a second electroactive moiety that is different from the first electroactive moiety; where at least one of the first electroactive moiety or the second electroactive moiety is an emitter moiety and where the repeat units of the first ethylenically unsaturated monomer are covalently bonded to repeat units of the second ethylenically unsaturated monomer.