Abstract: Electrodes, electrochemical cells having higher threshold oxygen-release energies, and methods of making the same are disclosed. The electrodes may be a nickel-rich cathode with up to 10% of a rare-earth element such as cerium. The rare-earth element may be added by doping during the manufacture of the cathode or by applying a coating on a surface of the cathode.

Abstract: Systems are provided for a diesel oxidation catalyst. In one example, the diesel oxidation catalyst comprises a washcoat with different catalytically active portions for reacting with one or more of carbon containing compounds and NOx. The diesel oxidation catalyst is located upstream of a particulate filter in an exhaust passage.

Abstract: The disclosure generally relates to filters, methods, and systems for filtering particulates from the exhaust of internal combustion engines such as gasoline direct injection engines and methods of preparing particulate filters.

Abstract: Systems are provided for a diesel oxidation catalyst. In one example, the diesel oxidation catalyst comprises a washcoat with different catalytically active portions for reacting with one or more of carbon containing compounds and NOx. The diesel oxidation catalyst is located upstream of a particulate filter in an exhaust passage.

Abstract: Methods and systems are provided for a diesel oxidation catalyst. In one example, the diesel oxidation catalyst comprises a washcoat with different catalytically active portions for reacting with one or more of carbon containing compounds and NOx. The diesel oxidation catalyst is located upstream of a particulate filter in an exhaust passage.

Abstract: The disclosure generally relates to filters, methods, and systems for filtering particulates from the exhaust of internal combustion engines such as gasoline direct injection engines and methods of preparing particulate filters.

Abstract: Methods and systems are provided for a diesel oxidation catalyst. In one example, the diesel oxidation catalyst comprises a washcoat with different catalytically active portions for reacting with one or more of carbon containing compounds and NOx. The diesel oxidation catalyst is located upstream of a particulate filter in an exhaust passage.

Abstract: Methods and systems are provided for SCR devices cascaded along an exhaust passage. In one example, a method may include adjusting a reductant injection pressure based on a temperature of one or more of the SCR devices.

Abstract: Methods and systems are provided for SCR devices cascaded along an exhaust passage. In one example, a method may include adjusting a reductant injection pressure based on a temperature of one or more of the SCR devices.

Abstract: A method utilizes a three-way catalytic converter, having a catalyst formed from a plurality of particles each including a first metal oxide center, a second metal oxide monolayer, and a catalytically active metal to decrease concentration of hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas during stoichiometric, rich, and lean conditions, wherein a molar ratio of metal in the monolayers to metal in the centers is between about 0.01 and 0.2.

Abstract: Methods and systems are provided for reducing engine cold-start emissions. An exhaust system having a passive NOx adsorber (PNA) may store NOx during an engine cold-start until conditions are optimal for release of the stored NOx to a downstream SCR catalyst. Based on PNA conditions, including a NOx load and a PNA bed temperature, adjustments to EGR rate and/or injection timing may be made to achieve a catalytically favorable ratio of NOx species upstream of the SCR catalyst, after the SCR catalyst has reached its light-off temperature.

Abstract: A selective catalytic reduction (SCR) catalyst includes a support layer. A copper-loaded chabazite (Cu/CHA) layer is supported on the support layer. A copper-loaded beta zeolite (Cu/beta) is supported on the Cu/CHA layer. The Cu/beta may be hydrothermally pre-aged prior to use of the SCR catalyst in a vehicle. The pre-aged Cu/beta is essentially free of phosphorous (P), calcium (Ca), zinc (Zn), sodium (Na), potassium (K), magnesium (Mg), iron (Fe), CaSO4, Ca19Zn2(PO4)14, CaZn2(PO4)2, ash, and/or soot.

Abstract: An exhaust system for a diesel engine is disclosed. The exhaust system may include a diesel oxidation catalyst (DOC) configured to receive exhaust gases from the engine and oxidize hydrocarbons in the exhaust gases and a passive NOx adsorber (PNA) downstream from the DOC and configured to store NOx from the exhaust gases at temperatures up to 150° C. A selective catalytic reduction (SCR) system may be downstream from the PNA and configured to reduce NOx in the exhaust gases. The PNA may be configured to release the stored NOx at temperatures above 200° C. The DOC upstream of the PNA may reduce the amount of N2O that is generated by the PNA by oxidizing hydrocarbons before they reach the PNA.

Abstract: Various methods are provided for operating an emission control device. In one example, a method for an emission control device including a catalyst and a filter comprises passively regenerating the filter, and adjusting, via a controller, a duration of active regeneration of the filter based on an oxygen storage capacity of the emission control device.

Abstract: Various systems and methods are described for managing ammonia storage in an SCR catalyst. In one example approach, a method comprises, in response to a vehicle-off event, injecting ammonia during a final exhaust blowdown until a predetermined value of ammonia is stored in the SCR catalyst; and in response to a subsequent vehicle-on event when an amount of ammonia stored in the SCR catalyst is less than the predetermined value, injecting ammonia until the predetermined value of ammonia is stored in the SCR catalyst.

Abstract: An exhaust system for a diesel engine is disclosed. The exhaust system may include a diesel oxidation catalyst (DOC) configured to receive exhaust gases from the engine and oxidize hydrocarbons in the exhaust gases and a passive NOx adsorber (PNA) downstream from the DOC and configured to store NOx from the exhaust gases at temperatures up to 150° C. A selective catalytic reduction (SCR) system may be downstream from the PNA and configured to reduce NOx in the exhaust gases. The PNA may be configured to release the stored NOx at temperatures above 200° C. The DOC upstream of the PNA may reduce the amount of N2O that is generated by the PNA by oxidizing hydrocarbons before they reach the PNA.

Abstract: A diesel engine exhaust treatment system is provided which includes a diesel oxidation catalyst and a diesel particulate filter, where a first SCR catalyst is positioned at the inlet of the diesel particulate filter, and a second SCR catalyst is coated on the filter. The first and second SCR catalysts each have a low loading, such that a lower backpressure is achieved over the use of a single SCR-coated diesel particulate filter at higher catalyst loadings. The exhaust treatment system also provides effective catalyst efficiency for removal of NOx and other gaseous emissions.

Abstract: An emission control system is provided. The emission control system includes an oxidation catalyst having a precious metal loading of less than 100 grams (g)/cubic foot (ft3) and a selective catalytic reduction (SCR) component positioned downstream of the oxidation catalyst operated between 150° C. and 300° C. during engine operation to reduce the formation of N2O in the selective-catalytic reduction component.

Abstract: Various methods are provided for operating an emission control device. In one example, a method for an emission control device including a catalyst and a filter comprises passively regenerating the filter, and adjusting, via a controller, a duration of active regeneration of the filter based on an oxygen storage capacity of the emission control device.

Abstract: A method for treating engine exhaust. The method includes contacting an NOx exhaust with an upstream catalyst material coated onto a substrate and including copper or iron loaded in a first zeolite at an upstream loading of 0 to 3.5 g/l to convert the NOx exhaust in a first temperature range of 150° C. to 500° C. to a first NOx converted exhaust. The method further includes contacting the first NOx converted exhaust with a downstream catalyst material coated onto the substrate downstream of the upstream catalyst material and including copper or iron loaded in a second zeolite at a downstream loading of 1.5 to 9.5 g/l to convert the first NOx converted exhaust in a second temperature range of 450° C. to 700° C.