Abstract: The invention concerns a process for the transformation of lignocellulosic biomass or cellulose into mono- or poly-oxygenated compounds, in which the lignocellulosic biomass or the cellulose is brought into simultaneous contact with a catalytic system comprising a combination of one or more homogeneous catalysts and one or more heterogeneous catalysts, in the same reaction chamber, in the presence of at least one solvent, said solvent being water alone or as a mixture with at least one other solvent, in a reducing atmosphere, and at a temperature in the range 80° C. to 250° C. and at a pressure in the range 0.5 MPa to 20 MPa.

Abstract: The present invention describes a process for the production of solutions of sugars and alcohols from lignocellulosic biomass, comprising a pre-treatment, a step for enzymatic hydrolysis and alcoholic fermentation, a step for extraction of the alcohol produced, a step for separation of the solid residue, an optional step for washing and drying, followed by a step for digestion of the solid residue in a medium comprising at least one hydrated inorganic salt with formula MXn.n?H2O, in which M is a metal selected from groups 1 to 13 of the periodic classification, X is an anion and n is a whole number in the range 1 to 6 and n? is in the range 0.5 to 12, in order to obtain a solid fraction and a liquid fraction, said solid fraction then being separated and undergoing either an enzymatic hydrolysis step or steps for enzymatic hydrolysis and alcoholic fermentation.

Abstract: A method for pretreating lignocellulosic biomass by: a) acid hydrolysis with an acid solution resulting in a liquid fraction and a solid fraction, b) separating the solid fraction and the liquid fraction, c) drying the solid fraction, d) firing the dried solid fraction in a medium comprising at least one hydrated inorganic salt to obtain a solid fraction and a liquid fraction, e) separating the solid fraction and the liquid fraction obtained in d), f) optionally, treating said solid fraction obtained in e), g) enzymatic hydrolysis of said solid fraction obtained in e) and/or f), and wherein at least a portion of the liquid fraction obtained in b) is used to grow microorganisms which produce the enzymes necessary for the enzymatic hydrolysis of g).

Abstract: A process for pretreatment of lignocellulosic biomass by a) A stage for acid hydrolysis of the biomass by an acid solution leading to a liquid fraction and to a solid fraction, b) A stage for separation of the solid fraction and the liquid fraction, c) A stage for drying the solid fraction, d) A stage for baking the solid fraction that is dried in a medium by a hydrated inorganic salt of formula: MXn.n?H2O in which M is a metal of groups 1 to 13 of the periodic table, X is an anion, and n is an integer between 1 and 6, and n? is between 0.5 and 12, making it possible to obtain a solid fraction and a liquid fraction, e) A stage for separation of the solid fraction and the liquid fraction obtained in stage d).

Abstract: An enhanced method of producing ethers from iso-olefins and alcohols comprises at least one stage of separation of the excess alcohol by an ionic liquid. The ether-hydrocarbon-alcohol effluent treated in said separation stage by the ionic liquid comes from the reaction section and/or from a fractionating column. The separated and condensed alcohol is recycled in the process.

Abstract: Novel group 6 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminate comprising at least one hydroxy group with at least one compound of a group 6 transition metal. These compounds are used in a catalytic composition utilized in an olefin metathesis method.

Abstract: The present invention concerns a process for the conversion of lignocellulosic biomass into sugars, comprising at least three steps. The first step is a step for cooking the lignocellulosic biomass in the presence of at least one hydrated inorganic salt mixed with at least one other metallic salt. The second step is a step for separating at least one solid fraction which has undergone the cooking step, and the third step is a step for enzymatic hydrolysis of said solid fraction to convert the polysaccharides into monosaccharides. The sugars obtained thereby can then be fermented into alcohols.

Abstract: Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminum comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.

Abstract: The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ?-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.

Abstract: Novel group 6 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminate comprising at least one hydroxy group with at least one compound of a group 6 transition metal. These compounds are used in a catalytic composition utilized in an olefin metathesis method.

Abstract: In order to produce both an olefinic fraction and a composition of diacids or diesters of fats, a process is carried out which comprises, in succession: a) metathesis of an unsaturated fat with ethylene in the presence of at least one non-aqueous ionic liquid; b) separating and recycling the ionic liquid used in the first step; c) separating, by distillation, the olefinic fraction (fraction A) from the unsaturated fat mono-ester or mono-basic acid fraction (fraction B) formed in step a); d) homometathesis of the mono-unsaturated fat ester or acid cut (fraction B) which allows the co-production of unsaturated fat diesters or diacids (fraction C) and ethylene which is recycled to the first methathesis step of the process; and e) optionally, recycling the ionic liquid containing the catalyst used in step d).

Abstract: An enhanced method of producing ethers from iso-olefins and alcohols comprises at least one stage of separation of the excess alcohol by an ionic liquid. The ether-hydrocarbon-alcohol effluent treated in said separation stage by the ionic liquid comes from the reaction section and/or from a fractionating column. The separated and condensed alcohol is recycled in the process.

Abstract: Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminium comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.

Abstract: An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by liquid-liquid extraction, the extraction solvent being a non-aqueous ionic liquid of general formula Q+A?, wherein Q+ is an ammonium, phosphonium and/or sulfonium cation, and A? an anion likely to form a liquid salt with said cation. Advantageously, the method according to the invention generally allows the amount of water at the etherification reactor inlet to be divided by at least two and thus the purity of the ether produced to be improved.

Abstract: A process is described in which an unsaturated fat is reacted in a homometathesis reaction in the presence of at least one non-aqueous ionic liquid to produce both an olefinic fraction and a composition of monoalcohol diesters or diacids. Particular application to a mixture of esters of an oleic sunflower seed oil or an oleic rapeseed oil, the process producing both an olefinic fraction and a composition of monoalcohol diesters or diacids wherein, in general, more than half of its chains is constituted by unsaturated C18 chains.

Abstract: Catalytic compositions useful for carrying out the metathesis of unsaturated fatty bodies, in particular unsaturated fatty bodies comprising oleic acid or oleic acid esters, contain a ruthenium-based catalyst which can be isolated and which has the formula (I) below:

Abstract: The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ?-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.

Abstract: An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by liquid-liquid extraction, the extraction solvent being a non-aqueous ionic liquid of general formula Q+A?, wherein Q+ is an ammonium, phosphonium and/or sulfonium cation, and A? an anion likely to form a liquid salt with said cation. Advantageously, the method according to the invention generally allows the amount of water at the etherification reactor inlet to be divided by at least two and thus the purity of the ether produced to be improved.

Abstract: A quick coupling comprising a body with a conical opening and an outside thread, a nut with a central through orifice and a cylindrical counterbore extending the through orifice and tapped over its portion that is remote from the through orifice, and a conical surface connecting the through orifice to the counterbore, the coupling comprising a ring housed in the counterbore of the nut, the ring having a front face directed towards the thread that is fitted with a sealing gasket whose rear face facing towards the coupling surface co-operates therewith to define a radial expansion housing for a split spring washer.

Abstract: In order to produce both an olefinic fraction and a composition of diacids or diesters of fats, a process is carried out which comprises, in succession: a) metathesis of an unsaturated fat with ethylene in the presence of at least one non-aqueous ionic liquid; b) separating and recycling the ionic liquid used in the first step; c) separating, by distillation, the olefinic fraction (fraction A) from the unsaturated fat mono-ester or mono-basic acid fraction (fraction B) formed in step a); d) homometathesis of the mono-unsaturated fat ester or acid cut (fraction B) which allows the co-production of unsaturated fat diesters or diacids (fraction C) and ethylene which is recycled to the first methathesis step of the process; and e) optionally, recycling the ionic liquid containing the catalyst used in step d).