Abstract: Presently described are self-assembling antireflective (“AR”) coating compositions comprising high refractive index surface modified nanoparticles. Also described are various articles such as protective films, optical displays, and windows, comprising such (e.g. dried and cured) AR coating.

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract: A method of reducing optical fringing of a coated substrate is described. The method comprises providing a (e.g. light transmissive) substrate; providing a primer having an unmatched refractive index, and applying the primer to the substrate forming a primer layer having an optically significant thickness. The primer layer in combination with the substrate has a percent reflectance at a maximum at a wavelength of interest. Also described are articles comprising a substrate, a primer having an unmatched refractive index, a high refractive index layer, and optional low refractive index layer such as an antireflective film article.

Abstract: Antireflective films comprising a flexible high refractive index layer that comprises at least 60 wt-% of inorganic nanoparticles, the nanoparticles having a refractive index of at least 1.60, dispersed in a crosslinked organic material. Also described are surface treated nanoparticles.

Abstract: A multi-layer film for reducing microbial contamination on a surface. The multi-layer film can include a core layer having a first surface and a second surface opposite the first surface, an adhesive layer disposed adjacent the first surface of the core layer, and an antimicrobial layer disposed adjacent the second surface. The antimicrobial layer can include a cross-linked matrix and an antimicrobial agent dispersed within the cross-linked matrix, where the cross-linked matrix is derived from a polymerizable precursor comprising a material selected from the group consisting of a polymerizable monomer, a polymerizable polymer having a molecular weight of about 1,000 or less, and combinations thereof.

Abstract: Described is a free-radically curable composition comprising a fluoroalkyl silicone having at least two hydride groups, a polyethylenically unsaturated component having at least two ethylenically unsaturated groups, a hydrosilylation catalyst, and a free radical initiator.

Abstract: Described is a free-radically curable composition comprising a fluoroalkyl silicone having at least two ethylenically unsaturated groups, silicone having at least two Si—H, a polyethylenically unsaturated component having at least two ethylenically unsaturated groups, a hydrosilylation catalyst, and a free radical initiator.

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer and a fluoroalkyl containing multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles.

Abstract: The invention relates to articles such as protective films and displays having a fluorochemical surface layer comprising an antistatic agent and the reaction products of at least one fluoropolyether (meth)acryl compound and at least 50 wt-% of non-fluorinated crosslinking agent(s).

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer or reactive fluoropolymer, an amino silane ester coupling agent or ester equivalent, a multi-olefinic crosslinker, and optional surface modified inorganic particles or sol gel precursors.

Abstract: The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.

Abstract: A cured coating for a siliceous material, preferably an optical fiber, comprises a thermally cured polyorganosilsesquioxane having an oxide powder dispersed therein. The oxide powder has a refractive index from about 1.2 to about 2.7 and includes particles having a particle size less than about 100 nanometers. The cured coating has adhesion to the siliceous material and is transparent to ultraviolet radiation.

Abstract: The invention relates to display and protective articles having a fluorochemical surface layer, and methods of making such articles. The invention also relates to fluoropolyether acrylate compositions.

Abstract: The present invention includes ultraviolet curable compositions preferably containing discrete, crystalline zirconia nanoparticles with reactive, or copolymerizable, surface modification, in a polymerizable monomer/oligomer resin mixture. It is believed that copolymerizable surface modification provides a functional group that enables the functionalized particle to co-polmerize with the reactive monomers, oligomers, and crosslinkers in the formulation. Relative to surface modification of the nanoparticles, acrylate functionality is preferred over methacrylate functionality. On the other hand, methacrylate functionality is preferred over non-reactive, or nonpolymerizable, functionality. As the nanocomposite cures, the resultant network is heavily crosslinked by selection of raw materials with substantial acrylate functionality.

Abstract: Disclosed herein is a coated optical fiber comprising: a siliceous optical fiber including a core inside a cladding; and a cured coating comprising: a thermally cured polyorganosilsesquioxane; and an oxide powder dispersed in said cured polyorganosilsesquioxane, wherein said oxide powder has a refractive index from about 1.2 to about 2.7 and includes a plurality of particles having a particle size less than about 100 nanometers, said cured coating having adhesion to said siliceous optical fiber and further having transparency to ultraviolet radiation. Also disclosed herein is a fiber optic device comprising the optical fiber.

Abstract: The invention relates to display and protective articles having a fluorochemical surface layer, and methods of making such articles. The invention also relates to fluoropolyether acrylate compositions.

Abstract: A filament coating apparatus comprising a frame for releasably securing a filament, and a carriage mounted on the frame to oscillate between a first position and a second position. There is a first filament holding fixture mounted on the carriage and a second filament holding fixture also mounted on the carriage in axial alignment with the first filament holding fixture to secure a measured filament portion, preferably of an optical fiber, including a bare portion thereof, located inside a first boundary and a second boundary, between the first filament holding fixture and the second filament holding fixture. At least one spray head is attached to the frame at the first position with at least one radiation source attached to the frame at the second position.

Abstract: A method for manufacturing an optical fiber refractive index grating. The method comprises the steps of, providing a substantially twist-free length of an optical fiber between a first spool and a second spool before attaching the first spool and the second spool to a support having a first surface opposite a second surface. The support and spools provide a filament organizer including the first spool as a lockable spool and the second spool as a rotary spool. The filament organizer further comprises a tensioner coupled to the rotary spool to apply tension to at least a central portion of the length of an optical fiber disposed between the lockable spool and the rotary spool.