Abstract: Metallization interconnect structures, integrated circuit devices, and methods related to high aspect ratio interconnects are discussed. A self assembled monolayer is selectively formed on interlayer dielectric sidewalls of an opening that exposes an underlying metallization structure. A first metal is formed on the underlying metallization structure and within only a bottom portion of the self assembled monolayer. The exposed portion of the self assembled monolayer is removed and a second metal is formed over the first metal.

Abstract: Integrated circuit interconnect structures including an interconnect line metallization feature subjected to one or more chalcogenation techniques to form a cap may reduce line resistance. A top portion of a bulk line material may be advantageously crystallized into a metal chalcogenide cap with exceptionally large crystal structure. Accordingly, chalcogenation of a top portion of a bulk material can lower scattering resistance of an interconnect line relative to alternatives where the bulk material is capped with an alternative material, such as an amorphous dielectric or a fine grained metallic or graphitic material.

Abstract: Devices, transistor structures, systems, and techniques are described herein related to field effect transistors having a stack of metal chalcogenide nanoribbons extending between a source and drain and contacted by a gate structure. The metal chalcogenide nanoribbons may be recrystallized using a local laser anneal treatment and/or a dopant may be applied, outside of a channel region of the metal chalcogenide nanoribbons, using a local laser treatment in the presence of a precursor including the dopant.

Abstract: Capacitor structures with a composite insulator comprising a first insulator and a second insulator. At least the first insulator is a compound of one or more metals and oxygen that may be deposited with an atomic layer deposition process upon topography having a high aspect ratio. Following a thermal anneal of the first insulator, the first insulator may be highly crystalline, but comprise a plurality of cracks where the first insulator is some lesser thickness. The second insulator may be deposited with an atomic layer deposition process to fill-in the cracks. Overburden associated with deposition of the second insulator may be removed and an electrode may then be formed over the resulting composite insulator.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: An apparatus comprising an integrated circuit die comprising a first interconnect layer; a second interconnect layer; and a plurality of vias coupling the first interconnect layer to the second interconnect layer; wherein the first interconnect layer comprises a conductive material having a grain size of at least 100 nanometers.

Abstract: Integrated circuitry interconnect structures comprising a first metal and a graphene cap over a top surface of the first metal. Within the interconnect structure an amount of a second metal, nitrogen, or silicon is greater proximal to an interface of the graphene cap. The presence of the second metal, nitrogen, or silicon may improve adhesion of the graphene to the first metal and/or otherwise improve electromigration resistance of a graphene capped interconnect structure. The second metal, nitrogen, or silicon may be introduced into the first metal during deposition of the first metal, or during a post-deposition treatment of the first metal. The second metal, nitrogen, or silicon may be introduced prior to, or after, capping the first metal with graphene.

Abstract: An integrated circuit device comprising at least one first layer at a bottom of a trench, the at least one layer connecting to a source/drain region of a transistor, the at least one layer comprising metal; a second layer on the at least one first layer, the second layer comprising metal; and a third layer on the at least one first layer and within the trench, the third layer comprising a dielectric material.

Abstract: Apparatuses, systems, and techniques related to ferroelectric material systems including hafnium oxide-based ferroelectric layers are described. A ferroelectric material system includes a hafnium oxide-based ferroelectric layer and a defect compensation material on the hafnium oxide-based ferroelectric layer. The defect compensation material is an oxide having a stronger bound dissociation energy relative to the hafnium oxide-based ferroelectric layer to compensate for oxygen defects formed in the hafnium oxide-based ferroelectric layer.

Abstract: Contacts to n-type and p-type source/drain regions of field-effect transistors comprise a doped contact metal layer positioned between the fill metal and the source/drain regions. The doped contact metal layer comprises a metal and a semiconductor dopant and is formed by reactive sputtering. By varying the concentration of a reactive gas comprising the dopant in the sputtering environment, the atomic composition of the dopant in the doped contact metal layer can vary as the doped contact metal layer is formed. The presence of doped contact metal layers in source/drain contacts can provide for thermally stable low resistance source/drain contacts by inhibiting dopant diffusion from the source/drain regions to the contact metal. In some embodiments, a non-doped contact metal layer can be positioned between the fill metal and the doped contact metal layer.

Abstract: Contacts to n-type and p-type source/drain regions in complementary metal-oxide semiconductor (CMOS) technologies comprise a diffusion barrier layer positioned between the contact metal and the source/drain regions. The contact metal-diffusion barrier layer pairs used to contact n-type and p-type source/drain regions can comprise different materials. The contact metal layers used in n-type and p-type source/drain contacts can comprise the same or different materials. The presence of diffusion barrier layers can provide for thermally stable low resistance source/drain contacts by inhibiting dopant diffusion from the source/drain regions to the contact metal.

Abstract: An aspect of the disclosure relates to an integrated circuit. The integrated circuit includes a first electrically conductive structure, a thin film crystal layer located on the first electrically conductive structure, and a second electrically conductive structure including metal e.g. copper. The second electrically conductive structure is located on the thin film crystal layer. The first electrically conductive structure is electrically connected to the second electrically conductive structure through the thin film crystal layer. The thin film crystal layer may be provided as a copper diffusion barrier.

Abstract: Integrated circuit interconnect structures including an interconnect metallization feature with a barrier material comprising a metal and a chalcogen. Introduction of the chalcogen may improve diffusion barrier properties at a given barrier material layer thickness with increasing the barrier layer thickness. A barrier material, such as TaN, may be deposited at minimal thickness, and doped with a chalcogen before or after one or more fill materials are deposited over the barrier material. During thermal processing mobile chalcogen impurities may collect within regions within the barrier material to high enough concentrations for at least a portion of the barrier material to be converted into a metal chalcogenide layer. The metal chalcogenide layer may have greater crystallinity than a remainder of the barrier layer.

Abstract: Transistor structures with a channel semiconductor material that is passivated with two-dimensional (2D) crystalline material. The 2D material may comprise a semiconductor having a bandgap offset from a band of the channel semiconductor. The 2D material may be a thin as a few monolayers and have good temperature stability. The 2D material may be a conversion product of a sacrificial precursor material, or of a portion of the channel semiconductor material. The 2D material may comprise one or more metal and a chalcogen. The channel material may be a metal oxide semiconductor suitable for low temperature processing (e.g., IGZO), and the 2D material may also be compatible with low temperature processing (e.g., <450° C.). The 2D material may be a chalcogenide of a metal present in the channel material (e.g., ZnSx or ZnSex) or of a metal absent from the channel material when formed from a sacrificial precursor.

Abstract: Stacked transistor structures having a conductive interconnect between source/drain regions of upper and lower transistors. In some embodiments, the interconnect is provided, at least in part, by highly doped epitaxial material deposited in the upper transistor's source/drain region. In such cases, the epitaxial material seeds off of an exposed portion of semiconductor material of or adjacent to the upper transistor's channel region and extends downward into a recess that exposes the lower transistor's source/drain contact structure. The epitaxial source/drain material directly contacts the lower transistor's source/drain contact structure, to provide the interconnect. In other embodiments, the epitaxial material still seeds off the exposed semiconductor material of or proximate to the channel region and extends downward into the recess, but need not contact the lower contact structure.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: Transistor structures employing metal chalcogenide channel materials may be formed where a chalcogen is introduced into at least a portion of a precursor material that comprises reactive metal(s). The precursor material may be substantially metallic, or may be a metallic oxide (e.g., an oxide semiconductor). The metal(s) may be transition, Group II, Group III, Group V elements, or alloys thereof. An oxide of one or more such metals (e.g., IGZO) may be converted into a chalcogenide (e.g., IGZSx or IGZSex) having semiconducting properties. The chalcogenide formed in this manner may be only a few monolayers in thickness (and may be more thermally stable than many oxide semiconductors. Where not all of the precursor material is converted, a transistor structure may retain the precursor material, for example as part of a transistor channel or a gate dielectric. Backend transistors including metal chalcogenide channel materials may be fabricated over silicon CMOS circuitry.

Abstract: Contacts to p-type source/drain regions comprise a boride, indium, or gallium metal compound layer. The boride, indium, or gallium metal compound layers can aid in forming thermally stable low resistance contacts. A boride, indium, or gallium metal compound layer is positioned between the source/drain region and the contact metal layer. A boride, indium, or gallium metal compound layer can be used in contacts contacting p-type source/drain regions comprising boron, indium, or gallium as the primary dopant, respectively. The boride, indium, or gallium metal compound layers prevent diffusion of boron, indium, or gallium from the source/drain region into the metal contact layer and dopant deactivation in the source/drain region due to annealing and other high-temperature processing steps that occur after contact formation.

Abstract: Contacts to n-type source/drain regions comprise a phosphide or arsenide metal compound layer. The phosphide or arsenide metal compound layers can aid in forming thermally stable low resistance contacts. A phosphide or arsenide metal compound layer is positioned between the source/drain region and the contact metal layer of the contact. A phosphide or arsenic metal compound layer can be used in contacts contacting n-type source/drain regions comprising phosphorous or arsenic as the primary dopant, respectively. The phosphide or arsenide metal compound layers prevent diffusion of phosphorous or arsenic from the source/drain region into the metal contact layer and dopant deactivation in the source/drain region due to annealing and other high-temperature processing steps that occur after contact formation.