Patents by Inventor Christopher M. Ryan
Christopher M. Ryan has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8377353Abstract: Conjugate fibers are prepared in which at least one segment is a mixture of a high-D PLA resin and a high-L PLA resin. These segments have crystallites having a crystalline melting temperature of at least 200° C. At least one other segment is a high-D PLA resin or a high-L PLA resin. The conjugate fibers may be, for example, bicomponent, multi-component, islands-in-the-sea or sheath-and-core types. Specialty fibers of various types can be made through further downstream processing of these conjugate fibers.Type: GrantFiled: September 26, 2008Date of Patent: February 19, 2013Assignee: NatureWorks LLCInventors: Robert A. Green, Chad Henry Kamann, Jeffrey John Kolstad, Christopher M. Ryan
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Publication number: 20100221471Abstract: Conjugate fibers are prepared in which at least one segment is a mixture of a high-D PLA resin and a high-L PLA resin. These segments have crystallites having a crystalline melting temperature of at least 200° C. At least one other segment is a high-D PLA resin or a high-L PLA resin. The conjugate fibers may be, for example, bicomponent, multi-component, islands-in-the-sea or sheath-and-core types. Specialty fibers of various types can be made through further downstream processing of these conjugate fibers.Type: ApplicationFiled: September 26, 2008Publication date: September 2, 2010Inventors: Robert A. Green, Chad Henry Kamann, Jeffrey John Kolstad, Christopher M. Ryan
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Patent number: 6365680Abstract: A hot melt adhesive composition can be made using a polyester derived from 2-hydroxy-propanoic acid (lactic acid). A biodegradable/compostable thermoplastic resin can be formulated into a hot melt adhesive using a lower molecular weight material as a tackifying resin. The adhesive material can be made pressure sensitive and can be made entirely biodegradable by combining the polyester polymer with other biodegradable/compostable ingredients. The biodegradable/compostable adhesive material can be used as a substitute for non-biodegradable materials made from commercial polymers that resist attack by bacteria, fungi and other microbial populations. The resulting adhesive composition can be used in a variety of applications such as packaging and for the manufacture of disposable articles which are made from degradable materials. The entire disposable article can be made from adhesives and structural materials that are fully biodegradable/compostable.Type: GrantFiled: July 6, 1995Date of Patent: April 2, 2002Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Garry J. Edgington, Christopher M. Ryan
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Patent number: 6355772Abstract: A nonwoven fabric comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a nonwoven fabric with the lactide polymer composition is also disclosed.Type: GrantFiled: May 9, 2000Date of Patent: March 12, 2002Assignee: Cargill, IncorporatedInventors: Patrick R. Gruber, Jeffrey J. Kolstad, Christopher M. Ryan, Robin S. Eichen Conn, Eric S. Hall
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Patent number: 6312823Abstract: A compostable multilayer film includes a core layer having a first surface and a second surface, a first blocking reducing layer covering the first surface of the core layer, and a second blocking reducing layer covering the second surface of the core layer. The core layer comprises a lactic acid residue-containing polymer having a glass transition temperature (Tg) below 20° C. At least one of the first and second blocking reducing layers comprise a semicrystalline aliphatic polyester. The core layer may be peroxide modified polylactide polymer which exhibits bridging between polylactide polymer chains.Type: GrantFiled: September 29, 1998Date of Patent: November 6, 2001Assignee: Cargrill, IncorporatedInventors: Ali Zakareya El-Afandi, Patrick Richard Gruber, Jeffrey John Kolstad, James Lunt, Christopher M. Ryan, James Zakareya Nangeroni, Nancy Uzelac Buehler, Mark Hartmann, Jed Richard Randall, Andrea Lee Brosch
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Patent number: 6207792Abstract: An amorphous film comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing an amorphous film with the lactide polymer composition is also disclosed.Type: GrantFiled: July 27, 1999Date of Patent: March 27, 2001Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 6197380Abstract: A lactide polymer coating resulting in a strong, repulpable, high gloss, paper coating. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 5 percent and water in concentration of less than about 2000 parts-per-million. A process for coating paper with the lactide polymer composition is also disclosed.Type: GrantFiled: April 6, 1999Date of Patent: March 6, 2001Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 6143863Abstract: A lactide polymer composition combining compositional and purity limitations and catalyst optimization or addition of stabilizing agents resulting in a melt-stable polymer is disclosed. The melt-stable lactide polymer comprises a plurality of polylactide polymer chains, residual lactide in concentration of less than 2 percent and water in concentration of less than 1000 parts-per-million. A stabilizing agent in an amount sufficient to reduce depolymerization of the lactide polymer during melt-processing or alternatively, control of catalyst level at a molar ratio of monomer to catalyst greater than 3000:1 is also included in the melt-stable composition. A process for manufacture of a melt-stable lactide polymer composition includes polymerizing a lactide mixture and adding stabilizing agents sufficient to reduce depolymerization of the polylactide during melt-processing, followed by devolatilizing the polylactide to remove monomer and water.Type: GrantFiled: May 11, 1999Date of Patent: November 7, 2000Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Eric Stanley Hall, Robin Sue Eichen Conn, Christopher M. Ryan
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Patent number: 6121410Abstract: A semi-crystalline film comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 5 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a semi-crystalline film with the lactide polymer composition is also disclosed.Type: GrantFiled: July 27, 1999Date of Patent: September 19, 2000Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 6111060Abstract: A nonwoven fabric comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a nonwoven fabric with the lactide polymer composition is also disclosed.Type: GrantFiled: January 2, 1998Date of Patent: August 29, 2000Assignee: Cargill, IncorporatedInventors: Patrick R. Gruber, Jeffrey J. Kolstad, Christopher M. Ryan, Robin S. Eichen Conn, Eric S. Hall
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Patent number: 6093791Abstract: A semi-crystalline film comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 5 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a semi-crystalline film with the lactide polymer composition is also disclosed.Type: GrantFiled: March 9, 1998Date of Patent: July 25, 2000Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 6005068Abstract: An amorphous film comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing an amorphous film with the lactide polymer composition is also disclosed.Type: GrantFiled: July 20, 1998Date of Patent: December 21, 1999Assignee: Cargill IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 5981694Abstract: A lactide polymer composition combining compositional and purity limitations and catalyst optimization or addition of stabilizing agents resulting in a melt-stable polymer is disclosed. The melt-stable lactide polymer comprises a plurality of polylactide polymer chains, residual lactide in concentration of less than 2 percent and water in concentration of less than 1000 parts-per-million. A stabilizing agent in an amount sufficient to reduce depolymerization of the lactide polymer during melt-processing or alternatively, control of catalyst level at a molar ratio of monomer to catalyst greater than 3000:1 is also included in the melt-stable composition. A process for manufacture of a melt-stable lactide polymer composition includes polymerizing a lactide mixture and adding stabilizing agents sufficient to reduce depolymerization of the polylactide during melt-processing, followed by devolatilizing the polylactide to remove monomer and water.Type: GrantFiled: November 7, 1997Date of Patent: November 9, 1999Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Eric Stanley Hall, Robin Sue Eichen Conn, Christopher M. Ryan
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Patent number: 5852166Abstract: A lactide polymer coating resulting in a strong, repulpable, high gloss, paper coating. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 5 percent and water in concentration of less than about 2000 parts-per-million. A process for coating paper with the lactide polymer composition is also disclosed.Type: GrantFiled: July 14, 1997Date of Patent: December 22, 1998Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 5849401Abstract: A compostable multilayer film includes a core layer having a first surface and a second surface, a first blocking reducing layer covering the first surface of the core layer, and a second blocking reducing core layer comprises a lactic acid residue-containing polymer having a glass transition temperature (Tg) below 20.degree. C. The first and second blocking reducing layers comprise a semicrystalline aliphatic polyester. The hydrolyzable polymer and have a T.sub.g above about 50.degree. C. The multilayer structure can be used for preparing bags and wrappers.Type: GrantFiled: May 3, 1996Date of Patent: December 15, 1998Assignee: Cargill, IncorporatedInventors: Ali Zakareya El-Afandi, Patrick Richard Gruber, Jeffrey John Kolstad, James Lunt, Christopher M. Ryan, James Zakareya Nangeroni, Nancy Uzelac Buehler, Mark Hartmann, Jed Richard Randall, Andrea Lee Brosch
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Patent number: 5849374Abstract: A compostable multilayer structure in the form of a film, sheet, laminate, and the like, which comprises a core layer having a first surface and a second surface, a first blocking reducing layer covering the first surface of the core layer, and a second blocking reducing layer covering the second surface of the core layer. The core layer contains a lactic acid residue-containing polymer and has a glass transition temperature (T.sub.g) below about 20.degree. C. The first and second blocking reducing layers include a polymer composition of a hydrolyzable polymer and have a T.sub.g above about 50.degree. C. The multilayer structure can be used for preparing bags and wrappers.Type: GrantFiled: September 28, 1995Date of Patent: December 15, 1998Assignee: Cargill, IncorporatedInventors: Patrick R. Gruber, Jeffrey John Kolstad, James Lunt, Christopher M. Ryan, Ali Zakareya El-Afandi, James Nangeroni, Nancy Uzelac Buehler, Mark Hartmann, Jed Richard Randall, Andrea Lee Brosch
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Patent number: 5807973Abstract: A nonwoven fabric comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a nonwoven fabric with the lactide polymer composition is also disclosed.Type: GrantFiled: September 27, 1995Date of Patent: September 15, 1998Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 5798436Abstract: An amorphous film comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing an amorphous film with the lactide polymer composition is also disclosed.Type: GrantFiled: September 5, 1996Date of Patent: August 25, 1998Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 5773562Abstract: A film having a net endotherm greater than about 10 joules per gram of polymer that contains chains including lactic acid residuals; said film further comprising; a) a melt stable polymer composition comprising at least 5% by weight of a melt stable first polymer component with lactic acid residuals b) said first polymer having a number average molecular weight of at least 40,000 and no greater than 300,000 and c) said first melt stable polymer composition having a lactide concentration of less than about 2% by weight of melt stable polymer including polymer chains with lactic acid residuals. A process for preparing a film having a net endotherm greater than about 10 joules per gram of polymer that contains chains including lactic acid residuals is also disclosed.Type: GrantFiled: February 28, 1996Date of Patent: June 30, 1998Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Christopher M. Ryan, Eric Stanley Hall, Robin Sue Eichen Conn
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Patent number: 5763564Abstract: A lactide polymer composition combining compositional and purity limitations and catalyst optimization or addition of stabilizing agents resulting in a melt-stable polymer is disclosed. The melt-stable lactide polymer comprises a plurality of polylactide polymer chains, residual lactide in concentration of less than 2 percent and water in concentration of less than 1000 parts-per-million. A stabilizing agent in an amount sufficient to reduce depolymerization of the lactide polymer during melt-processing or alternatively, control of catalyst level at a molar ratio of monomer to catalyst greater than 3000:1 is also included in the melt-stable composition. A process for manufacture of a melt-stable lactide polymer composition includes polymerizing a lactide mixture and adding stabilizing agents sufficient to reduce depolymerization of the polylactide during melt-processing, followed by devolatilizing the polylactide to remove monomer and water.Type: GrantFiled: March 29, 1996Date of Patent: June 9, 1998Assignee: Cargill, IncorporatedInventors: Patrick Richard Gruber, Jeffrey John Kolstad, Eric Stanley Hall, Robin Sue Eichen Conn, Christopher M. Ryan