Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g, where the volume fraction of micropores is in the range from 0.1 to 0.9 and the volume fraction of pores having a pore diameter no more than 20 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: This invention relates to particulate electroactive materials consisting of a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework including micropores and/or mesopores having a total volume of at least 0.6 cm 3/g, wherein at least half of the micropore/mesopore volume is in the form of pores having a diameter of no more than 2 nm; and (b) an electroactive material located within the micropores and/or mesopores of the porous carbon framework. The D 90 particle diameter of the composite particles is no more than 10 nm.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g, where the volume fraction of micropores is in the range from 0.1 to 0.9 and the volume fraction of pores having a pore diameter no more than 20 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: An electrode for a metal-ion battery is provided wherein the active layer of the electrode comprises a plurality of low porosity particles comprising an electroactive material selected from silicon, silicon oxide germanium, tin, aluminium and mixtures thereof and a plurality of carbon particles selected from one or more of graphite, soft carbon and hard carbon. The ratio of the D50 particles size of the carbon particles to the D50 particle diameter of the porous particles is in the range of from 1.5 to 30. Also provided are rechargeable metal-ion batteries comprising said electrode and compositions of porous particles and carbon particles which may be used to prepare the active layer of said electrode.

Abstract: This invention relates to particulate electroactive materials consisting of a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework including micropores and mesopores having a total volume of 0.5 to 1.5 cm3/g; and (b) silicon located at least within the micropores of the porous carbon framework. The porous carbon framework is an activated carbon material obtained by the pyrolysis of a plant source comprising at least 25 wt % lignin on a dry weight basis followed by activation with steam or carbon dioxide.

Abstract: This invention relates to particulate electroactive materials consisting of a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework including micropores and mesopores having a total volume of 0.5 to 1.5 cm3/g; and (b) silicon located at least within the micropores of the porous carbon framework in a defined amount relative to the volume of the micropores and mesopores. At least 20 wt % of the silicon is characterized as surface silicon by thermogravimetric analysis.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: The invention relates to a particulate material comprising a plurality of composite particles, wherein the composite particles comprise: (a) a porous carbon framework comprising micropores and mesopores having a total pore volume of at least 0.6 cm3/g and no more than 2 cm3/g, where the volume fraction of micropores is in the range from 0.5 to 0.9 and the volume fraction of pores having a pore diameter no more than 10 nm is at least 0.75, and the porous carbon framework has a D50 particle size of less than 20 ?m; (b) silicon located within the micropores and/or mesopores of the porous carbon framework in a defined amount relative to the volume of the micropores and/or mesopores.

Abstract: An electrode for a metal-ion battery is provided wherein the active layer of the electrode comprises a plurality of low porosity particles comprising an electroactive material selected from silicon, silicon oxide germanium, tin, aluminium and mixtures thereof and a plurality of carbon particles selected from one or more of graphite, soft carbon and hard carbon. The ratio of the D50 particles size of the carbon particles to the D50 particle diameter of the porous particles is in the range of from 1.5 to 30. Also provided are rechargeable metal-ion batteries comprising said electrode and compositions of porous particles and carbon particles which may be used to prepare the active layer of said electrode.

Abstract: A composite particle is provided. The particle comprises a first particle component and a second particle component in which: (a) the first particle component comprises a body portion and a surface portion, the surface portion comprising one or more structural features and one or more voids, whereby the surface portion and body portion define together a structured particle; and (b) the second component comprises a removable filler; characterized in that (i) one or both of the body portion and the surface portion comprise an active material; and (ii) the filler is contained within one or more voids comprised within the surface portion of the first component.

Abstract: A method of forming a particulate material comprising silicon, the method comprising the step of reducing a particulate starting material comprising silica-containing particles having an aspect ratio of at least 3:1 and a smallest dimension of less than 15 microns, or reducing a particulate starting material comprising silica-containing particles comprising a plurality of elongate structural elements, each elongate structural element having an aspect ratio of at least 3:1 and a smallest dimension of less than 15 microns.

Abstract: A process is provided for preparing a particulate material consisting of a plurality of porous particles comprising an electroactive material selected from silicon, tin, germanium, aluminium or a mixture thereof, wherein the particles are assembled from a plurality of particle fragments comprising the electroactive material wherein the fragments are obtained by the fragmentation of a porous precursor. The fragmentation step may be realized e.g. by wet ball milling and the later assembling step is preferably realized by spray-drying. Also provided are particulate materials obtainable according to the process of the invention, compositions comprising the particulate materials, and electrodes and electrochemical cells comprising the particulate materials. The materials and compositions are especially useful as anode materials in the context of a metal-ion battery such as a lithium-ion battery.

Abstract: A particulate material is provided consisting of a plurality of porous particles comprising an electroactive material selected from silicon, germanium or a mixture thereof (especially a silicon-aluminium alloy), wherein the porous particles have a D50 particle diameter in the range of 0.5 to 7 ?m, an intra-particle porosity between 50 and 90%, and a pore diameter distribution having at least one peak in the range of 30 to 400 nm as determined by mercury porosimetry. Also provided are electrodes (especially anodes) and electrode compositions comprising the particulate material, a rechargeable metal-ion battery (especially a Li-ion battery) comprising the particulate material, and a process for the preparation of the particulate material. It is suggested that the claimed particulate material can be repeatedly lithiated without fracturing, allows easy access to the electrolyte and can be easily dispersed in an electrode slurry.

Abstract: A particulate material is provided consisting of a plurality of porous particles comprising an electroactive material selected from silicon, germanium or a mixture thereof, wherein the porous particles have a D50 particle diameter in the range of greater than 5 to 25 ?m, an intra-particle porosity in the range of from 30 to 90%, and a pore diameter distribution having a peak in the range of from 50 to less than 400 nm as determined by mercury porosimetry. Also provided are electrodes and electrode compositions comprising the particulate material, a rechargeable metal-ion battery comprising the particulate material, and a process for the preparation of the particulate material.

Abstract: A method is provided for the manufacture of an electrode for a metal-ion battery. The method comprises sintering porous silicon-containing particles at a temperature of 500 to 1200° C. and in an oxygen-free atmosphere to obtain particles of reduced BET surface area which are suitable for use as the active material of a metal ion battery when disposed onto a current collector.