Patents by Inventor Christopher Spadaccini

Christopher Spadaccini has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20250289968
    Abstract: A composition includes a glass-forming material and a solvent. A composition includes a glass-forming material that includes mixed composition particles and a solvent.
    Type: Application
    Filed: May 28, 2025
    Publication date: September 18, 2025
    Inventors: Rebecca Dylla-Spears, Theodore F. Baumann, Eric B. Duoss, Joshua D. Kuntz, Robin Miles, Du Nguyen, Christopher Spadaccini, Tayyab I. Suratwala, Timothy Dexter Yee, Cheng Zhu, Cameron David Meyers, Nikola Dudukovic, Tyler Fears, Fang Qian, Koroush Sasan, Joel Destino
  • Patent number: 12404413
    Abstract: Bio-ink comprising freeze-dried cells, methods of making a living structure from a bio-ink material of freeze-dried cells, and methods of using the living structure for biosensing, tissue regeneration, environment sensing, drug discovery, catalysis, and/or clinical implementation are described herein.
    Type: Grant
    Filed: October 5, 2018
    Date of Patent: September 2, 2025
    Assignee: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
    Inventors: Fang Qian, Sarah Baker, Joshua R. Deotte, Eric Duoss, Jennifer Marie Knipe, Samantha Ruelas, Christopher Spadaccini, Joshuah K. Stolaroff, Cheng Zhu
  • Patent number: 12351718
    Abstract: According to one embodiment, a method includes forming a structure by printing an ink, the ink including a glass-forming material, and heat treating the formed structure for converting the glass-forming material to glass. According to another embodiment, an ink composition includes a glass-forming material and a solvent.
    Type: Grant
    Filed: December 6, 2018
    Date of Patent: July 8, 2025
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Rebecca Dylla-Spears, Theodore F. Baumann, Eric B. Duoss, Joshua D. Kuntz, Robin Miles, Du Nguyen, Christopher Spadaccini, Tayyab I. Suratwala, Timothy Dexter Yee, Cheng Zhu, Cameron David Meyers, Nikola Dudukovic, Tyler Fears, Fang Qian, Koroush Sasan, Joel Destino
  • Patent number: 12138863
    Abstract: In one aspect the present disclosure relates to a system for forming a three dimensional (3D) object from a volume of photo-responsive material contained within a material container. A plurality of optical projection subsystems are adapted to be arranged at least partially circumferentially around a material container containing the volume of photo-responsive material, and are controlled by a controller. The optical projection subsystems direct optical projections at a plurality of angles ? through the volume of photo-responsive material. The optical projections are further directed about a z axis extending through the volume of photo-responsive material.
    Type: Grant
    Filed: March 25, 2022
    Date of Patent: November 12, 2024
    Assignees: Lawrence Livermore National Security, LLC, The Regents Of The University Of California
    Inventors: Brett Kelly, Robert Matthew Panas, Maxim Shusteff, Christopher Spadaccini, Hayden Taylor, Indrasen Bhattacharya
  • Patent number: 12134704
    Abstract: An aerogel includes a three-dimensional printed structure having printed ligaments geometrically arranged, where an average diameter of the printed ligaments is in a range of greater than 0 microns and less than 50 microns. In addition, an average distance between a center of a first of the printed ligaments and a center of a second of the printed ligaments is at least equal to the average diameter of the printed ligaments, where the first and the second of the printed ligaments are adjacent. Each printed ligament includes of a plurality of random pores, where an average diameter of the random pores is less than 50 nanometers.
    Type: Grant
    Filed: December 1, 2023
    Date of Patent: November 5, 2024
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Cheng Zhu, Eric Duoss, Christopher Spadaccini, Marcus A. Worsley, Jianchao Ye, Swetha Chandrasekaran
  • Publication number: 20240110073
    Abstract: An aerogel includes a three-dimensional printed structure having printed ligaments geometrically arranged, where an average diameter of the printed ligaments is in a range of greater than 0 microns and less than 50 microns. In addition, an average distance between a center of a first of the printed ligaments and a center of a second of the printed ligaments is at least equal to the average diameter of the printed ligaments, where the first and the second of the printed ligaments are adjacent. Each printed ligament includes of a plurality of random pores, where an average diameter of the random pores is less than 50 nanometers.
    Type: Application
    Filed: December 1, 2023
    Publication date: April 4, 2024
    Inventors: Cheng Zhu, Eric Duoss, Christopher Spadaccini, Marcus A. Worsley, Jianchao Ye, Swetha Chandrasekaran
  • Patent number: 11945151
    Abstract: An additive manufacturing apparatus includes an additive manufacturing print head and a nozzle that receives a bio-based shape memory polymer material and a bio-based material. The nozzle extrudes the bio-based shape memory polymer material and the bio-based material onto a substrate to form a bio-based shape memory polymer part or product.
    Type: Grant
    Filed: August 16, 2022
    Date of Patent: April 2, 2024
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Jennifer Nicole Rodriguez, Eric B. Duoss, James Lewicki, Christopher Spadaccini, Thomas S. Wilson, Cheng Zhu
  • Publication number: 20240080965
    Abstract: A method for producing a neutrons includes triggering a raising or a lowering of a temperature of a pyroelectric crystal of less than about 40° C. to produce a voltage of negative polarity of at least ?100 keV on a surface of a deuterated or tritiated target coupled thereto. A deuterium ion source is pulsed to produce a deuterium ion beam. The accelerating of the deuterium ion beam is achieved by accelerating voltage of the pyroelectric crystal toward the deuterated or tritiated target to produce neutrons. Furthermore, the pyroelectric crystal, the deuterated or tritiated target, and the deuterium ion source are coupled to a common support. The method also includes throwing the common support housing the pyroelectric crystal, the deuterated or tritiated target, and the deuterium ion source near an unknown threat for identification thereof.
    Type: Application
    Filed: October 3, 2023
    Publication date: March 7, 2024
    Inventors: Vincent Tang, Glenn A. Meyer, Steven Falabella, Gary Guethlein, Brian Rusnak, Stephen Sampayan, Christopher Spadaccini, Li-Fang Wang, John Harris, Jeff Morse
  • Patent number: 11884830
    Abstract: According to one aspect of an inventive concept, an ink includes a base catalyst, a sol gel precursor composition, and a block copolymer. According to another aspect of an inventive concept, an aerogel includes a three-dimensional printed structure having printed ligaments geometrically arranged, where an average diameter of the printed ligaments is in a range of greater than 0 microns and less than 50 microns. In addition, an average distance between a center of a first of the printed ligaments and a center of a second of the printed ligaments is at least equal to the average diameter of the printed ligaments, where the first and the second of the printed ligaments are adjacent. Each printed ligament includes of a plurality of random pores, where an average diameter of the random pores is less than 50 nanometers.
    Type: Grant
    Filed: March 22, 2019
    Date of Patent: January 30, 2024
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Cheng Zhu, Eric Duoss, Christopher Spadaccini, Marcus A. Worsley, Jianchao Ye, Swetha Chandrasekaran
  • Patent number: 11884002
    Abstract: Disclosed here is a method for making a three-dimensional micro-architected aerogel, comprising: (a) curing a reaction mixture comprising a co-sol-gel material (e.g., graphene oxide (GO)) and at least one catalyst to obtain a crosslinked co-sol-gel (e.g., GO hydrogel); (b) providing a photoresin comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of the crosslinked co-sol-gel (e.g., GO hydrogel); (c) curing the photoresin using projection microstereolithography layer-by-layer to produce a wet gel having a pre-designed three-dimensional structure; (d) drying the wet gel to produce a dry gel; and (e) pyrolyzing the dry gel to produce a three-dimensional micro-architected aerogel (e.g., graphene aerogel). Also disclosed is a photoresin for projection microstereolithography, comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of a crosslinked co-sol-gel.
    Type: Grant
    Filed: April 5, 2019
    Date of Patent: January 30, 2024
    Assignees: Lawrence Livermore National Security, LLC, Virginia Polytechnic Institute and State University
    Inventors: Marcus A. Worsley, Xiaoyu Zheng, Patrick G. Campbell, Eric Duoss, James Oakdale, Christopher Spadaccini, Ryan Hensleigh
  • Patent number: 11839016
    Abstract: A method for producing a neutrons includes producing a voltage of negative polarity of at least ?100 keV on a surface of a deuterated or tritiated target in response to a temperature change of a pyroelectric crystal of less than about 40° C., the pyroelectric crystal having the deuterated or tritiated target coupled thereto, pulsing a deuterium ion source to produce a deuterium ion beam, accelerating the deuterium ion beam to the deuterated or tritiated target, and directing the ion beam onto the deuterated or tritiated target to make neutrons using at least one element of the following: a voltage of the pyroelectric crystal and a high gradient insulator (HGI) surrounding the pyroelectric crystal. The accelerating of the deuterium ion beam is achieved by using an ion accelerating mechanism comprising a pyroelectric stack accelerator having a first thermal altering mechanism for changing a temperature of the pyroelectric stack accelerator.
    Type: Grant
    Filed: December 15, 2020
    Date of Patent: December 5, 2023
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Vincent Tang, Glenn A. Meyer, Steven Falabella, Gary Guethlein, Brian Rusnak, Stephen Sampayan, Christopher Spadaccini, Li-Fang Wang, John Harris, Jeff Morse
  • Patent number: 11801635
    Abstract: The present disclosure relates to an apparatus for additively manufacturing a product in a layer-by-layer sequence, wherein the product is formed using powder particles deposited on an interface layer of a substrate. A laser generates first and second beam components. The second beam component has a higher power level and a shorter duration than the first beam component. A mask creates a 2D optical pattern in which only select portions of the second beam components can irradiate the powder particles. The first beam component heats the powder particles close to a melting point, where the particles experience surface tension forces relative to the interface layer. While the particles are heated, the second beam component further heats the particles and also melts the interface layer before the surface tension forces can act on and distort the particles, enabling the particles and the interface layer are able to bond together.
    Type: Grant
    Filed: November 10, 2022
    Date of Patent: October 31, 2023
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: James A. Demuth, Andrew J. Bayramian, Eric B. Duoss, Joshua D. Kuntz, Christopher Spadaccini
  • Publication number: 20230076771
    Abstract: The present disclosure relates to an apparatus for additively manufacturing a product in a layer-by-layer sequence, wherein the product is formed using powder particles deposited on an interface layer of a substrate. A laser generates first and second beam components. The second beam component has a higher power level and a shorter duration than the first beam component. A mask creates a 2D optical pattern in which only select portions of the second beam components can irradiate the powder particles. The first beam component heats the powder particles close to a melting point, where the particles experience surface tension forces relative to the interface layer. While the particles are heated, the second beam component further heats the particles and also melts the interface layer before the surface tension forces can act on and distort the particles, enabling the particles and the interface layer are able to bond together.
    Type: Application
    Filed: November 10, 2022
    Publication date: March 9, 2023
    Inventors: James A. DEMUTH, Andrew J. BAYRAMIAN, Eric B. DUOSS, Joshua D. KUNTZ, Christopher SPADACCINI
  • Publication number: 20220402194
    Abstract: An additive manufacturing apparatus includes an additive manufacturing print head and a nozzle that receives a bio-based shape memory polymer material and a bio-based material. The nozzle extrudes the bio-based shape memory polymer material and the bio-based material onto a substrate to form a bio-based shape memory polymer part or product.
    Type: Application
    Filed: August 16, 2022
    Publication date: December 22, 2022
    Inventors: Jennifer Nicole Rodriguez, Eric B. Duoss, James Lewicki, Christopher Spadaccini, Thomas S. Wilson, Cheng Zhu
  • Publication number: 20220212414
    Abstract: In one aspect the present disclosure relates to a system for forming a three dimensional (3D) object from a volume of photo-responsive material contained within a material container. A plurality of optical projection subsystems are adapted to be arranged at least partially circumferentially around a material container containing the volume of photo-responsive material, and are controlled by a controller. The optical projection subsystems direct optical projections at a plurality of angles ? through the volume of photo-responsive material. The optical projections are further directed about a z axis extending through the volume of photo-responsive material.
    Type: Application
    Filed: March 25, 2022
    Publication date: July 7, 2022
    Inventors: Brett KELLY, Robert Matthew PANAS, Maxim SHUSTEFF, Christopher SPADACCINI, Hayden TAYLOR, Indrasen BHATTACHARYA
  • Publication number: 20220209277
    Abstract: The present disclosure relates to an electrical energy storage apparatus. The apparatus has an interpenetrating, three dimensional periodic structure formed from an ionically conductive solid electrolyte material having a plurality of interpenetrating, non-planar channels. The interpenetrating, non-planar channels are made up of a first plurality of channels filled with an anode material, a second plurality of channels adjacent the first plurality of channels and interpenetrating with the first plurality of channels, and filled with a cathode material, and a third plurality of channels adjacent to, and interpenetrating with, one of the first and second pluralities of channels, and filled with a material to form a separator. The first, second and third channels form a spatially dense, three dimensional structure. A first non-flat current collector layer is incorporated which is in communication with the first plurality of channels, and which forms a first electrode.
    Type: Application
    Filed: March 17, 2022
    Publication date: June 30, 2022
    Inventors: Eric DUOSS, Juergen BIENER, Patrick CAMPBELL, Julie A. JACKSON, Geoffrey M. OXBERRY, Christopher SPADACCINI, Michael STADERMANN, Cheng ZHU, Bradley TREMBACKI, Jayathi MURTHY, Matthew MERRILL
  • Patent number: 11370173
    Abstract: In one aspect the present disclosure relates to a system for forming a three dimensional (3D) object from a volume of photo-responsive material contained within a material container. A plurality of optical projection subsystems are adapted to be arranged circumferentially around a material container containing the volume of photo-responsive material, and are controlled by a controller. The optical projection subsystems direct optical projections at a plurality of angles ? through the volume of photo-responsive material. The optical projections are further directed about a z axis extending through the volume of photo-responsive material.
    Type: Grant
    Filed: November 21, 2019
    Date of Patent: June 28, 2022
    Assignees: Lawrence Livermore National Security, LLC, The Regents of the University of California
    Inventors: Brett Kelly, Robert Panas, Maxim Shusteff, Christopher Spadaccini, Hayden Taylor, Indrasen Bhattacharya
  • Patent number: 11309574
    Abstract: The present disclosure relates to an electrical energy storage apparatus which forms an interpenetrating, three dimensional structure. The structure may have a first non-planar channel filled with an anode material to form an anode, and a second non-planar channel adjacent the first non-planar channel filled with a cathode material to form a cathode. A third non-planar channel may be formed adjacent the first and second non-planar channels and filled with an electrolyte. The first, second and third channels are formed so as to be interpenetrating and form a spatially dense, three dimensional structure. A first current collector is in communication with the first non-planar channel and forms a first electrode, while a second current collector is in communication with the second non-planar channel and forms a second electrode. A separator layers separates the current collectors.
    Type: Grant
    Filed: November 20, 2015
    Date of Patent: April 19, 2022
    Assignees: Lawrence Livermore National Security, LLC, Board of Regents, The University of Texas System
    Inventors: Eric Duoss, Juergen Biener, Patrick Campbell, Julie A. Jackson, Geoffrey M. Oxberry, Christopher Spadaccini, Michael Stadermann, Cheng Zhu, Bradley Trembacki, Jayathi Murthy, Matthew Merrill
  • Publication number: 20220032369
    Abstract: The present disclosure relates to a system for using a feedstock to form a three dimensional, hierarchical, porous metal structure with deterministically controlled 3D multiscale porous architectures. The system may have a reservoir for holding the feedstock, the feedstock including a rheologically tuned alloy ink. A printing stage may be used for receiving the feedstock. A processor may be incorporated which has a memory, and which is configured to help carry out an additive manufacturing printing process to produce a three dimensional (3D) structure using the feedstock in a layer-by-layer fashion, on the printing stage. A nozzle may be included for applying the feedstock therethrough onto the printing stage.
    Type: Application
    Filed: October 15, 2021
    Publication date: February 3, 2022
    Inventors: Zhen QI, Juergen BIENER, Wen CHEN, Eric DUOSS, Christopher SPADACCINI, Marcus A. WORSLEY, Jianchao YE, Cheng ZHU
  • Patent number: 11173545
    Abstract: The present disclosure relates to a method for forming a three dimensional, hierarchical, porous metal structure with deterministically controlled 3D multiscale pore architectures. The method may involve providing a feedstock able to be applied in an additive manufacturing process, and using an additive manufacturing process to produce a three dimensional (3D) structure using the feedstock. The method may involve further processing the 3D structure through at least a de-alloying operation to form a metallic 3D structure having an engineered, digitally controlled macropore morphology with integrated nanoporosity.
    Type: Grant
    Filed: October 23, 2017
    Date of Patent: November 16, 2021
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Zhen Qi, Juergen Biener, Wen Chen, Eric Duoss, Christopher Spadaccini, Marcus A. Worsley, Jianchao Ye, Cheng Zhu