Abstract: A silicone release coating composition comprises: (A) 100 weight parts of an organopolysiloxane fluid having a viscosity at 25° C. of 50 to 10,000 mPa·s and an alkenyl content of 0.10 to 3.0 wt %; (B) 0.5-40 weight parts of a diorganopolysiloxane represented by the average structural formula (1): Rc3SiO(RbRcSiO2/2)n1(Rc2SiO2/2)n2SiRc3??(1) ?wherein Rb is an alkenyl group; Rc is an alkyl group or a phenyl group; n1 provides an alkenyl content of 0.05 to 0.80 wt. %; n2 is at least 1; and n1+n2 provides this component with a viscosity at 25° C. of 5,000 to 150,000 mPa·s; (C) an organohydrogenpolysiloxane that has a viscosity at 25° C. of 1 to 1,000 mPa·s, at least two silicon-bonded hydrogen atoms in each molecule, and an alkyl group or a phenyl group for its silicon-bonded organic groups; (D) a hydrosilylation reaction catalyst in a catalytic amount; (E) a surfactant; (F) water; and (G) an inhibitor.

Abstract: Disclosed is an emulsion type silicone pressure sensitive adhesive composition and a process for the production thereof. Also provided is an emulsion type silicone pressure sensitive adhesive composition, comprising: (A) 100 parts by weight of a silicone pressure sensitive adhesive; (B) 1-30 parts by weight of an emulsifier selected from the group consisting of a polyvinylalcohol and a polyether modified MQ resin wherein M is R 3SiO 1/2, and Q is SiO 4/2, wherein R represents C 1-20 alkyl; (C) water; and (D) catalyst.

Abstract: This invention relates to solventless release coating organopolysiloxane composition and sheet-form substrate having cured release coating, providing a solventless release coating organopolysiloxane composition having a viscosity of 50 to 3,000 mPa s, comprising (A) 100 parts of an organopolysiloxane fluid having a viscosity at 25° C. of 10 to 1,000 mPa s and alkenyl content of 0.10 to 3.0 wt %; (B) 0.5 to 15 parts of a diorganopolysiloxane having a viscosity at 25° C. of 10,000 to 150,000 mPa s, and 0.05 to 0.30% of alkenyl groups at the pendant position of its siloxane-chain and trialkylsiloxy-terminals; (C) a prescribed quantity of an organohydrogenpolysiloxane; and (D) a hydrosilylation reaction catalyst. Also, a cured release coating-bearing sheet-form substrate that has a cured coating from this solventless release coating organopolysiloxane composition is provided.

Abstract: A silicone emulsion comprises: (A) a silicone compound comprising an anchorage additive for enhancing the adhesion to a polymer film substrate; (B) at least one surfactant; and (C) water. The anchorage additive is the reaction product of (A1) a fluid polyorganosiloxane containing at least one alkenyl group and at least one silanol group with (A2) a hydrolysable silane containing at least one epoxide group. A water-based anchorage additive comprises the silicone emulsion. A silicone release coating composition comprises: (X1) the silicone emulsion; and (X2) at least one curable silicone composition, e.g. a water-based silicone release coating composition. The curable silicone release coating composition may be applied to a sheet-form substrate and cured to form a release-coated layer having good release property and improved rub-off resistance on the substrate.

Abstract: A silicone release coating composition comprises: (A) 100 weight parts of an organopolysiloxane fluid having a viscosity at 25° C. of 50 to 10,000 mPa·s and an alkenyl content of 0.10 to 3.0 wt %; (B) 0.5-40 weight parts of a diorganopolysiloxane represented by the average structural formula (1): Rc3SiO(RbRcSiO2/2)n1(Rc2SiO2/2)n2SiRc3 ??(1) wherein Rb is an alkenyl group; Rc is an alkyl group or a phenyl group; n1 provides an alkenyl content of 0.05 to 0.80 wt. %; n2 is at least 1; and n1+n2 provides this component with a viscosity at 25° C. of 5,000 to 150,000 mPa·s; (C) an organohydrogenpolysiloxane that has a viscosity at 25° C. of 1 to 1,000 mPa·s, at least two silicon-bonded hydrogen atoms in each molecule, and an alkyl group or a phenyl group for its silicon-bonded organic groups; (D) a hydrosilylation reaction catalyst in a catalytic amount; (E) a surfactant; (F) water; and (G) an inhibitor.

Abstract: A silicone release coating composition comprises: (A) 100 weight parts of an organopolysiloxane fluid having a viscosity at 25° C. of 50 to 10,000 mPa·s and an alkenyl content of 0.10 to 3.0 wt %; (B) 0.5-40 weight parts of a diorganopolysiloxane represented by the average structural formula (1): Rc3SiO(RbRcSiO2/2)n1(Rc2SiO2/2)n2SiRc3 ??(1) wherein Rb is an alkenyl group; Rc is an alkyl group or a phenyl group; n1 provides an alkenyl content of 0.05 to 0.80 wt. %; n2 is at least 1; and n1+n2 provides this component with a viscosity at 25° C. of 5,000 to 150,000 mPa·s; (C) an organohydrogenpolysiloxane that has a viscosity at 25° C. of 1 to 1,000 mPa·s, at least two silicon-bonded hydrogen atoms in each molecule, and an alkyl group or a phenyl group for its silicon-bonded organic groups; (D) a hydrosilylation reaction catalyst in a catalytic amount; (E) a surfactant; (F) water; and (G) an inhibitor.

Abstract: Disclosed is an emulsion type silicone pressure sensitive adhesive composition and a process for the production thereof. Also provided is an emulsion type silicone pressure sensitive adhesive composition, comprising: (A) 100 parts by weight of a silicone pressure sensitive adhesive; (B) 1-30 parts by weight of an emulsifier selected from the group consisting of a polyvinylalcohol and a polyether modified MQ resin wherein M is R 3SiO 1/2, and Q is SiO 4/2, wherein R represents C 1-20 alkyl; (C) water; and (D) catalyst.

Abstract: A silicone emulsion comprises: (A) a silicone compound comprising an anchorage additive for enhancing the adhesion to a polymer film substrate; (B) at least one surfactant; and (C) water. The anchorage additive is the reaction product of (A1) a fluid polyorganosiloxane containing at least one alkenyl group and at least one silanol group with (A2) a hydrolysable silane containing at least one epoxide group. A water-based anchorage additive comprises the silicone emulsion. A silicone release coating composition comprises: (X1) the silicone emulsion; and (X2) at least one curable silicone composition, e.g. a water-based silicone release coating composition. The curable silicone release coating composition may be applied to a sheet-form substrate and cured to form a release-coated layer having good release property and improved rub-off resistance on the substrate.

Abstract: This invention relates to solventless release coating organopolysiloxane composition and sheet-form substrate having cured release coating, providing a solventless release coating organopolysiloxane composition having a viscosity of 50 to 3,000 mPa s, comprising (A) 100 parts of an organopolysiloxane fluid having a viscosity at 25° C. of 10 to 1,000 mPa s and alkenyl content of 0.10 to 3.0 wt %; (B) 0.5 to 15 parts of a diorganopolysiloxane having a viscosity at 25° C. of 10,000 to 150,000 mPa s, and 0.05 to 0.30% of alkenyl groups at the pendant position of its siloxane-chain and trialkylsiloxy-terminals; (C) a prescribed quantity of an organohydrogenpolysiloxane; and (D) a hydrosilylation reaction catalyst. Also, a cured release coating-bearing sheet-form substrate that has a cured coating from this solventless release coating organopolysiloxane composition is provided.

Abstract: To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.

Abstract: Problem: To provide a silicone-based releasable adhesive composition that is capable of easily controlling peeling force of a releasable adhesive layer by the composition, and whereby the silicone-based releasable adhesive composition has excellent attachment characteristics and releasability characteristics. A further object is to provide a sheet-form substrate and a releasable adhesive sheet that have a releasable adhesive layer formed by curing this composition. Resolution Means: The silicone-based releasable adhesive composition includes an organopolysiloxane resin-organopolysiloxane condensation reaction product obtained by condensation reaction between (a1) 100 weight parts of an MQ type organopolysiloxane resin containing hydroxyl groups or alkoxy groups in a range of 0.3 to 2.0 weight % and having an M unit to Q unit molar ratio of 0.6 to 1.

Abstract: To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.

Abstract: This invention relates to organopolysiloxane-modified graft copolymers obtained by a method comprising heating a mixture comprising an ethylenically unsaturated monomer, a polyethylene-polybutylene macromonomer, an organopolysiloxane macromonomer, a free radical initiator, and optionally a solvent. The copolymers of this invention find utility in adhesives such as pressure sensitive adhesives, contact adhesives. laminating adhesives, and assembly adhesives, and release coatings.

Abstract: Compositions and a method for performing the room temperature vulcanization of silicone elastomers are disclosed. The compositions and method utilize specifically-defined hydroxy-terminated polyorganosiloxanes, cross-linking agents which contain a hydrolyzable moiety, a catalyst which exhibits catalytic action in the condensation reaction between the hydroxy groups of the polyorganosiloxanes and the hydrolyzable groups of the cross-linking agents, and a formamide-type cure accelerator component. It has been found that these compositions can be stably stored under substantially moisture-free conditions and be readily vulcanized to form solid elastomers when exposed to moisture in the air. The vulcanization process provides a fast cure and a final silicone rubber product which exhibits good depth of hardening and excellent physical properties.