Abstract: A preparation method includes the following steps: S1, preparing an aqueous solution of a metal salt and an aqueous solution of a precipitant, where the precipitant includes one or more selected from oxalic acid and a water-soluble oxalate; S2, mixing the aqueous solution of the precipitant and the aqueous solution of the metal salt at a shear speed of 10000 r/min or more for co-precipitation reaction; and S3, after the reaction is completed, obtaining the positive electrode active material precursor via washing and drying.

Abstract: The present application provides a carbonaceous material and a preparation method therefor, and a secondary battery and an electrical device comprising the same. The carbonaceous material has 0.13?A/B?0.50, wherein A represents a mass of water vapor adsorbed on the carbonaceous material after a water vapor adsorption test by placing the carbonaceous material under constant temperature and humidity conditions of 25° C. and 100% RH for 100 h, and B represents an initial mass of the carbonaceous material. The present application can simultaneously improve the capacity and initial coulombic efficiency of the carbonaceous material.

Abstract: A method for preparing the ammonium manganese iron phosphate precursor includes mixing and grinding metal source powder and phosphorus source powder to enable a low-heating-temperature solid-state reaction of each component, and then washing and drying the obtained product to obtain the ammonium manganese iron phosphate precursor, where the metal source includes an iron source, a manganese source and an optional source of a doping element M which represents doping elements at manganese and iron sites, and the phosphorus source includes triammonium phosphate.

Abstract: This application provides a secondary battery and an electrical device. The secondary battery includes a current collector and a negative film layer. The negative film layer includes: a first film layer, disposed on at least one surface of the current collector, where the first film layer includes a first negative active material; a second film layer, disposed on a surface of the first film layer, where the surface is away from the current collector, and the second film layer includes a second negative active material. A volume distribution diameter Dv50 of the first negative active material is greater than a volume distribution diameter Dv50 of the second negative active material, and a powder compaction density of the first negative active material is greater than the powder compaction density of the second negative active material under a same pressure.

Abstract: A composite positive electrode active material, a method for preparing the same, and an electric device are described. The method includes: providing positive electrode active material particles; providing a solid aluminum salt to make the solid aluminum salt cover a surface of the positive electrode active material particles; and providing a solid base to the positive electrode active material particles covered by the solid aluminum salt to make the solid aluminum salt and the solid base undergo an in situ solid-phase chemical reaction and generate a cladding layer covering the surface of the positive electrode active material particles, to obtain the composite positive electrode active material, wherein the cladding layer has alumina nanoparticles. The prepared alumina can uniformly cover the surface of the positive electrode active material particles, protect the positive electrode active material, and ensure the electrochemical performance of the positive electrode active material.

Abstract: A conductive film includes: a substrate, where the substrate has a first surface and a second surface facing away from each other, and the substrate has a dense structure; and a first porous layer, where the first porous layer is stacked and bonded to the first surface of the substrate; the first porous layer includes a porous conductive material; and the porous conductive material has pores with first pore size and pores with second pore size; the first pore size being n micrometers, where 0.5?n?10; and the second pore size being m nanometers, where 20<m<200.

Abstract: A separator and a preparation method thereof, a secondary battery, and an electric apparatus are described. The separator includes a first base film and a coating provided on at least one surface of the first base film. The coating includes a thermosensitive functional material. The thermosensitive functional material includes a high-temperature-resistant core layer and a thermosensitive surface layer at least partially enveloping the high-temperature-resistant core layer. The high-temperature-resistant core layer includes one or more of organic polymer fiber and inorganic particle that is surface-modified by a silane coupling agent. This application relates to corresponding preparation method of separator, secondary battery, and electric apparatus. The separator has low pore-closing temperature and high puncture strength, thereby improving the safety performance of the corresponding battery.

Abstract: A core-shell polymer comprises a core portion and a shell portion that at least partially covers the core portion. The core portion comprises a structural unit derived from a monomer represented by Formula I, and the shell portion comprises a structural unit derived from a monomer represented by Formula I, a structural unit derived from a monomer represented by Formula II, and a structural unit derived from a monomer represented by Formula III, wherein R1, R2 and R3 are each independently selected from hydrogen, fluorine, chlorine or C1-3 alkyl containing at least one fluorine atom, R4, R5, R6, R7, R8, R9 are each independently selected from hydrogen or substituted or unsubstituted C1-3 alkyl, and Ar is substituted or unsubstituted aryl.

Abstract: A carbonaceous material contains element O, where the content of element O of the carbonaceous material tested by X-ray photoelectron spectroscopy is denoted as A, the content of element O of the carbonaceous material tested by elemental analysis is denoted as B, and the carbonaceous material satisfies A/B?3 and 5 wt %?A?20 wt %.

Abstract: A fluoropolymer includes a structural unit derived from a monomer of Formula I, a structural unit derived from an olefin monomer, and a structural unit derived from a monomer of Formula II. A molar content of the structural unit derived from the monomer of Formula I is in a range of 60% to 80% based on a total mole of the structural units in the fluoropolymer, wherein R1, R2 and R3 each are independently selected from hydrogen, fluorine, chlorine, or C1-3 alkyl containing at least one fluorine atom, and R4, R5 and R6 each are independently selected from hydrogen, or substituted or unsubstituted C1-5 alkyl.

Abstract: A preparation method of a positive electrode slurry includes a first stirring, a second stirring, a third stirring and a fourth stirring. In the first stirring, a positive electrode active material and a binder are mixed and stirred to prepare a dry mixture. In the second stirring, a binder and a solvent are mixed and stirred to prepare an adhesive solution. In the third stirring, the dry mixture and the adhesive solution are mixed and stirred to prepare a primary slurry. In the fourth stirring, a positive electrode active material, a conductive agent, a solvent and the primary slurry are mixed and stirred to prepare a positive electrode slurry. The binder used in the first stirring is the same as the binder used in the second stirring.

Abstract: A positive electrode active material, including a boron-doped Prussian blue analog; and the Prussian blue analog has a chemical formula of AaMbM?c(CN)6·dH2O, in which A includes at least one of an alkali metal cation, an alkaline earth metal cation, Zn2+, and Al3+, M and M? each independently includes at least one of Ni ion, Cu ion, Fe ion, Mn ion, Co ion, and Zn ion, and H2O is coordination water, 0<a?2, 0<b?1, 0<c?1, 0?d?2; and relates to a preparation method, a secondary battery, and an electrical device. The stability of the positive electrode active material is improved, and thus improving a cycle performance of the corresponding secondary battery; and the preparation method of the positive electrode active material is simple in operation, mild in reaction conditions, and convenient for industrial application.

Abstract: A carbonaceous material where in the CO2 adsorption test of the carbonaceous material, the total CO2 adsorption at 0° C. and a relative pressure P/P0 between 10?8 and 0.029 is recorded as A, the adsorption time is recorded as B, and the carbonaceous material satisfies: A/B?1.7 cm3/(g×h) STP, where STP is the standard condition, P represents the test pressure of CO2, and P0 represents the saturated vapor pressure of CO2 at 0° C.

Abstract: A carbonaceous material has an adsorption velocity v that satisfies 0.015?v?0.050 when subjected to an adsorption test using water vapor at a constant temperature and humidity of 25° C. and 40% RH. The water vapor adsorption test is performed under the following conditions: in a constant temperature and humidity chamber at 25° C. and 40% RH, the carbonaceous material with a mass of m1 is placed in a container, and a water vapor adsorption mass m2 and a water vapor adsorption time t are recorded when the water vapor adsorption of the carbonaceous material reaches equilibrium, and the water vapor adsorption velocity is v=m2/(m1×t), where mi is measured in g, m2 is measured in g, and t is measured in h.

Abstract: The present application provides an organic-inorganic hybrid complex which can be used in a coating of a separator for a secondary battery, wherein the organic-inorganic hybrid complex is formed from basic units represented by formula (I) being periodically assembled in at least one spatial direction: [Lx-i?i][MaCb].Az (I), wherein a defect percentage expressed in i/x*100% is 1% to 30%. The present application further provides a coating composition comprising the organic-inorganic hybrid complex, a coating formed from the coating composition, a separator comprising the coating for a secondary battery, a secondary battery comprising the separator, a battery module, a battery pack and a device. By applying the organic-inorganic hybrid complex of the present application in a coating, the electrolyte infiltration of a separator for a secondary battery is improved while increasing the electrolyte retention rate, thereby improving the rate capability and cycling life of the secondary battery.

Abstract: Provided a separator, a preparation method therefor, a secondary battery and a power consuming device. The separator comprises a first substrate layer, a mixed material layer and a second substrate layer; the mixed material layer is provided between the first substrate layer and the second substrate layer; the mixed material layer comprises an inorganic material and a dispersant. The separator of the present application can delay the occurrence of lithium dendrites or sodium dendrites puncturing the separator and the occurrence of internal short circuit in the battery, prolong the service life of the battery, increase the infiltration of the separator to the electrolyte solution and the charge and discharge rate of the battery, improve the thermal shrinkage performance of the battery, and increase the safety and the first coulombic efficiency of the battery.

Abstract: A conductive film includes: a substrate, where the substrate has a first surface and a second surface facing away from each other, and the substrate has a dense structure; and a first porous layer, where the first porous layer is stacked and bonded to the first surface of the substrate; the first porous layer includes a porous conductive material; and the porous conductive material has pores with first pore size and pores with second pore size, the first pore size being n micrometers, where 0.5?n?10; and the second pore size being m nanometers, where 20<m<200.

Abstract: Provided are a positive electrode active material and a preparation method thereof, a positive electrode plate, a secondary battery, a battery module, a battery pack, and an electric apparatus. The positive electrode active material includes a core and a shell layer enveloping the core, the core having a chemical formula LiaAxMn1-yByP1-zCzO4-nDn, where A includes one or more elements selected from Zn, Al, Na, K, Mg, Nb, Mo, and W, B includes one or more elements selected from Ti, V, Zr, Fe, Ni, Mg, Co, Ga, Sn, Sb, Nb, and Ge, C includes one or more elements selected from B, S, Si, and N, and D includes one or more elements selected from S, F, Cl, and Br; and the shell layer is a doped carbon layer, a doping element in the doped carbon layer including any one or more selected from nitrogen, phosphorus, sulfur, boron, and fluorine.

Abstract: The present application provides a positive electrode active material which may be in a particulate form and comprise a compound represented by Formula 1: NaxAyM1[M2(CN)6]?·zH2O??Formula 1 wherein, A is selected from at least one of an alkali metal element and an alkaline earth metal element, and the ionic radius of A is greater than the ionic radius of sodium; M1 and M2 are each independently selected from at least one of a transition metal element, 0<y?0.2, 0<x+y?2, 0<??1, and 0?z?10; and the particles of the positive electrode active material may have a gradient layer in which the content of the A element decreases from the particle surface to the particle interior.

Abstract: A hard carbon. A total quantity of adsorbed nitrogen under a relative pressure P/P0 of nitrogen between 10?8 and 0.035 is V1 cm3 (STP)/g and a total quantity of adsorbed nitrogen under a relative pressure P/Po of nitrogen between 0.035 and 1 is V2 cm3 (STP)/g in a nitrogen adsorption isotherm determined at a temperature of 77 K for the hard carbon. The hard carbon satisfies: V2/V1?0.20 and 20?V1?150, where P represents an actual pressure of nitrogen, and P0 represents a saturated vapor pressure of nitrogen at a temperature of 77 K.