Abstract: Fluorination of a porous hydrocarbon-based polymer for use as a composite membrane and, more particularly, for use as a composite proton exchange membrane for a fuel cell. The composite membrane is formed by fluorination of the porous hydrocarbon-based polymer to yield a selectively fluorinated polymer, which is then loaded with an ionomer to yield the composite membrane.

Abstract: Fluorination of a porous hydrocarbon-based polymer for use as a composite membrane and, more particularly, for use as a composite proton exchange membrane for a fuel cell. The composite membrane is formed by fluorination of the porous hydrocarbon-based polymer to yield a selectively fluorinated polymer, which is then loaded with an ionomer to yield the composite membrane.

Abstract: A membrane electrode assembly has two gas diffusion layers, two catalyst layers and an ion-exchange membrane interposed therebetween wherein the ion-exchange membrane is cast from a sulphonated polyether ketone/sulfone ionomer. Specifically, the ionomer can be represented as A-B-C wherein Further x, y, z represent the mole ratios of each moiety in the ionomer such that x is between 0.25 and 0.40; y is between 0.01 and 0.26; and z is between 0.40 and 0.67. Melt viscosity of the corresponding base polymer also affects performance in the fuel cell, particularly at values over 0.4 kNsm?2 as measured at 400° C., 1000 s?1. In preparing the membrane electrode assembly, the catalyst layers may be coated directly on the membrane and then bonded with two gas diffusion layers.