Abstract: A crosslinkable copolymer is provided. The crosslinkable copolymer has pendant cationic nitrogen-containing groups with some, but not all, of these pendant groups further including a (meth)acryloyl group. The (meth)acryloyl groups can react to form a crosslinked copolymer that is ionically conductive. The crosslinked copolymer can be used to provide an anion exchange membrane that can be used in electrochemical cells such as fuel cells, electrolyzers, batteries, and electrodialysis cells.

Abstract: Low dielectric constant curable compositions include a first alkyl (meth)acrylate monomer with 12 or more carbon atoms, a crosslinking monomer, a copolymeric additive of a polyisobutylene-polysiloxane block copolymer, and at least one initiator. The curable composition is solvent free and inkjet printable. Upon curing the curable composition forms a non-crystalline, optically clear layer with a dielectric constant of less than or equal to 3.0 at 1 MegaHertz.

Abstract: Curable silsesquioxane compositions, include three dimension networks of Formula I, Formula II, or a combination of Formula I and Formula II, where the oxygen atom at the * is bonded to another Si atom, R is a fluorinated organic group, R2 is an ethylenically unsaturated organic group, n+m is greater than 3, and the —OH groups are present in an amount of at least 15 wt-% of the network. The curable composition may also include a silanol-terminated fluorinated polysiloxane fluid. The curable composition is a coatable composition that is solvent free and wets glass. The curable composition, when cured, has a refractive index of 1.40 or lower.

Abstract: The invention relates to piperidine-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.

Abstract: Curable, coatable compositions include silane surface-treated inorganic nanoparticles with a high refractive index, and a curable reaction mixture. The curable reaction mixture includes a first (meth)acrylate monomer comprising a high refractive index (meth)acrylate monomer with a refractive index of 1.6 or higher, a second (meth)acrylate monomer comprising a lower refractive index (meth)acrylate monomer with a refractive index of less than 1.6, and at least one initiator. Cured optical coatings prepared from the compositions are optically clear, having a visible light transmission of at least 88% and a haze of 5% or less, and have a refractive index of at least 1.78, and are capable of passing a 10 millimeter mandrel flexibility test.

Abstract: Dual cure transfer films include a siloxane-based matrix formed by thermal curing of a siloxane with thermally curable groups, a silsesquioxane with UV-curable groups that is dispersed within the siloxane-based matrix, and a UV photoinitiator. The transfer film is an adhesive and can be cured by UV radiation to form a non-tacky cured layer, where the non-tacky cured layer is optically transparent. In preferred embodiments at least one siloxane comprising thermally curable groups comprises a siloxane with epoxy functional groups; and the at least one silsesquioxane comprising UV-curable groups comprises a (meth)acrylate functional silsesquioxane.

Abstract: Curable compositions include an acrylate of Formula I: Formula I at least one multifunctional (meth)acrylate with fused aromatic groups, heteroarylene groups, heteroalkylene groups, alkylene groups, or aralkylene groups, and a photoinitiator. The compositions, when cured, have a refractive index of 1.63 or greater at 532 nanometers, are optically transparent, and have a thermal stability such that upon heating for 1 hour at 250° C. they have a weight loss of 3.5% or less.

Abstract: Barrier adhesive compositions include at least one polyisobutylene-containing polymer and a curable silsesquioxane additive. The curable silsesquioxane additive may contain free radically polymerizable groups. Barrier film articles include the barrier adhesive compositions and a film. The barrier film articles can be used to encapsulate organic electronic devices.

Abstract: Hyperbranched polydiorganosiloxane polyoxamide polymers are formed from reaction mixtures containing AXg and BZm compounds where either A or B is a siloxane-based group, and each X is either an oxalylamino-functional group or an amino-functional group, and each Z is either an amino-functional group or an oxylamino-functional group, such that upon reaction X and Z form an oxamide bond.

Abstract: Curable ink compositions include a curable aromatic monomer composition, and surface treated metal oxide nanoparticles. The surface treated metal oxide nanoparticles are surface treated with a mixture of at least two silane-functional surface treatment agents, at least one aromatic-containing silane-functional surface treatment agent and at least one silane-functional surface treatment agent comprising a co-polymerizable group. The curable ink composition is inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 60° C., and is free from solvents. The curable ink composition, when printed and cured, has a refractive index of 1.55 or greater, and is optically clear.

Abstract: A particle having a first portion and a second portion surrounding the first portion is described. A volume of the second portion is at least 50 percent of a volume of the particle. The second portion includes a material having a local composition or an effective refractive index that varies substantially continuously across the thickness of the second portion. The material includes a plurality of inorganic regions and may further include organic regions. The particle can be made via atomic or molecular layer deposition.

Abstract: Barrier adhesive compositions include at least one polyisobutylene-containing polymer and a copolymeric additive that is a polyisobutylene-polysiloxane copolymer. The polyisobutylene-polysiloxane copolymers are prepared by the reaction of a hydridosilane-functional polysiloxane and an ethylenically unsaturated polyisobutylene oligomer. Barrier film articles include the barrier adhesive compositions and a film. The barrier film articles can be used to encapsulate organic electronic devices.

Abstract: The invention relates to piperidine-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.

Abstract: A method of forming a transfer film is described. The transfer film includes a template layer having a first major surface and an opposing second major surface. The second major surface includes a structured non-planar release surface. A backfill layer is disposed upon and conforms to the non-planar structured surface. The backfill layer includes a first cross-linked polymer and a plurality of multifunctional monomers, which cure via different and independent curing mechanisms.

Abstract: Curable ink compositions include at least one aromatic (meth)acrylate, at least one multifunctional (meth)acrylate with heteroaromatic groups, fused aromatic groups, heteroalkylene groups, or a group containing both heteroalkylene and aromatic groups, and a photoinitiator. The curable ink composition is Inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 35° C., and is free from solvents. The ink composition, when printed and cured has a refractive index of 1.55 or greater, and is optically clear. The cured ink composition, when cured to a thickness of from 1-16 micrometers, has a surface roughness of less than or equal to 5 nanometers.

Abstract: Curable, coatable compositions include silane surface-treated inorganic nanoparticles with a high refractive index, and a curable reaction mixture. The curable reaction mixture includes a first (meth)acrylate monomer comprising a high refractive index (meth)acrylate monomer with a refractive index of 1.6 or higher, a second (meth)acrylate monomer comprising a lower refractive index (meth)acrylate monomer with a refractive index of less than 1.6, and at least one initiator. Cured optical coatings prepared from the compositions are optically clear, having a visible light transmission of at least 88% and a haze of 5% or less, and have a refractive index of at least 1.78, and are capable of passing a 10 millimeter mandrel flexibility test.

Abstract: Composite structures that include a first layer including a silicone block copolymer; a transition layer, the transition layer having a first surface contiguous with the first layer and a second opposing surface, the transition layer formed from the silicone block copolymer of the first layer; and a glass-like layer contiguous with the second surface of the transition layer, at least a portion of the glass-like layer formed from the transition layer.

Abstract: A curable coating composition is described comprising a silsesquioxane polymer comprising first non-hydrolyzed functional groups; inorganic oxide nanoparticles; and at least one silane compound comprising a second functional group wherein the second functional group covalently bonds with the first non-hydrolyzed functional groups of the silsesquioxane polymer. Preferably, the silane compound further covalently bonds to the inorganic oxide nanoparticles. Preferably, the first non-hydrolyzed functional groups are independently selected from an ethylenically unsaturated group, epoxy, mercapto, amino, and isocyanato. Also describes are method of making an article and articles comprising a curable or cured composition as described herein. In one embodiment, the cured composition comprises inorganic oxide nanoparticles covalently bonded to non-hydrolyzed functional groups of a silsesquioxane polymer matrix.

Abstract: A transfer film includes a template layer having a first major surface and an opposing second major surface. The second major surface includes a structured non-planar release surface. A backfill layer is disposed upon and conforms to the non-planar structured surface. The backfill layer includes a first cross-linked polymer and a plurality of multifunctional monomers, which cure via different and independent curing mechanisms.

Abstract: The invention relates to piperidine-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.