Patents by Inventor Claude Eckhardt

Claude Eckhardt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6482241
    Abstract: The present invention provides, as a first aspect, an asymmetric compound having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; Xa and Xb are the same or different and each is NH2; NH(C1-C4alkyl); NH(C2-C4alkoxyalkyl); N(C1-C4alkyl)2; N(CH2CH2OH)2; a group NH—Z—NR1R2 in which Z is C2-C14alkylene or optionally substituted arylene, and R1 and R2 are the same or different and each is C1-C12alkyl or R1 and R2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C1-C4alkoxy; hydroxy-substituted-C2-C4alkoxy; and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: in which R3 is CN; SO2R5 in which R5 is, C1-C12alkyl, C1-C12alkoxy, NH2, NH(C1-C4alkyl), N(C1-C4alkyl)2, N(CH2CH2OH)2, C1-C4alkoxy or hydroxy-substituted-C2-C4alkoxy;
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: November 19, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Dieter Reinehr, Claude Eckhardt, Fabienne Cuesta
  • Patent number: 6143889
    Abstract: Asymmetric compounds having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine: Xa and Xb are the same or different and each is NH.sub.2 ; NH(C.sub.1 -C.sub.4 alkyl); NH(C.sub.2 -.sub.4 alkoxyalkyl); N(C.sub.1 -C.sub.4 alkyl).sub.2 ; N(CH.sub.2 CH.sub.2 OH).sub.2 ; a group NH--Z--NR.sub.1 R.sub.2 in which Z is C.sub.2 -C.sub.14 alkylene or optionally substituted arylene, and R.sub.1 and R.sub.2 are the same or different and each is C.sub.1 -C.sub.12 alkyl or R.sub.1 and R.sub.2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C.sub.1 -C.sub.4 alkoxy; hydroxy-substituted-C.sub.2 -C.sub.4 alkoxy; ##STR1## and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: ##STR2## in which R.sub.3 is CN; SO.sub.2 R.sub.5 in which R.sub.5 is C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, NH.sub.
    Type: Grant
    Filed: December 11, 1998
    Date of Patent: November 7, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Dieter Reinehr, Claude Eckhardt, Fabienne Cuesta
  • Patent number: 6117189
    Abstract: The present invention relates to a method for the improvement of the sun protection factor (SPF) of textile fiber material, comprising applying to the textile fiber material a detergent comprising at least one fluorescent whitening agent, which absorbs radiation in the wavelength range 280-400 nm, preferably by washing the textile fiber material with a detergent containing said fluorescent whitening agent.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: September 12, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Peter Fankhauser, Claude Eckhardt
  • Patent number: 6015504
    Abstract: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fiber material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: January 18, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Claude Eckhardt, Robert Hochberg, Werner Kaufmann, Georges Metzger
  • Patent number: 5965506
    Abstract: A fabric bleaching composition comprising a peroxy compound and a specified manganese complex is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: October 12, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Pierre Bacher, Claude Eckhardt, Dieter Reinehr
  • Patent number: 5945396
    Abstract: The present invention provides a compound having the formula: ##STR1## in which each R.sub.d is the same or different and each is --NH--Z--N(R.sub.a)(R.sub.b) or --N--?Z--N(R.sub.a)(R.sub.b)!.sub.2 in which Z is C.sub.2 -C.sub.14 alkylene or optionally substituted arylene, R.sub.a and R.sub.b are the same or different and each is C.sub.1 -C.sub.12 alkyl, or R.sub.a and R.sub.b, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; each R.sub.c is the same or different and is NH.sub.2, NH(C.sub.1 -C.sub.4 alkyl), N(C.sub.1 -C.sub.4 alkyl).sub.2, N(CH.sub.2 CH.sub.2 OH).sub.2, O--C.sub.1 -C.sub.4 alkyl, ##STR2## alkali metal atom, ammonium or a cation formed from an amine; or a quaternized form thereof.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: August 31, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Claude Eckhardt, Georges Metzger, Dieter Reinehr, Hanspeter Sauter, Mario Dubini
  • Patent number: 5939379
    Abstract: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, treated with the new compounds.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: August 17, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Claude Eckhardt, Dieter Reinehr, Georges Metzger, Hanspeter Sauter
  • Patent number: 5885952
    Abstract: A detergent base which is obtainable from the reaction of an ethylenically unsaturated sulfonic acid or carboxylic acid or anhydride thereof with a nonionic surfactant of the formulaR.sub.1 --O-(alkylene-O).sub.n.sbsb.1 --R.sub.2 (1)in whichR.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.18 alkenyl;R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, a cycloaliphatic radical having at least 6 C atoms or benzyl; andn.sub.1 is a number from 1 to 60;and if appropriate with sugar derivatives.The detergent base has a good calcium-dispersing power, is very stable to electrolytes and heat and has an excellent washing action and anti-redeposition properties. It is therefore suitable for the preparation of powder and liquid detergents.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: March 23, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Kuratli, Claude Eckhardt, Frank Bachmann, Werner Schreiber
  • Patent number: 5779741
    Abstract: The present invention provides a compound having the formula: ##STR1## in which M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-, di-, tri- or tetra-C.sub.1 -C.sub.4 alkylammonium, mono-, di- or tri-C.sub.1 -C.sub.4 hydroxyalkylammonium or ammonium that is di- or tri-substituted by a mixture of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 hydroxyalkyl groups; R.sub.1 is a group having the formula: ##STR2## in which M has its previous significance and n is 1 or 2; and R.sub.2 is O--C.sub.1 -C.sub.12 alkyl or N(R.sub.3)(R.sub.4) in which R.sub.3 and R.sub.4, independently, are hydrogen, C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, or R.sub.3 and R.sub.4, together with the nitrogen atom, are the atoms required to form a pyrrolidine, piperidine or morpholine group.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: July 14, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Pierre Bacher, Claude Eckhardt, Dieter Reinehr
  • Patent number: 5744599
    Abstract: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
    Type: Grant
    Filed: February 21, 1996
    Date of Patent: April 28, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Claude Eckhardt, Robert Hochberg, Werner Kaufmann, Georges Metzger
  • Patent number: 5741920
    Abstract: A process for inhibiting the re-absorption of migrating dyes in the wash liquor comprises introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg, per liter of wash liquor, of one or more manganese compounds having the formula (1), (2), (3), (4), (5), (6) or (7) as defined in the specification. The manganese compounds do not exhaust at all on to cotton, polyamide or polyester fibres so that the compounds cannot lead to fibre discolouration problems.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 21, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Claude Eckhardt, Dieter Reinehr
  • Patent number: 5733341
    Abstract: A process is described for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13) or (14) as defined in the specification. The compounds of formula (1), (2), (3), (4), (5), (6), (8), (9) (10), (11), (12), (13) or (14) are new compounds. The compounds used do not exhaust at all on to cotton, polyamide or polyester fibers, so that the compounds cannot lead to fiber discoloration problems.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: March 31, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Claude Eckhardt, Dieter Reinehr, Georges Metzger
  • Patent number: 5688758
    Abstract: There is provided a stable, concentrated fabric rinse composition comprising 0.3 to 10, preferably 0.3 to 3% by weight of a fluorescent whitening agent which is compatible with a fabric care ingredient, preferably a cationic, amphoteric or anionic fluorescent whitening agent, based on the total weight of the composition, and optionally a fabric care ingredient, preferably a fabric softener, a stain release or stain repellant ingredient or a water-proofing agent, the remainder being substantially water. The fabric rinse composition is preferably a fabric softener composition comprising 5 to 25, preferably 10 to 20% by weight of a cationic fabric softening agent and 0.3 to 10, preferably 0.3 to 3% by weight of a cationic, amphoteric or anionic fluorescent whitening agent, each based on the total weight of the composition, the remainder being substantially water.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: November 18, 1997
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Claude Eckhardt
  • Patent number: 5656760
    Abstract: The present invention provides a compound having the formula: ##STR1## in which M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-, di-, tri- or tetra-C.sub.1 -C.sub.4 alkylammonium, mono-, di- or tri-C.sub.1 -C.sub.4 hydroxyalkylammonium or ammonium that is di- or tri-substituted by a mixture of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 hydroxyalkyl groups; R.sub.1 is a group having the formula: ##STR2## in which M has its previous significance and n is 1 or 2; and R.sub.2 is O--C.sub.1 -C.sub.12 alkyl or N(R.sub.3)(R.sub.4) in which R.sub.3 and R.sub.4, independently, are hydrogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, or R.sub.3 and R.sub.4, together with the nitrogen atom, are the atoms required to form a pyrrolidine, piperidine or morpholine group.
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: August 12, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Pierre Bacher, Claude Eckhardt, Dieter Reinehr
  • Patent number: 5470990
    Abstract: Novel benzofuranylbiphenyl compounds of the formula ##STR1## which are unsubstituted or polysubstituted by radicals R=hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, phenoxy and benzyloxy and in which M is hydrogen and/or one equivalent of a non-chromophoric cation and n is the number zero, 1 or 2 and m is the number zero or 1, subject to the condition that n and m are not both zero, and the preparation and use thereof as fluorescent brighteners, for example for textiles and paper. The novel benzofuranylbiphenyl compounds are distinguished by their very good stability associated with excellent whitening properties.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: November 28, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Weber, Hans R. Meyer, Jurgen Kaschig, Claude Eckhardt
  • Patent number: 5468884
    Abstract: The invention describes novel highly concentrated, aqueous liquid detergent compositions comprisinga) 0.01 to 2% by weight of dibenzofuranyl biphenyls of formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each independently of one another a sulfonic acid radical, hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, CN, phenoxy or benzyloxy, with the proviso that only one of R.sub.1 to R.sub.5 is a sulfonic acid radical,b) 6 to 22% by weight of water, based on the weight of the detergent composition, andc) suffactants,and to their preparation and use for pretreating and washing textile fabrics.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: November 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Claude Eckhardt
  • Patent number: 5462564
    Abstract: A process for inhibiting the re-absorption of migrating dyes in the wash liquor comprises introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg, per liter of wash liquor, of one or more manganese compounds having the formula (1), (2), (3), (4), (5), (6) or (7) as defined in the specification. The manganese compounds do not exhaust at all on to cotton, polyamide or polyester fibres so that the compounds cannot lead to fibre discoloration problems.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: October 31, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Claude Eckhardt, Dieter Reinehr
  • Patent number: 5449477
    Abstract: A bleach dispersion of long shelf life comprising, apart from at least one peracid or salts thereof, one or more fluorescent whiteners of the bis(benzofuranyl) type and the preparation and use of this bleach dispersion for the simultaneous bleaching and whitening of household and industrial fabrics at temperatures starting from +10.degree. C. or higher are described.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: September 12, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Claude Eckhardt
  • Patent number: 5437689
    Abstract: A process is disclosed for treating polyamide fiber containing materials which process comprises applying a benzofuran-2-one compound to the material in order to enhance its moulding stability. In addition, compositions containing a fluorescent whitening agent and a benzofuran-2-one, and optionally one or more dyes, are disclosed.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: August 1, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Manfred Rembold, Claude Eckhardt, Peter Nesvadba
  • Patent number: 5434275
    Abstract: Novel dibenzofuranylbiphenyl compounds of the formula (I) ##STR1## which are unsubstituted or are monosubstituted or polysubstituted by radicals R=hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, phenoxy and benzyloxy and in which R.sub.3 is C.sub.1 -C.sub.4 alkyl, halogen or phenyl and M is hydrogen and/or one equivalent of a non-chromophoric cation and the preparation and use thereof for fluorescent whitening are described.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: July 18, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Weber, Claude Eckhardt, Hans R. Meyer