Patents by Inventor Clay E. Ringold

Clay E. Ringold has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10711401
    Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
    Type: Grant
    Filed: October 2, 2017
    Date of Patent: July 14, 2020
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
  • Patent number: 10633798
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Grant
    Filed: December 4, 2017
    Date of Patent: April 28, 2020
    Assignee: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Patent number: 10472549
    Abstract: Creping adhesives can include one or more crosslinked resins having the chemical formula (O), (P), or (Q), where RX can be a crosslinking moiety, each RY can independently be a substituted or unsubstituted organic diyl moiety, and each A? can independently be an anion. The creping adhesive can have a cylinder probe adhesion of about 100 gram-force to about 300 gram-force. The creping adhesive can have a peel adhesion of about 20 g/cm to about 110 g/cm.
    Type: Grant
    Filed: June 23, 2016
    Date of Patent: November 12, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol
  • Patent number: 10301777
    Abstract: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: May 28, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston
  • Patent number: 10190261
    Abstract: Resin compositions, products made therewith, and methods for making such resin compositions and products. The resin composition can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound. The product can include a fiber web and an at least partially cured resin composition. The resin composition, prior to curing, can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound.
    Type: Grant
    Filed: June 26, 2017
    Date of Patent: January 29, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, James W. Johnston, Frederick S. Potter
  • Patent number: 10144818
    Abstract: Resins compositions and methods for making and using same. The resin composition can include a glyoxalated polyacrylamide resin and a polyamide-epihalohydrin resin. The polyamide-epihalohydrin resin can include a polyamine partially crosslinked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric crosslinker. A fiber product can include a plurality of fibers and the resin composition, where the resin composition can be at least partially cured.
    Type: Grant
    Filed: October 15, 2015
    Date of Patent: December 4, 2018
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, David F. Townsend, Cornel Hagiopol, James W. Johnston
  • Patent number: 10077217
    Abstract: The disclosure provides strengthened products, including strengthened fibrous composite products and methods for making and using same and strengthened particulates, such as particulate fertilizer products, and methods for making and using same. The fibrous composite product can include a plurality of fibers and an at least partially cured strengthening resin. The fertilizer composition can include a particulate core that can include a plant nutrient, at least one coating layer of the strengthening resin, and at least one coating layer of a water insoluble material. The strengthening resin can include one or more aldehyde-based resins and one or more crosslinked resins. The crosslinked resin can include one or more polyamines at least partially crosslinked by one or more symmetric crosslinks and can include one or more azetidinium functional groups.
    Type: Grant
    Filed: November 23, 2017
    Date of Patent: September 18, 2018
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Kelly A. Shoemake, Arun Narayan
  • Publication number: 20180179427
    Abstract: Creping adhesives can include one or more crosslinked resins having the chemical formula (O), (P), or (Q), where RX can be a crosslinking moiety, each RY can independently be a substituted or unsubstituted organic diyl moiety, and each A? can independently be an anion. The creping adhesive can have a cylinder probe adhesion of about 100 gram-force to about 300 gram-force. The creping adhesive can have a peel adhesion of about 20 g/cm to about 110 g/cm.
    Type: Application
    Filed: June 23, 2016
    Publication date: June 28, 2018
    Applicant: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol
  • Patent number: 9982395
    Abstract: Strengthening resins and methods for making and using same. The strengthening resin can include a polyamine partially cross-linked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric cross-linker. The functionally symmetric cross-linker can include a diisocyanate, a 1,3-dialkyldiazetidine-2,4-dione, a dianhydride, a diacyl halide, a dienone, a dialkyl halide, or any mixture thereof.
    Type: Grant
    Filed: May 29, 2015
    Date of Patent: May 29, 2018
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson, Brian L. Swift, David R. Snead
  • Publication number: 20180112359
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Application
    Filed: December 4, 2017
    Publication date: April 26, 2018
    Applicant: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Publication number: 20180079694
    Abstract: The disclosure provides strengthened products, including strengthened fibrous composite products and methods for making and using same and strengthened particulates, such as particulate fertilizer products, and methods for making and using same. The fibrous composite product can include a plurality of fibers and an at least partially cured strengthening resin. The fertilizer composition can include a particulate core that can include a plant nutrient, at least one coating layer of the strengthening resin, and at least one coating layer of a water insoluble material. The strengthening resin can include one or more aldehyde-based resins and one or more crosslinked resins. The crosslinked resin can include one or more polyamines at least partially crosslinked by one or more symmetric crosslinks and can include one or more azetidinium functional groups.
    Type: Application
    Filed: November 23, 2017
    Publication date: March 22, 2018
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Kelly A. Shoemake, Arun Narayan
  • Publication number: 20180023254
    Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
    Type: Application
    Filed: October 2, 2017
    Publication date: January 25, 2018
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
  • Patent number: 9834890
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Grant
    Filed: May 23, 2016
    Date of Patent: December 5, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Patent number: 9828302
    Abstract: The disclosure provides strengthened products, including strengthened fibrous composite products and methods for making and using same and strengthened particulates, such as particulate fertilizer products, and methods for making and using same. The fibrous composite product can include a plurality of fibers and an at least partially cured strengthening resin. The fertilizer composition can include a particulate core that can include a plant nutrient, at least one coating layer of the strengthening resin, and at least one coating layer of a water insoluble material. The strengthening resin can include one or more aldehyde-based resins and one or more crosslinked resins. The crosslinked resin can include one or more polyamines at least partially crosslinked by one or more symmetric crosslinks and can include one or more azetidinium functional groups.
    Type: Grant
    Filed: June 17, 2016
    Date of Patent: November 28, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Kelly A. Shoemake, Arun Narayan
  • Patent number: 9815717
    Abstract: Methods for removing particulates from an aqueous suspension are provided. In at least one specific embodiment, the method can include mixing a polyamidoamine-epihalohydrin resin with an aqueous suspension comprising one or more first particulates to produce a treated mixture. An amount of the polyamidoamine-epihalohydrin resin in the treated mixture can be less than 500 g/tonne of the one or more first particulates. The method can also include recovering from the treated mixture a purified water having a reduced concentration of the one or more first particulates relative to the aqueous suspension, a purified first particulate product having a reduced concentration of water relative to the aqueous suspension, or both.
    Type: Grant
    Filed: November 6, 2014
    Date of Patent: November 14, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: David R. Snead, Clay E. Ringold, Brian L. Swift
  • Publication number: 20170292222
    Abstract: Resin compositions, products made therewith, and methods for making such resin compositions and products. The resin composition can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound. The product can include a fiber web and an at least partially cured resin composition. The resin composition, prior to curing, can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound.
    Type: Application
    Filed: June 26, 2017
    Publication date: October 12, 2017
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Cornel Hagiopol, James W. Johnston, Frederick S. Potter
  • Publication number: 20170292223
    Abstract: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
    Type: Application
    Filed: June 27, 2017
    Publication date: October 12, 2017
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston
  • Patent number: 9777436
    Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
    Type: Grant
    Filed: May 29, 2015
    Date of Patent: October 3, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
  • Publication number: 20170204565
    Abstract: Creping adhesives and methods for making and using same are provided. The creping adhesive can include a first thermosetting polyamidoamine-epihalohydrin resin that includes a reaction product of a first epihalohydrin and a first polyamidoamine containing one or more secondary amine groups, a first thermoplastic polyamidoamine-epihalohydrin resin that includes a reaction product of a second epihalohydrin and a second polyamidoamine containing one or more secondary amine groups, and one or more re-wetting agents. The first thermosetting polyamidoamine-epihalohydrin resin can have a weight average molecular weight of about 800,000 to about 1,200,000 and a molar ratio of the first epihalohydrin to the secondary amine groups of about 0.002:1 to about 0.1:1. The first thermoplastic polyamidoamine-epihalohydrin resin can have a weight average molecular weight of about 40,000 to about 200,000 and a molar ratio of the second epihalohydrin to the secondary amine groups of about 0.001:1 to about 0.1:1.
    Type: Application
    Filed: April 3, 2017
    Publication date: July 20, 2017
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, David F. Townsend, Cornel Hagiopol, Karla D. Favors, Thomas L. Wright
  • Patent number: 9695552
    Abstract: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: July 4, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston