Abstract: A method and apparatus for electrochemically synthesizing N.sub.2 O.sub.5 includes oxidizing a solution of N.sub.2 O.sub.4 /HNO.sub.3 at an anode, while maintaining a controlled potential between the N.sub.2 O.sub.4 /HNO.sub.3 solution and the anode. A potential of about 1.35 to 2.0 V vs. SCE is preferred, while a potential of about 1.80 V vs. SCE is most preferred. Thereafter, the N.sub.2 O.sub.5 is reacted with either 1.5-diacetyl-3,7-dinitro-1,3,5,7-tetraazacyclooctane (DADN) or 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane (TAT) to form cyclotetramethylenetetraamine (HMX).

Abstract: A method of synthesizing fluoromethylhexafluoroisopropyl ether, comprising mixing hexafluoroisopropyl alcohol, formaldehyde, hydrogen fluoride, and a protonating, dehydrating and fluoride ion-generating agent under conditions suitable to generate fluoromethylhexafluoroisopropyl ether, and then recovering the fluoromethylhexafluoroisopropyl ether.

Abstract: A method and apparatus for electrochemically synthesizing anhydrous HNO.sub.3 from an aqueous solution of HNO.sub.3 includes oxidizing a solution of N.sub.2 O.sub.4 /aqueous HNO.sub.3 at an anode, while maintaining a controlled potential between the N.sub.2 O.sub.4 /aqueous HNO.sub.3 solution and the anode. A potential of about 1.80V vs. SCE is preferred. Anhydrous or aqueous HNO.sub.3 may be disposed at the cathode within the electrochemical cell. Aqueous HNO.sub.3 having a water content of up to about 12% by weight is utilized to synthesize anhydrous HNO.sub.3.

Abstract: A method and apparatus for electrochemically synthesizing N.sub.2 O.sub.5 cludes oxidizing a solution of N.sub.2 O.sub.4 /HNO.sub.3 at an anode, while maintaining a controlled potential between the N.sub.2 O.sub.4 /HNO.sub.3 solution and the anode. A potential of about 1.35 to 2.0 V vs. SCE is preferred, while a potential of about 1.80 V vs. SCE is most preferred. Thereafter, the N.sub.2 O.sub.5 is reacted with either 1.5-diacetyl-3,7-dinitro-1,3,5,7-tetraazacyclooctane (DADN) or 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane (TAT) to form cyclotetramethylenetetraamine (HMX).

Abstract: 1,3,5,5-Tetranitrohexahydropyrimidine, termed DNNC for convenience, useful as an oxident in explosive and rocket propellant compositions.

Abstract: A method of synthesizing fluoromethylhexafluoroisopropyl ether comprises adding hexafluoroisopropyl alcohol to a mixture comprising a stoichiometric excess of paraformaldehyde and hydrogen fluoride, plus sufficient sulfuric acid to sequester most of the water produced by the reaction. The mixture is maintained at a temperature of at least 57.degree. C., to cause vapor formation by boiling of the fluoromethylhexafluoroisopropyl ether formed. The vapor is then collected and condensed, and may be purified by distillation.

Abstract: The composition of matter of N-chloroformamide is disclosed along with a method for preparing the same. The N-chloroformamide normally exists in its tautomeric imidol form. The N-chloroformamide readily reacts with amines to form substituted ureas.

Abstract: A method for preparing anhydrous nitric acid comprising extracting an aqueous mixture of nitric acid and sulfuric acid with methylene chloride to yield a solution of anhydrous nitric acid in methylene chloride. The anhydrous nitric acid can be isolated from the methylene chloride by distillation or crystallization. Alternatively, the anhydrous solution of nitric acid in methylene chloride may be used directly. The methylene chloride extract of the nitric acid-sulfuric acid mixture is a useful nitrating agent.

Abstract: Octahydro-1,3,5,7-tetraalkanoyl-1,3,5,7-tetrazocines are produced by acting a methylene-bis-alkanecarboxamide with formaldehyde. The reaction carried out by heating the reactants in the presence of an acidic catalyst an inert organic liquid under substantially anhydrous conditions.

Abstract: Hexahydro-1,3,5-trialkanoyl-s-triazines are produced by reacting a polymeric formaldehyde and an alkanoic acid amide in the presence of sulfuric acid catalyst and a liquid organic solvent or diluent while removing the water formed in the reaction by distillation, the amount of sulfuric acid catalyst employed being at least 0.05 mol per mol of said amide.