Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally insulating particles distributed within the polymeric network structure, wherein the thermally insulating particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally insulating particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density not greater than 3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.

Abstract: The present disclosure provides an article including an isoporous membrane disposed on a porous substrate. The iso-porous membrane includes a triblock copolymer or a pentablock copolymer. The isoporous membrane has a thickness and is isoporous throughout its thickness. A method of making an article is also provided, which does not require a solvent exchange process. The method includes depositing a composition on a porous substrate, thereby forming a fdm, and removing at least a portion of the solvent from the film, thereby forming an isoporous membrane having numerous pores. The composition contains a solvent and solids including a triblock copolymer or a pentablock copolymer. The article advantageously can be hydrophilic and provides sharp molecular weight cut-offs and high flux.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of intumescent particles distributed within the polymeric network structure; wherein the intumescent particles are present in a range from 15 to 99 weight percent, based on the total weight of the intumescent particles and the polymer (excluding the solvent); and wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.; and methods for making the same. The polymer matrix composites are useful, for example, as fillers, thermally initiated fuses, and fire stop devices.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of functional particles distributed within the polymeric network structure, and wherein the polymer matrix composite has an air flow resistance at 25° C., as measured by the “Air Flow Resistance Test,” of less than 300 seconds/50 cm3/500 micrometers; and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, as filters.

Abstract: Method of making a polymer matrix composite comprising a porous polymeric network structure; and a plurality of particles distributed within the polymeric network structure, the method comprising: combining a thermoplastic polymer, a solvent that the thermoplastic polymer is soluble in, and a plurality of particles to provide a slurry; forming the slurry in to an article; heating the article in an environment to retain at least 90 percent by weight of the solvent, based on the weight of the solvent in the slurry, and inducing phase separation of the thermoplastic polymer from the solvent to provide the polymer matrix composite.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of functional particles distributed within the polymeric network structure, and wherein the polymer matrix composite has an air flow resistance at 25° C., as measured by the “Air Flow Resistance Test,” of less than 300 seconds/50 cm3/500 micrometers; and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, as filters.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of dielectric particles distributed within the polymeric network structure; wherein the dielectric particles are present in a range from 5 to 98 weight percent, based on the total weight of the dielectric particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a dielectric constant in a range from 1.05 to 80; and methods for making the same. Polymer matrix composites comprising dielectric particles are useful, for example, as electric field insulators.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally conductive particles distributed within the polymeric network structure; wherein the thermally conductive particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally conductive particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles and a multiplicity of magnetic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles, magnetic particles and optional magnetic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing thermal interface materials that also provide magnetic properties useful, for example, in flux field directional materials or shielding from electromagnetic interference.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, a multiplicity of intumescent particles and optionally a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles, intumescent particles and optional endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 50% over its initial volume when exposed to at least one temperature greater than 135° C. when exposed to at least one temperature greater than 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, thermally-initiated fuses, and fire-stop devices.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, and a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles and endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 10% of its initial volume when exposed to a temperature of at least 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, as fillers, thermal interface materials, and thermal management materials, for example, in electronic devices, more particularly mobile handheld electronic devices, power supplies, and batteries.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a nonvolatile diluent, and a multiplicity of thermally-conductive particles distributed within the (co)polymeric network; wherein the thermally-conductive particles are present in a range from 15 to 99 weight percent, based on the total weight of the (co)polymer matrix (including the thermally-conductive particles and the nonvolatile diluent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 10% of its initial volume when exposed to a temperature of at least 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, as fillers, thermal interface materials, and thermal management materials, for example, in electronic devices, more particularly mobile handheld electronic devices, power supplies, and batteries.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally conductive particles distributed within the polymeric network structure; wherein the thermally conductive particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally conductive particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.

Abstract: The present disclosure provides a porous membrane made of pentablock copolymer. The porous membrane includes an ABCBA block copolymer and has a number of pores. The A block is immiscible with each of the B block and the C block, the B block has a glass transition temperature (Tg) of 90 degrees Celsius or greater, and the C block has a Tg of 25 degrees Celsius or less. The A block comprises a poly(alkylene oxide), a substituted epoxide, a polylactam, or a substituted carbonate; B block comprises a vinyl aromatic monomer or a polyalkylmethacrylate and C block comprises a polyacrylate, a polysiloxane or a polyisoprene. A method of making a porous membrane is also provided. The method includes forming a film or a hollow fiber from a solution including a solvent and solids containing an ABCBA block copolymer. The method further includes removing at least a portion of the solvent from the film or the hollow fiber and contacting the film or the hollow fiber with a nonsolvent.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of intumescent particles distributed within the polymeric network structure; wherein the intumescent particles are present in a range from 15 to 99 weight percent, based on the total weight of the intumescent particles and the polymer (excluding the solvent); and wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.; and methods for making the same. The polymer matrix composites are useful, for example, as fillers, thermally initiated fuses, and fire stop devices.

Abstract: A coalescing element for aggregating droplets of an emulsion. The coalescing element includes a nonwoven web substrate. A coalescer that includes the coalescing element can also include a housing and a fluid inlet and a fluid outlet each in fluid communication with the coalescing element. The coalescing element and coalescer may be useful for emulsions that form in solvent extraction/electrowinning copper processing and for other emulsions.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of at least one of polar solvent soluble particles or polar solvent swellable particles distributed within the polymeric network structure; wherein the polymeric network structure is insoluble relative to the soluble particles, wherein the soluble particles are present in a range from 1 to 99 weight percent, based on the total weight of the at least one of soluble particles or swellable particles and the polymer (excluding any solvent); and wherein the polymer matrix composite has particles that at least one of (a) upon exposure to a polar fluid, release at least some component from the polymer matrix composite layer or (b) upon exposure to a polar fluid, absorb some of the polar fluid; and methods for making the same.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of intumescent particles distributed within the polymeric network structure; wherein the intumescent particles are present in a range from 15 to 99 weight percent, based on the total weight of the intumescent particles and the polymer (excluding the solvent); and wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.; and methods for making the same. The polymer matrix composites are useful, for example, as fillers, thermally initiated fuses, and fire stop devices.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of indicator particles distributed within the polymeric network structure; wherein the indicator particles are present in a range from 1 to 99 weight percent, based on the total weight of the indicator particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density of at least 0.05 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, as sensors.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally insulating particles distributed within the polymeric network structure, wherein the thermally insulating particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally insulating particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density not greater than 3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.