Abstract: The present application relates to an electrochemical metal-air cell in which a low temperature ionic liquid is used.

Abstract: The present invention relates to an electrochemical cell for generating electrical power that includes an anode, a cathode, a charging electrode and an ionically conductive medium containing at least metal fuel ions and poly(ethylene glycol)tetrahydrofurfuryl. The present invention also relates to a method for charging the cell by electrodeposition of metal fuel on the anode thereof.

Abstract: An embodiment of the invention provides for an electrochemical cell comprising: a fuel electrode comprising a metal fuel, a second electrode, and an ionically conductive medium communicating the electrodes; the ionically conductive medium comprising hetero-ionic aromatic additives. The fuel electrode and the second electrode are operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode functioning as an anode, whereby electrons are generated for conduction from the fuel electrode to the second electrode via a load. An ionically conductive medium and methods of operating an electrochemical cell are also disclosed.

Abstract: An embodiment of the invention provides for an electrochemical cell comprising: a fuel electrode comprising a metal fuel, a second electrode, an ionically conductive medium communicating the electrodes, the ionically conductive medium comprising at least two different additives, wherein at least one additive is selected from the group consisting of: macroheterocyclic compounds, phosphonium salts, hetero-ionic compounds and their derivatives; and, at least one additive is selected from the group consisting of: macroheterocyclic compounds, phosphonium salts, hetero-ionic compounds, and their derivatives. The fuel electrode and the second electrode are operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode functioning as an anode, whereby electrons are generated for conduction from the fuel electrode to the second electrode via a load. An ionically conductive medium and methods of operating an electrochemical cell are also disclosed.

Abstract: An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.

Abstract: A system for managing water content in one or more electrochemical cells, each comprising a plurality of electrodes and a liquid ionically conductive medium, includes a first gas-phase conduit for receiving humid gas-phase associated with the electrochemical cell. The system also includes a desiccator unit communicated to the first air conduit and configured for extracting water from the humid gas-phase. The system additionally includes a heater for selectively heating the desiccant to selectively release extracted water from the desiccator unit. The system further includes a return conduit communicating the desiccator unit to the ionically conductive medium for receiving extracted water from the desiccator unit, and directing the extracted water to the ionically conductive medium. Other associated systems and methods are also disclosed.

Abstract: Embodiments are related to ionic liquids and more specifically to ionic liquids used in electrochemical metal-air cells in which the ionic liquid includes sulfonate ions as the anion.

Abstract: Embodiments of the invention relate to an electrochemical cell comprising: (i) a fuel electrode comprising a metal fuel, (ii) a positive electrode, (iii) an ionically conductive medium, and (iv) a dopant; the electrodes being operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode and the dopant increases the conductivity of the metal fuel oxidation product. In an embodiment, the oxidation product comprises an oxide of the metal fuel which is doped degenerately. In an embodiment, the positive electrode is an air electrode that absorbs gaseous oxygen, wherein during discharge mode, oxygen is reduced at the air electrode. Embodiments of the invention also relate to methods of producing an electrode comprising a metal and a doped metal oxidation product.

Abstract: An electrochemical cell includes a fuel electrode configured to operate as an anode to oxidize a fuel when connected to a load, and configured to operate as a cathode when connected to a power supply. The fuel electrode comprises a plurality of scaffolded electrode bodies, wherein the scaffolded electrode bodies are of varying size. The electrode bodies are of a larger size at positions distal from a charging electrode configured to act as an anode when connected to the power supply, and of a smaller size at positions proximal to the charging electrode. When connected to a load, the scaffolded electrode bodies-containing fuel electrode acts as the electrochemical cell anode and electrodeposited fuel is oxidized.

Abstract: The present invention relates to an electrochemical cell for generating electrical power that includes an anode, a cathode, a charging electrode and an ionically conductive medium containing at least metal fuel ions and an additive for enhancing at least one electrochemical reaction in the cell. The cell also includes an additive sorbent material in contact with the ionically conductive medium that contains an excess amount of the additive, the sorbent material configured to release the excess additive to the ionically conductive medium as concentration of the additive in the ionically conductive medium is reduced during operation of the cell.

Abstract: An electrochemical cell includes a first electrode configured to operate as an anode to oxidize a fuel when connected to a load. The first electrode includes a permeable electrode body configured to allow flow of an ionically conductive medium therethrough. An electrode holder includes a cavity for holding the first electrode. A diffuser is positioned in the cavity between the first electrode and the electrode holder with a gap formed between the diffuser and the electrode holder. The diffuser includes openings configured to allow flow of the ionically conductive medium therethrough and to distribute the flow through the first electrode. A second electrode is positioned in the cavity on a side of the first electrode that is opposite the diffuser, and is configured to operate as a cathode when connected to the load and in contact with the ionically conductive medium.

Abstract: The present invention relates to a method for charging the cell by electrodeposition of metal fuel on the anode thereof.

Abstract: An oxygen recovery system configured to recover evolved oxygen from a regenerative electrochemical cell. The electrochemical cell includes an oxygen reduction cathode, a fuel electrode configured to be a fuel anode when the cell is operated to generate electricity and a cathode for reducing fuel thereon when the cell is operated to regenerate the fuel, and an oxygen evolution anode that is configured to evolve oxygen from an electrolyte solution when the cell is operated to regenerate the fuel. The oxygen recovery system includes an oxygen separator located downstream of the oxygen evolution anode in a recharge direction of flow. The oxygen separator is configured to separate the evolved oxygen from the electrolyte solution. An oxygen recovery path is disposed between the oxygen separator and the oxygen reduction cathode. The oxygen recovery path is configured to direct the evolved oxygen separated from the electrolyte solution to the oxygen reduction cathode.

Abstract: An electrochemical cell includes a fuel electrode configured to operate as an anode to oxidize a fuel when connected to a load. An electrode holder includes a cavity for holding the fuel electrode, at least one inlet connected to the cavity on one side of the cavity and configured to supply an ionically conductive medium to the cavity, and at least one outlet connected to the cavity on an opposite side of the cavity and configured to allow the ionically conductive medium to flow out of the cavity. A plurality of spacers extend across the fuel electrode and the cavity in a spaced relation from each other to define a plurality of flow lanes in the cavity.

Abstract: Provided in one embodiment is an electrochemical cell for generating power, and more particularly to a metal-air electrochemical cell using a low temperature ionic liquid and a liquid metal fuel.

Abstract: Various apparatuses and methods for producing ammonia are provided. One embodiment has uses in a plurality of environments and an electrode configured to be exposed to the plurality of environments. The electrode is configured to receive hydrogen while being exposed to one of the environments, reduce nitrogen while being exposed to another environment, and allow the hydrogen and nitrogen to react with each other to form ammonia. Other embodiments provide for simultaneous hydrogen oxidation and nitrogen reduction at the same electrode, which in turn react for formation of ammonia.

Abstract: An electrode for a charge storage device and a method for forming the electrode. The electrode comprises an electrode body having an essentially continuous phase of an active material, an essentially continuous phase of an electroconductive material, and an essentially continuous phase of void space. The active material is oxidized by applying a potential to the electrode body in the charge storage device so as to transform the active material to an oxide species thereof. The resulting oxide species of the active material has a higher active surface area than the active material prior to the oxidizing.

Abstract: An electrochemical cell system is configured to utilize an oxidant reduction electrode module containing an oxidant reduction electrode mounted to a housing to form a gaseous oxidant space therein that is immersed into the ionically conductive medium. A fuel electrode is spaced from the oxidant reduction electrode, such that the ionically conductive medium may conduct ions between the fuel and oxidant reduction electrodes to support electrochemical reactions at the fuel and oxidant reduction electrodes. A gaseous oxidant channel extending through the gaseous oxidant space provides a supply of oxidant to the oxidant reduction electrode, such that the fuel electrode and the oxidant reduction electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce the oxidant at the oxidant reduction electrode, to generate a discharge potential difference therebetween for application to a load.

Abstract: An electrochemical cell includes a permeable fuel electrode configured to support a metal fuel thereon, and an oxidant reduction electrode spaced from the fuel electrode. An ionically conductive medium is provided for conducting ions between the fuel and oxidant reduction electrodes, to support electrochemical reactions at the fuel and oxidant reduction electrodes. A charging electrode is also included, selected from the group consisting of (a) the oxidant reduction electrode, (b) a separate charging electrode spaced from the fuel and oxidant reduction electrodes, and (c) a portion of the permeable fuel electrode. The charging electrode is configured to evolve gaseous oxygen bubbles that generate a flow of the ionically conductive medium. One or more flow diverters are also provided in the electrochemical cell, and configured to direct the flow of the ionically conductive medium at least partially through the permeable fuel electrode.

Abstract: An electrochemical cell includes a housing, a fuel electrode comprising a metal fuel; an oxidant electrode spaced from the fuel electrode, having fuel electrode and oxidant facing sides, and a liquid ionically conductive medium for conducting ions between the fuel and oxidant electrodes to support electrochemical reactions thereat. The fuel and oxidant electrodes are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce a gaseous oxidant at the oxidant electrode to generate a discharge potential difference therebetween for application to a load. The oxidant electrode includes an active layer configured to participate in the electrochemical reactions, and a current collector electrically coupled to the active layer. The oxidant electrode further includes a graphite layer comprising a mixture of graphite particles and solvophobic binder, the graphite layer providing a surface thereof for exposure to a sealant that adheres the oxidant electrode to the housing.