Abstract: The present invention provides an aqueous emulsion and a process for preparing an aqueous emulsion of a midblock sulfonated styrenic block copolymer comprising at least two non-sulfonated polymer end-blocks A and at least one 5 sulfonated block B comprising the steps of providing a cement of a midblock sulfonated styrenic block copolymer in a non-polar solvent wherein the non-polar solvent is a hydrocarbon compound comprising from 5 to 12 carbon atoms with a boiling point of less than 100 degree Celsius or mixture of such compounds, mixing the cement with a co-solvent to form a mixture, emulsifying the mixture optionally in the 10 presence of an emulsifier with water to produce an emulsion, and removing the hydrocarbon solvent and optionally the co-solvent from the emulsion to produce the aqueous emulsion. The resulting emulsion of the midblock sulfonated styrenic block copolymer has relatively small particle diameters.

Abstract: The present invention concerns aqueous emulsions and a process for preparing aqueous emulsions of a midblock sulfonated styrenic block copolymer comprising at least two non-sulfonated polymer end-blocks A and at least one sulfonated block B, comprising the steps of providing a cement of a midblock sulfonated styrenic block copolymer in the apolar solvent, mixing the cement with a co-solvent to form a mixture, emulsifying the mixture in the absence of a surfactant with water to produce an emulsion, and removing the hydrocarbon solvent and any optional co-solvent from the emulsion to produce the aqueous emulsion. The resulting emulsion of the midblock sulfonated styrenic block copolymer has relatively small particle diameters.

Abstract: The present invention provides an aqueous emulsion and a process for preparing an aqueous emulsion of a midblock sulfonated styrenic block copolymer comprising at least two non-sulfonated polymer end-blocks A and at least one 5 sulfonated block B comprising the steps of providing a cement of a midblock sulfonated styrenic block copolymer in a non-polar solvent wherein the non-polar solvent is a hydrocarbon compound comprising from 5 to 12 carbon atoms with a boiling point of less than 100 degree Celsius or mixture of such compounds, mixing the cement with a co-solvent to form a mixture, emulsifying the mixture optionally in the 10 presence of an emulsifier with water to produce an emulsion, and removing the hydrocarbon solvent and optionally the co-solvent from the emulsion to produce the aqueous emulsion. The resulting emulsion of the midblock sulfonated styrenic block copolymer has relatively small particle diameters.

Abstract: The present invention concerns aqueous emulsions and a process for preparing aqueous emulsions of a midblock sulfonated styrenic block copolymer comprising at least two non-sulfonated polymer end-blocks A and at least one sulfonated block B, comprising the steps of providing a cement of a midblock sulfonated styrenic block copolymer in the apolar solvent, mixing the cement with a co-solvent to form a mixture, emulsifying the mixture in the absence of a surfactant with water to produce an emulsion, and removing the hydrocarbon solvent and any optional co-solvent from the emulsion to produce the aqueous emulsion. The resulting emulsion of the midblock sulfonated styrenic block copolymer has relatively small particle diameters.