Patents by Inventor Cole A. Witham

Cole A. Witham has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9598626
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula: (I), R is an alkyl group having 1 to 6 carbons; R1 may be the same or different than R and is an alkyl group having 1 to 10 carbons or a hydroxy alkyl group comprising n number of carbons wherein n is an integer from 1 to 10 and n?1 hydroxyl groups; R2 is an alkyl group having 1 to 6 carbons; R3 may be the same or different than R2 and is an alkyl group having 1 to 10 carbons or a hydroxy alkyl group comprising n number of carbons wherein n is an integer from 1 to 10 and n?1 hydroxyl groups, with the proviso that R3 is not the same as R1; and X is an anion. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: March 21, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Cole A. Witham, Joseph L. Deavenport, Michael K. Poindexter
  • Patent number: 9574126
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula: (Formula I should be inserted here.) wherein R is hydrogen or an alkyl group having 1 to 12 carbons, R1 is an alkylene group having 1 to 12 carbons, and R2 is an alkyl group having 1 to 12 carbons. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: February 21, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Aleksandr T. Gamble, Cole A. Witham, Michael K. Poindexter, Felipe A. Donate, Kyle R. Essenmacher, Stephen W. King, John Beckerdite
  • Publication number: 20170036939
    Abstract: The present invention relates to a method of dewatering an aqueous mineral suspension comprising introducing into the suspension a flocculating system comprising a poly(ethylene oxide) copolymer, in particular a copolymer of ethylene oxide and one or more silane- or siloxane-functionalized glycidyl ether monomer. Said poly(ethylene oxide) copolymers are useful for the treatment of suspensions of particulate material, especially waste mineral slurries. The invention is particularly suitable for the treatment of tailings and other waste material resulting from mineral processing, in particular, the processing of oil sands tailings.
    Type: Application
    Filed: April 30, 2015
    Publication date: February 9, 2017
    Applicant: Dow Global Technologies LLC
    Inventors: Cole Witham, Matthew J. Hansen, James E. Hitt, Carol E. Mohler, Michael K. Poindexter
  • Publication number: 20170036929
    Abstract: The present invention relates to a method of dewatering an aqueous mineral suspension comprising introducing into the suspension a flocculating system comprising a poly(ethylene oxide) copolymer, in particular a copolymer of ethylene oxide and one or more epoxy or glycidyl ether functionalized hydrophobic monomer. Said poly(ethylene oxide) copolymers are useful for the treatment of suspensions of particulate material, especially waste mineral slurries. The invention is particularly suitable for the treatment of tailings and other waste material resulting from mineral processing, in particular, the processing of oil sands tailings.
    Type: Application
    Filed: April 30, 2015
    Publication date: February 9, 2017
    Applicant: Dow Global Technologies LLC
    Inventors: Cole A. Witham, Matthew J. Hansen, James E. Hitt, Carol E. Mohler, Michael K. Poindexter
  • Patent number: 9416051
    Abstract: Disclosed is a composition and a method for cementing a casing in a borehole of a well using an aqueous cementing composition comprising (a) water, (b) a cementing composition comprising (i) a hydraulic cement, (ii) a hydrophobically modified polymer, (iii) a dispersant, and optionally (iv) one or more other additives conventionally added to aqueous cementing compositions useful in cementing casings in the borehole of wells. Preferably the hydrophobically modified hydroxyethyl cellulose has an ethylene oxide molar substitution of from 0.5 to 3.5, a hydrophobe degree of substitution of from 0.001 to 0.025, and a weight-average molecular weight of from 500,000 to 4,000,000 Daltons and the dispersant is sulfonated polymer, melamine formaldehyde condensate, a naphthalene formaldehyde condensate, a branched or non-branched polycarboxylate polymer.
    Type: Grant
    Filed: December 6, 2013
    Date of Patent: August 16, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Roger L. Kuhlman, Cole A. Witham, Michael K. Poindexter, Raymond M. Jones, Nathan Kyle Combs, Jeffrey T. Watters, Larry T. Watters
  • Patent number: 9328279
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula wherein R is an alkyl group having 1 to 6 carbons, R1 is an alkyl group having 1 to 18 carbons, and X is an anion. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: May 3, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Cole A. Witham, Joseph L. Deavenport, Michael K. Poindexter
  • Publication number: 20150353807
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent comprising a polyaminopolyamide-epichlorohydrin resin, preferably the polyamino polyamide-epichlorohydrin resin is a reaction product of an aliphatic polyamine, an aliphatic polycarboxylic acid, and epichlorohydrin. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Application
    Filed: January 27, 2014
    Publication date: December 10, 2015
    Applicants: The Dow Chemical Company, Dow Chemical International PVT. LTD., Dow International Technology Corporation
    Inventors: Cole A. Witham, Michael K. Poindexter, Stephen W. King, Prashant Tatake
  • Publication number: 20150353810
    Abstract: Disclosed is a composition and a method for cementing a casing in a borehole of a well using an aqueous cementing composition comprising (a) water, (b) a cementing composition comprising (i) a hydraulic cement, (ii) a hydrophobically modified polymer, (iii) a dispersant, and optionally (iv) one or more other additives conventionally added to aqueous cementing compositions useful in cementing casings in the borehole of wells. Preferably the hydrophobically modified hydroxyethyl cellulose has an ethylene oxide molar substitution of from 0.5 to 3.5, a hydrophobe degree of substitution of from 0.001 to 0.025, and a weight-average molecular weight of from 500,000 to 4,000,000 Daltons and the dispersant is sulfonated polymer, melamine formaldehyde condensate, a naphthalene formaldehyde condensate, a branched or non-branched polycarboxylate polymer.
    Type: Application
    Filed: December 6, 2013
    Publication date: December 10, 2015
    Applicant: Dow Global Technologies LLC
    Inventors: Roger L. Kuhlman, Cole A. Witham, Michael K. Poindexter, Raymond M. Jones, Nathan Kyle Combs, Jeffrey T. Watters, Larry T. Watters
  • Publication number: 20150203738
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula: (I), R is an alkyl group having 1 to 6 carbons; R1 may be the same or different than R and is an alkyl group having 1 to 10 carbons or a hydroxy alkyl group comprising n number of carbons wherein n is an integer from 1 to 10 and n-1 hydroxyl groups; R2 is an alkyl group having 1 to 6 carbons; R3 may be the same or different than R2 and is an alkyl group having 1 to 10 carbons or a hydroxy alkyl group comprising n number of carbons wherein n is an integer from 1 to 10 and n-1 hydroxyl groups, with the proviso that R3 is not the same as R1; and X is an anion. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Application
    Filed: July 16, 2013
    Publication date: July 23, 2015
    Inventors: Cole A. Witham, Joseph L. Deavenport, Michael K. Poindexter
  • Publication number: 20150184059
    Abstract: The present invention provides strategies for improved control of fluid loss, hydration, settling, and separation of aqueous cementing compositions over a wide temperature and time range. The present invention is based at least in part upon water-effusing particles used as additives for the compositions, wherein the particles are activated to control rheology when water soluble portions of the particles are released in the presence of water.
    Type: Application
    Filed: July 13, 2013
    Publication date: July 2, 2015
    Inventors: Cole Witham, Roger Kuhlman, Michael Poindexter, Jorg Theuerkauf, Michael Radler
  • Publication number: 20150166867
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula: (Formula I should be inserted here.) wherein R is hydrogen or an alkyl group having 1 to 12 carbons, R1 is an alkylene group having 1 to 12 carbons, and R2 is an alkyl group having 1 to 12 carbons. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Application
    Filed: June 19, 2013
    Publication date: June 18, 2015
    Inventors: Aleksandr T. Gamble, Cole A. Witham, Michael K. Poindexter, Felipe A. Donate, Kyle R. Essenmacher, Stephen W. King, John Beckerdite
  • Publication number: 20150166868
    Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula wherein R is an alkyl group having 1 to 6 carbons, R1 is an alkyl group having 1 to 18 carbons, and X is an anion. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.
    Type: Application
    Filed: July 16, 2013
    Publication date: June 18, 2015
    Applicant: Dow Global Technologies LLC
    Inventors: Cole A. Witham, Joseph L. Deavenport, Michael K. Poindexter
  • Publication number: 20140345867
    Abstract: Disclosed is a composition and a method for cementing a casing in a borehole of a well using an aqueous cementing composition comprising (a) water, (b) a cementing composition comprising (i) a hydraulic cement, (ii) an anionically- and hydrophobically-modified polymer, (iii) a dispersant, and optionally (iv) one or more other additives conventionally added to aqueous cementing compositions useful in cementing casings in the borehole of wells. Preferably the anionically- and hydrophobically-modified hydroxyethyl cellulose has an ethylene oxide molar substitution of from 0.5 to 3.5, a hydrophobe degree of substitution of from 0.001 to 0.025, an anionic degree of substitution of from 0.001 to 1, and a weight-average molecular weight of from 100,000 to 4,000,000 Daltons and the dispersant is sulfonated polymer, melamine formaldehyde condensate, a naphthalene formaldehyde condensate, a branched or non-branched polycarboxylate polymer.
    Type: Application
    Filed: September 26, 2012
    Publication date: November 27, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: Cole A. Witham, Michael K. Poindexter, Roger L. Kuhlman
  • Publication number: 20140206583
    Abstract: Embodiments of the present disclosure include a wellbore servicing fluid that includes a diluent, a hydrophobically modified polymer, and a base. The base provides the wellbore servicing fluid with a pH of greater than 10. The presence of the base in the wellbore servicing fluid helps to minimize changes in the viscosity of the wellbore servicing fluid when a deposit, or a kick, of salt is encountered during the drilling operation.
    Type: Application
    Filed: September 6, 2012
    Publication date: July 24, 2014
    Applicant: DOW Global Technologies LLC
    Inventors: Roger L. Kuhlman, Michael Poindexter, Cole Witham